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Benzo-18-crown-6

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Products Intro: Product Name:14098-24-9 1,4,7,10,13,16-Benzohexaoxacyclooctadecin,2,3,5,6,8,9,11,12,14,15-decahydro-
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  • CAS:14098-24-9
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  • CAS:14098-24-9
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  • Purity: 98% Min
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Benzo-18-crown-6 Basic information
Product Name:Benzo-18-crown-6
Synonyms:4,7,10,13,16-Benzophexaoxacyclooctadecin,,3,5,6,8,9,11,12,14,15-decahydro-1;2,3-BENZO-1,4,7,10,13,16-HEXAOXAOCTADEC-2-ENE;2,3,5,6,8,9,11,12,14,15-DECAHYDRO-1,4,7,10,13,16-BENZOHEXAOXACYCLOOCTADECIN;BENZO-18-CROWN 6-ETHER;BENZO-18-CROWN-6;CROWN ETHER/BENZO-18-CROWN-6;1,4,7,10,13,16-Benzohexaoxacyclooctadecin, 2,3,5,6,8,9,11,12,14,15-decahydro-;2,3,5,6,8,9,11,12, 14,15-decahydro-1,4,7,10,13,16-Benzophexaoxacyclooctadecin
CAS:14098-24-9
MF:C16H24O6
MW:312.36
EINECS:604-215-6
Product Categories:Crown Ethers;Functional Materials;Macrocycles for Host-Guest Chemistry;Chelation/Complexation Compounds;Crown Ethers;Synthetic Reagents
Mol File:14098-24-9.mol
Benzo-18-crown-6 Structure
Benzo-18-crown-6 Chemical Properties
Melting point 42-45 °C (lit.)
Boiling point 412.28°C (rough estimate)
density 1.1858 (rough estimate)
refractive index 1.4795 (estimate)
Fp >230 °F
storage temp. Inert atmosphere,Room Temperature
solubility very faint turbidity in Methanol
form Liquid
color Clear colorless
Sensitive Hygroscopic
BRN 1626123
InChIInChI=1S/C16H24O6/c1-2-4-16-15(3-1)21-13-11-19-9-7-17-5-6-18-8-10-20-12-14-22-16/h1-4H,5-14H2
InChIKeyDSFHXKRFDFROER-UHFFFAOYSA-N
SMILESO1C2=CC=CC=C2OCCOCCOCCOCCOCC1
CAS DataBase Reference14098-24-9(CAS DataBase Reference)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 36/37/38-20/21/22
Safety Statements 22-24/25-37/39-26
WGK Germany 3
3
HazardClass IRRITANT
HS Code 29329985
Storage Class11 - Combustible Solids
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
Benzo-18-crown-6 Usage And Synthesis
Chemical Propertieswhite granular powder and chunks
UsesBenzo-18-crown-6-ether (B18C6) is an organic compound that can be used to prepare stable microcapsule responsive layers for further assembly into bilayer microcapsules. For example, 18-Crown-6-ether is used to prepare the response layer and is coated with a G-quadruplex cross-linked hydrogel layer stabilized by K+; when Mg2+ ions are present, 18-Crown-6-ether and K+ ions can respectively Dissociates and locks with the G-quadruplex cross-linked layer, thereby achieving switchable controlled release of the load[1].
Purification MethodsPurify it by passage through a DEAE cellulose column in cyclohexane. It recrystallises from n-hexane. Its thiourea complex has m 127o [5-6 mol of urea to ether, Pedersen J Org Chem 36 1690 1971]. The stability constants of the Na+, K+, Rb+, Cs+, Tl+ and Ba2+ complexes are described in Hofmanova et al. Inorg Chim Acta 28 73 1978. [NMR: Live & Chan J Am Chem Soc 98 3769 1976]. [Beilstein 19/12 V 618.] IRRITANT.
References[1] Ehala S, et al. Application of affinity capillary electrophoresis and density functional theory to the investigation of benzo-18-crown-6-ether complex with ammonium cation. J Chromatogr A. 2009 Nov 6;1216(45):7927-31. DOI:10.1016/j.chroma.2009.09.034
Benzo-18-crown-6 Preparation Products And Raw materials
Preparation Products2,3-(4-CARBOXYBENZO)-1,4,7,10,13,16-HEXAOXACYCLOOCTADEC-2-ENE
Tag:Benzo-18-crown-6(14098-24-9) Related Product Information
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