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| | Furfuryl mercaptan Basic information |
| | Furfuryl mercaptan Chemical Properties |
| Melting point | 157.5 °C | | Boiling point | 155 °C(lit.) | | density | 1.132 g/mL at 25 °C(lit.) | | FEMA | 2493 | FURFURYL MERCAPTAN | | refractive index | n20/D 1.531(lit.) | | Fp | 113 °F | | storage temp. | Flammables area | | solubility | Chloroform (Slightly), Ethyl Acetate (Slightly) | | pka | 9.59±0.10(Predicted) | | form | Liquid | | color | Clear colorless to pale yellow | | Odor | at 0.10 % in dipropylene glycol. sulfury roasted coffee oily fatty burnt smoky | | Odor Type | coffee | | biological source | synthetic | | Water Solubility | insoluble | | Sensitive | Air Sensitive | | JECFA Number | 1072 | | BRN | 383594 | | Stability: | Air Sensitive | | Major Application | flavors and fragrances | | Cosmetics Ingredients Functions | PERFUMING | | InChI | 1S/C5H6OS/c7-4-5-2-1-3-6-5/h1-3,7H,4H2 | | InChIKey | ZFFTZDQKIXPDAF-UHFFFAOYSA-N | | SMILES | SCc1ccco1 | | LogP | 1.73 | | CAS DataBase Reference | 98-02-2(CAS DataBase Reference) | | NIST Chemistry Reference | 2-Furanmethanethiol(98-02-2) | | EPA Substance Registry System | 2-Furanmethanethiol (98-02-2) |
| Hazard Codes | F,Xn | | Risk Statements | 10-36/37-20/21/22 | | Safety Statements | 23-24/25-16-36-26-7/9 | | RIDADR | UN 3336 3/PG 3 | | WGK Germany | 3 | | RTECS | LU2100000 | | F | 10-13-23 | | TSCA | TSCA listed | | HazardClass | 3 | | PackingGroup | III | | HS Code | 29321900 | | Storage Class | 3 - Flammable liquids | | Hazard Classifications | Flam. Liq. 3 |
| | Furfuryl mercaptan Usage And Synthesis |
| Description | Furfuryl mercaptan has a characteristic unpleasant odor. It is prepared by reacting thiourea and furfuryl chloride with subsequent hydrolysis of the reaction product; also by reduction of difurfuryl disulfide in alcoholic solution using zinc dust and a small amount of acetic acid or using activated alumina. Furfuryl mercaptan tends to polymerize when heated in the presence of mineral acids. | | Chemical Properties | Furfuryl mercaptan has a characteristic unpleasant odor. | | Chemical Properties | clear colorless to pale yellow liquid | | Chemical Properties | 2-Furylmethanethiol is an important constituent
of the aroma of roasted coffee. It is a liquid with an unpleasant odor, which
becomes like coffee when diluted. | | Occurrence | Reported found in raw and roasted chicken, cooked beef, grilled pork, sesame seed oil, coffee and popcorn; tends to polymerize when heated in the presence of mineral acids | | Uses | Furfuryl Mercaptam is a volatile flavor component of corn tortilla chips. | | Preparation | Furfuryl mercaptan is prepared from furfuryl alcohol, thiourea, and hydrogen
chloride.The resulting S-furfurylisothiouronium chloride is cleaved with sodium
hydroxide to give furfuryl mercaptan. | | Definition | ChEBI: 2-Furanmethanethiol is a heteroarene. | | Aroma threshold values | Detection: 0.005 to 0.01 ppb; aroma characteristics at 0.01%: intense sulfurous onion impact, lacrimator, slightly skunk-like with a dairy nuance and a hint of savory and coffee-like notes. | | Taste threshold values | Taste characteristics at 0.2 to 1 ppb: sulfureous, roasted, onion, garlic and coffee. | | General Description | Darkens on storage | | Safety Profile | Poison by
intraperitoneal route. Experimental
reproductive effects. Used as a flavoring in
chocolate, fruit, nuts, and coffee. When
heated to decomposition it emits toxic
fumes of SOx. See also MERCAPTANS. | | Synthesis | Prepared by reacting thiourea and furfuryl chloride with subsequent hydrolysis of the reaction product; also by reduction of difurfuryl disulfde in alcoholic solution using zinc dust and a small amount of acetic acid or using activated alumina. |
| | Furfuryl mercaptan Preparation Products And Raw materials |
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