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Product Name:N,N,N',N',N'',N''-hexaethylphosphinetriamine
CAS:2283-11-6
Purity:98%(Min,HPLC) Package:100g;1kg;5kg,10kg,25kg,50kg
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| | TRIS(DIETHYLAMINO)PHOSPHINE Basic information |
| Product Name: | TRIS(DIETHYLAMINO)PHOSPHINE | | Synonyms: | hexaethyl-phosphoroustriamid;Hexaethylphosphoruo triamide;P(N(C2H5)2)3;Tris(N,N-diethylamino)phosphine;HEXAETHYLTRIAMINOPHOSPHINE;HEXAETHYLPHOSPHOROUS TRIAMIDE;HEXAETHYLPHOSPHORUS TRIAMIDE;AURORA KA-1249 | | CAS: | 2283-11-6 | | MF: | C12H30N3P | | MW: | 247.36 | | EINECS: | 218-920-8 | | Product Categories: | | | Mol File: | 2283-11-6.mol |  |
| | TRIS(DIETHYLAMINO)PHOSPHINE Chemical Properties |
| Melting point | 230-232 °C | | Boiling point | 80-90 °C10 mm Hg(lit.) | | density | 0.903 g/mL at 25 °C(lit.) | | refractive index | n20/D 1.475(lit.) | | Fp | 58 °C | | storage temp. | Store below +30°C. | | pka | 9.74±0.70(Predicted) | | form | Liquid | | color | Clear colorless to yellow-orange | | Specific Gravity | 0.903 | | Water Solubility | Insoluble in water. | | Sensitive | Air Sensitive | | BRN | 636187 | | InChI | 1S/C12H30N3P/c1-7-13(8-2)16(14(9-3)10-4)15(11-5)12-6/h7-12H2,1-6H3 | | InChIKey | FDIOSTIIZGWENY-UHFFFAOYSA-N | | SMILES | CCN(CC)P(N(CC)CC)N(CC)CC | | CAS DataBase Reference | 2283-11-6(CAS DataBase Reference) | | EPA Substance Registry System | Phosphorous triamide, hexaethyl- (2283-11-6) |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-36 | | RIDADR | UN 1993 3/PG 3 | | WGK Germany | 3 | | F | 10-23 | | TSCA | TSCA listed | | HazardClass | 3 | | PackingGroup | III | | HS Code | 29319090 | | Storage Class | 3 - Flammable liquids | | Hazard Classifications | Eye Irrit. 2
Flam. Liq. 3
Skin Irrit. 2
STOT SE 3 |
| | TRIS(DIETHYLAMINO)PHOSPHINE Usage And Synthesis |
| Chemical Properties | clear colorless to yellow-orange liquid | | Uses | suzuki reaction | | Uses | Tris(diethylamino)phosphine [(Et2N)3P] can be used as a reagent to synthesize:
- 1,1′-Dialkylisoindigo derivatives by reacting with various 1-alkylisatins via deoxygenation reaction.
- 1-Aminomethylisatins by treating with isatin and primary and secondary amines.
It can also be used in the deoxygenation of some cyclic α-diketones using fullerene C60. | | reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand |
| | TRIS(DIETHYLAMINO)PHOSPHINE Preparation Products And Raw materials |
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