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Diethylphenylphosphine

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Diethylphenylphosphine manufacturers
Diethylphenylphosphine Basic information
Product Name:Diethylphenylphosphine
Synonyms:Diethylphenylphosphene;Phosphine, diethylphenyl-;Diethylphenylphosphine ,96%;Phenyldiethylphosphine;NSC 158475;Diethylphenylphosphine >;Diethylphenylphosphine >97.0%(GC);diethylphenylphosphino
CAS:1605-53-4
MF:C10H15P
MW:166.2
EINECS:216-516-6
Product Categories:Catalysis and Inorganic Chemistry;Phosphine Ligands;Phosphorus Compounds;Phosphines (Mitsunobu Reaction);Mitsunobu Reaction;Phosphine Ligands;Synthetic Organic Chemistry
Mol File:1605-53-4.mol
Diethylphenylphosphine Structure
Diethylphenylphosphine Chemical Properties
Melting point 45 °C
Boiling point 120-121 °C/29 mmHg (lit.)
density 0.954 g/mL at 25 °C (lit.)
refractive index n20/D 1.546(lit.)
Fp 185 °F
form Liquid
color Colorless to Light yellow
Specific Gravity0.954
Water Solubility Not miscible or difficult to mix in water.
Sensitive Air & Moisture Sensitive
BRN 742484
InChIInChI=1S/C10H15P/c1-3-11(4-2)10-8-6-5-7-9-10/h5-9H,3-4H2,1-2H3
InChIKeyLVTCZSBUROAWTE-UHFFFAOYSA-N
SMILESP(CC)(CC)C1=CC=CC=C1
CAS DataBase Reference1605-53-4(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 17-26-36
RIDADR UN3278
WGK Germany 3
F 10
HazardClass 6.1
PackingGroup III
HS Code 29319090
Storage Class10 - Combustible liquids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Diethylphenylphosphine Usage And Synthesis
Chemical PropertiesColorless liquid
UsesDiethylphenylphosphine is used as a catalyst for selective cross-dimerization, carboxyl migration reactions, selective hydrogenation, asymmetric induction by chiral diphosphines in ring contraction.
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
Diethylphenylphosphine Preparation Products And Raw materials
Raw materialsDiethyl ether-->Nitrogen-->Magnesium-->Bromoethane-->Dichlorophenylphosphine
Tag:Diethylphenylphosphine(1605-53-4) Related Product Information
Octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide Dicyclohexylphenylphosphine (-)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene (+)-1,2-Bis[(2S,5S)-2,5-dimethylphospholano]benzene Bis(2-cyanoethyl)phenylphosphine 3-Methyl-1-phenyl-3-phospholene 1-oxide Dibutylphenylphosphine Diethylphenylphosphine Bis(2-diphenylphosphinoethyl)phenylphosphine (+)-1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene Di-tert-butylphenylphosphine Diethylbenzene Ethylbenzene Bis(3-aminopropyl)phenylphosphine Di-n-pentylphenylphosphine (-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene (-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(I)trifluoromethanesulfonate Diallylphenylphosphine