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| | BIS(2-FURYL)CHLOROPHOSPHINE Basic information |
| Product Name: | BIS(2-FURYL)CHLOROPHOSPHINE | | Synonyms: | BIS(2-FURYL)CHLOROPHOSPHINE;Bis(2-furyl)phosphine chloride,;Bis(2-furyl)phosphinechloride,98+%;Bis(2-furyl)phosphine chloride 85%;Di-2-furanylphosphinous chloride;Chlorodi(2-furyl)phosphine, 98+%;Chlorodi(2-furyl)phosphine;chloro-bis(furan-2-yl)phosphane | | CAS: | 181257-35-2 | | MF: | C8H6ClO2P | | MW: | 200.56 | | EINECS: | | | Product Categories: | | | Mol File: | 181257-35-2.mol |  |
| | BIS(2-FURYL)CHLOROPHOSPHINE Chemical Properties |
| Boiling point | 102-104°C/14mm | | density | 1.287 g/mL at 25 °C | | Fp | 102-104°C/14mm | | refractive index | 1.5930 | | form | liquid | | Water Solubility | Reacts with water. | | Sensitive | Moisture Sensitive | | InChI | 1S/C8H6ClO2P/c9-12(7-3-1-5-10-7)8-4-2-6-11-8/h1-6H | | InChIKey | IYEUYNXDXNWPJI-UHFFFAOYSA-N | | SMILES | ClP(c1ccco1)c2ccco2 |
| Hazard Codes | C | | Risk Statements | 14-34 | | Safety Statements | 26-36/37/39-45 | | RIDADR | UN3265 | | WGK Germany | 3 | | HazardClass | 8 | | PackingGroup | II | | Storage Class | 4.3 - Hazardous materials which set free flammable gases upon contact with water | | Hazard Classifications | Skin Corr. 1B
Water-react 2 |
| | BIS(2-FURYL)CHLOROPHOSPHINE Usage And Synthesis |
| Uses | Reactant for synthesis of:
- Centrostereogenic 1,3-bidentate ferrocenyldiphosphane ligands
- Ferrocene-based chiral diphosphine
- Phosphine containing amino acids
Reactant for:
- α-Arylation of aldehydes
- Stereoselective [2,3] sigmatropic rearrangement of acyclic allylic phosphinites
- Hydrophosphination of functionalized alkenes
| | reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand |
| | BIS(2-FURYL)CHLOROPHOSPHINE Preparation Products And Raw materials |
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