- 1,6-Diacetoxyhexane
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- $120.00
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2026-02-02
- CAS:6222-17-9
- Min. Order: 1g
- Purity: 98%min
- Supply Ability: 200tons
- 1,6-Diacetoxyhexane
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- $1.00
-
2024-10-22
- CAS:6222-17-9
- Min. Order: 1g
- Purity: 85.0-99.8%
- Supply Ability: 20tons
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| Product Name: | 1,6-Diacetoxyhexane | | Synonyms: | 1,6-dihydroxyhexanediacetate;HEXAMETHYLENE DIACETATE;2-BUTANE-1,4-DIOL DIACETATE;hexane-1,6-diyl diacetate;1,6-DIACETOXYHEXANE;1,6-HEXANEDIOL DIACETATE;Hexanedioldiacetate;1,6-Hexanediol, 1,6-diacetate | | CAS: | 6222-17-9 | | MF: | C10H18O4 | | MW: | 202.25 | | EINECS: | | | Product Categories: | | | Mol File: | 6222-17-9.mol |  |
| | 1,6-Diacetoxyhexane Chemical Properties |
| Safety Statements | 23-24/25 | | RTECS | MO2325000 | | TSCA | TSCA listed | | HS Code | 2915.39.4550 |
| Provider | Language |
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ALFA
| English |
| | 1,6-Diacetoxyhexane Usage And Synthesis |
| Application | 1,6-Diacetoxyhexane, also known as hexanediol diacetate, can be prepared from 3-bromopropylacetate. Literature reports that it can be used to prepare the fungicide 3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxylic acid. | | Synthesis Reference(s) | Tetrahedron Letters, 35, p. 2027, 1994 DOI: 10.1016/S0040-4039(00)73040-1 | | Synthesis | 3-Bromopropyl acetate (453 mg, 2.50 mmol) was added to a solution of CoBr2 (10 mol%, 0.25 mmol, 55 mg) and manganese powder (3.8 eq, 9.5 mmol, 500 mg) in CH3CN (3 mL) at room temperature. The manganese powder was activated with a trace amount of trifluoroacetic acid (50 L) and stirred at room temperature for 5 min until the fumes disappeared. Pyridine (0.5 mL) was added and stirred at 50C for 3-6 hours. Quench by adding 2MHCl (30mL) solution. The solution was extracted with Et2O or EtOAc (3x50 mL), dried over MgSO4, filtered and concentrated in vacuum. 1,6-Diacetoxyhexane was purified by rapid chromatography on silica gel. |
| | 1,6-Diacetoxyhexane Preparation Products And Raw materials |
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