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| | ETHYL 2-CYANO-3-METHYLCROTONATE Basic information |
| | ETHYL 2-CYANO-3-METHYLCROTONATE Chemical Properties |
| Melting point | ca 20℃ | | Boiling point | 98-99 °C/1 mmHg (lit.) | | density | 1.014 g/mL at 25 °C (lit.) | | refractive index | n20/D 1.464(lit.) | | Fp | 224 °F | | BRN | 507839 | | InChI | 1S/C8H11NO2/c1-4-11-8(10)7(5-9)6(2)3/h4H2,1-3H3 | | InChIKey | PZMDAADKKAXROL-UHFFFAOYSA-N | | SMILES | CCOC(=O)\C(C#N)=C(\C)C |
| Hazard Codes | Xn | | Risk Statements | 20/21/22-36/37/38 | | Safety Statements | 26-37/39 | | RIDADR | 3276 | | WGK Germany | 3 | | HazardClass | 6.1 | | PackingGroup | III | | HS Code | 29269095 | | Storage Class | 10 - Combustible liquids | | Hazard Classifications | Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| | ETHYL 2-CYANO-3-METHYLCROTONATE Usage And Synthesis |
| Chemical Properties | clear colorless to slightly yellow liquid | | Uses | Ethyl 2-cyano-3-methyl-2-butenoate, a highly activated acceptor, undergoes the phospha-Michael reaction upon trituration of the reagents at room temperature. | | Synthesis Reference(s) | Journal of the American Chemical Society, 71, p. 3418, 1949 DOI: 10.1021/ja01178a044 | | General Description | Ethyl 2-cyano-3-methyl-2-butenoate, a highly activated acceptor, undergoes the phospha-Michael reaction upon trituration of the reagents at room temperature. |
| | ETHYL 2-CYANO-3-METHYLCROTONATE Preparation Products And Raw materials |
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