Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine

Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine Suppliers list

Company Name:	Soochow Chirally Material Science and Technology Co.,Ltd Gold
Tel:	0512-66834346 17751187418
Email:	sales@krl-tech.com

Company Name:	Beijing HwrkChemical Technology Co., Ltd
Tel:	89508211 18501085097
Email:	sales.bj@hwrkchemical.com

Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine manufacturers

Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine Basic information

Product Name:	Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine
Synonyms:	BIS[BIS(3,5-TRIFLUOROMETHYL)PHENYL]CHLOROPHOSPHINE;Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine, 98+%;Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine;Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine, 98+%, may contain suspended dimethylamine hydrochloride crystals;P,P-Bis[3,5-bis(trifluoromethyl)phenyl]phosphinous chloride;bis[3,5-bis(trifluoromethyl)phenyl]-chlorophosphane;Bis(3,5-di(trifluoroMethyl)phenyl)chlorophosphine,Min.98%;Phosphinous chloride, P,P-bis[3,5-bis(trifluoromethyl)phenyl]-
CAS:	142421-57-6
MF:	C16H6ClF12P
MW:	492.63
EINECS:
Product Categories:	Catalysis and Inorganic Chemistry;Phosphorus Compounds;Phosphorus Precursors;organophosphine ligand;Achiral Phosphine;Aryl Phosphine;P-Cl
Mol File:	142421-57-6.mol

Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine Chemical Properties

Melting point	25-29 °C
Boiling point	333.2±42.0 °C(Predicted)
form	liquid
color	colorless
Water Solubility	Reacts with water.
Sensitive	Moisture Sensitive
InChI	1S/C16H6ClF12P/c17-30(11-3-7(13(18,19)20)1-8(4-11)14(21,22)23)12-5-9(15(24,25)26)2-10(6-12)16(27,28)29/h1-6H
InChIKey	DFZQEHBNAJGDCT-UHFFFAOYSA-N
SMILES	FC(F)(F)c1cc(cc(c1)C(F)(F)F)P(Cl)c2cc(cc(c2)C(F)(F)F)C(F)(F)F

Safety Information

Hazard Codes	C
Risk Statements	14-34
Safety Statements	26-36/37/39-45
RIDADR	UN3265
WGK Germany	3
HazardClass	8
PackingGroup	II
Storage Class	4.3 - Hazardous materials which set free flammable gases upon contact with water
Hazard Classifications	Skin Corr. 1B Water-react 3

MSDS Information

Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine Usage And Synthesis

Uses	Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine is used as a reactant for the synthesis of chiral phosphine-aminophosphine ligands for rhodium-catalyzed asymmetric hydrogenation, ligands for palladium-catalyzed stereoselective allylation reactions, enantioselective hydrogenations, Josiphos analog as catalyst for asymmetric hydrogenation, ligands used in asymmetric hydrovinylation reactions.
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: ligand

Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine Preparation Products And Raw materials

Raw materials

Tag:Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine(142421-57-6) Related Product Information

Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine, 98+% Bis(3,5-dimethylphenyl)chlorophosphine Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine Methylphenylchlorophosphine Bis(3,5-di(trifluoromethyl)phenyl)phosphine Bis(3,5-dimethylphenyl)phosphine Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine, min. 98% Chlorodiphenylphosphine