Dichloro[1,3-Bis(2-methylphenyl)-2-imidazolidinylidene](benzylidene)(tricyclohexylphosphine)ruthenium(II)

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Dichloro[1,3-Bis(2-methylphenyl)-2-imidazolidinylidene](benzylidene)(tricyclohexylphosphine)ruthenium(II) Basic information
Product Name:Dichloro[1,3-Bis(2-methylphenyl)-2-imidazolidinylidene](benzylidene)(tricyclohexylphosphine)ruthenium(II)
Synonyms:[1,3-bis(2-methylphenyl)-2-(imidazolidene)dichloro(phenylmethylene)(tricyclohexylphosphine)]ruthenium (II);Dichloro[1,3-Bis(2-methylphenyl)-2-imidazolidinylidene](benzylidene)(tricyclohexylphosphine)ruthenium(II);Grubbs Catalyst? M205;Grubbs Catalyst M205
CAS:927429-60-5
MF:C42H57Cl2N2PRu
MW:792.88
EINECS:
Product Categories:
Mol File:927429-60-5.mol
Dichloro[1,3-Bis(2-methylphenyl)-2-imidazolidinylidene](benzylidene)(tricyclohexylphosphine)ruthenium(II) Structure
Dichloro[1,3-Bis(2-methylphenyl)-2-imidazolidinylidene](benzylidene)(tricyclohexylphosphine)ruthenium(II) Chemical Properties
Melting point 160.5-161.0°C
storage temp. 2-8°C
form solid
InChIKeyMYBIVOYIHBQJIU-UHFFFAOYSA-L
SMILESC1CCC(CC1)P(C2CCCCC2)C3CCCCC3.Cc4ccccc4N5CCN(C5[Ru](Cl)(Cl)=Cc6ccccc6)c7ccccc7C
Safety Information
Hazard Codes F
Risk Statements 11
RIDADR UN1325 - class 4.1 - PG 2 - Flammable solids, organic, n.o.s., HI: all
WGK Germany 3
Storage Class4.1B - Flammable solid hazardous materials
Hazard ClassificationsFlam. Sol. 2
MSDS Information
Dichloro[1,3-Bis(2-methylphenyl)-2-imidazolidinylidene](benzylidene)(tricyclohexylphosphine)ruthenium(II) Usage And Synthesis
Uses
  • Highly reactive in metathesis of sterically hindered olefins, particularly in Ring-Closing Metathesis (RCM).
  • Useful for the preparation of tetrasubstituted olefins via RCM.
  • Enabling metathesis catalyst.
Dichloro[1,3-Bis(2-methylphenyl)-2-imidazolidinylidene](benzylidene)(tricyclohexylphosphine)ruthenium(II) Preparation Products And Raw materials
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