Formyl acetate

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CAS:2258-42-6
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CAS:2258-42-6
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Formyl acetate manufacturers

  • Formyl acetate
  • Formyl acetate pictures
  • $0.00 / 25KG
  • 2025-12-01
  • CAS:2258-42-6
  • Min. Order: 1KG
  • Purity: 98.0%
  • Supply Ability: 10000KGS
  • Formyl acetate
  • Formyl acetate pictures
  • $1.00 / 1KG
  • 2025-04-23
  • CAS:2258-42-6
  • Min. Order: 1KG
  • Purity: 99%
  • Supply Ability: 20T
  • Formyl acetate
  • Formyl acetate pictures
  • $0.00 / 1KG
  • 2022-01-04
  • CAS:2258-42-6
  • Min. Order: 1g
  • Purity: 98%minGC
  • Supply Ability: 50kgs/month
Formyl acetate Basic information
Product Name:Formyl acetate
Synonyms:acetic formic anhydride;Acetic acid, anhydride with formic acid;Formic acetic anhydride;FORMYL ACETATE;Acetic acid formyl ester;methanoyl ethanoate;O-ForMyl Acetate;2-Thiazolidinethione,4-phenyl-,(5R)-
CAS:2258-42-6
MF:C3H4O3
MW:88.06
EINECS:202-110-6
Product Categories:
Mol File:2258-42-6.mol
Formyl acetate Structure
Formyl acetate Chemical Properties
Boiling point 27-28 °C(Press: 1 Torr)
density 1.116±0.06 g/cm3(Predicted)
solubility Chloroform (Slightly), Ethyl Acetate (Soluble), Methanol (Slightly)
form Oil
color Colourless
Stability:Air Sensitive, Hygroscopic
Safety Information
HS Code 29159000
MSDS Information
Formyl acetate Usage And Synthesis
DescriptionAcetic formic anhydride, or ethanoic methanoic anhydride is a chemical compound with formula C3H4O3, or H3C-(C=O)-O-(C=O)H. It can be viewed as the mixed anhydride of acetic acid (H3C- (C=O)OH) and formic acid (H(C= O)OH) by removal of a molecule of water.
It can be produced by reaction between sodium formate and acetyl chloride in anhydrous diethyl ether, at 23–27 °C.Among other uses, it is a formylation agent for amines, amino acids, and alcohols, and a starting material for formyl fluoride.
Chemical PropertiesLiquid. Boiling point 27-28°C (1.33kPa). Contact with water accelerates decomposition to produce acetic acid and carbon monoxide.
UsesFormyl acetate is a useful formylating agent for the hydroxyl, phenol, and amine groups as well as other heteroatoms; useful for the synthesis of aldehydes from aromatic Grignard reagents, for the preparation of formyl  fluoride, and for the preparation of diazoacetaldehyde.
PreparationPreparative Methods of Formyl acetate: acetic formic anhydride is not comercially available. The easiest method of  preparation is by the reaction of sodium formate and Acetyl Chloride in dry ether as reported by Krimen. Alternatively, Ketene and Formic Acid form the title compound at room temperature or below. Acetic formic anhydride can be prepared rapidly in situ by stirring formic acid, acetyl chloride, and Triethylamine in THF at -70 °C for 10 min. AFA is found in a mixture of formic acid (excess) with Acetic Anhydride. The mixture is more accurately described as formic acid-acetic anhydride mixture (FAM) and is also used  as a formylating agent. Purification: by fractional distillation at low pressure.
storageHandling, Storage, and Precautions of formyl acetate: it decomposes slowly at room temperature and faster at elevated temperatures, giving acetic acid and carbon monoxide. Due to gas evolution, AFA is best stored at 4 °C in a flask fitted with a polyethylene stopper since sealed samples can explode. The compound is an eye and skin irritant and should be handled in a fume hood.
Tag:Formyl acetate(2258-42-6) Related Product Information
Maleic anhydride Tocopheryl acetate Glatiramer acetate Ethyl acetate Glutaric anhydride Sodium acetate POLY(VINYL ACETATE) Vinyl acetate Methyl acetate Succinic anhydride Formic acid 2-Butanone peroxide Isatoic Anhydride Phthalic anhydride Acetic anhydride ACETATE Methyl 2-Chloro 2-formyl acetate 2-Butanone

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