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| | 1,3-Bis(diphenylphosphinomethyl)benzene Basic information |
| Product Name: | 1,3-Bis(diphenylphosphinomethyl)benzene | | Synonyms: | 1,3-Bis(diphenylphosphinomethyl)benzene;[1,3-Phenylenebis(methylene)]bis[diphenyl]phosphine;α,α′-Bis(diphenylphosphino)-m-xylene;Phosphine, 1,1'-[1,3-phenylenebis(methylene)]bis[1,1-diphenyl- | | CAS: | 89756-88-7 | | MF: | C32H28P2 | | MW: | 474.51 | | EINECS: | | | Product Categories: | | | Mol File: | 89756-88-7.mol |  |
| | 1,3-Bis(diphenylphosphinomethyl)benzene Chemical Properties |
| Melting point | 50-55°C | | Boiling point | 605.0±48.0 °C(Predicted) | | Fp | >110℃ | | form | powder | | InChI | 1S/C32H28P2/c1-5-16-29(17-6-1)33(30-18-7-2-8-19-30)25-27-14-13-15-28(24-27)26-34(31-20-9-3-10-21-31)32-22-11-4-12-23-32/h1-24H,25-26H2 | | InChIKey | QLSOZHFOFHARBJ-UHFFFAOYSA-N | | SMILES | C(P(c1ccccc1)c2ccccc2)c3cccc(CP(c4ccccc4)c5ccccc5)c3 |
| WGK Germany | 3 | | Storage Class | 13 - Non Combustible Solids | | Hazard Classifications | Aquatic Chronic 4 |
| | 1,3-Bis(diphenylphosphinomethyl)benzene Usage And Synthesis |
| Uses | Reactant for:
- Cyclometalation of pincer ligands
- Insertion of carbon dioxide into (PCP)PDII-Me Bonds
- Synthesis of iridium complexes containing bidentate phosphine ligands
- Transcyclometalation processes
- Synthesis of vinylidene and carbyne complexes
| | reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand |
| | 1,3-Bis(diphenylphosphinomethyl)benzene Preparation Products And Raw materials |
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