2,6-Dimethylphenylpropionate

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2,6-Dimethylphenylpropionate Basic information
Product Name:2,6-Dimethylphenylpropionate
Synonyms:3-(2,6-DIMETHYLPHENYL)PROPIONIC ACID;2,6-Xylyl Propionate;Phenol, 2,6-dimethyl-, 1-propanoate;2,6-Dimethylphenylpropionate
CAS:51233-80-8
MF:C11H14O2
MW:178.23
EINECS:
Product Categories:Intermediates;Aromatics Compounds;Aromatics
Mol File:Mol File
2,6-Dimethylphenylpropionate Structure
2,6-Dimethylphenylpropionate Chemical Properties
Boiling point 78-80°C under H.V.
density 1.012±0.06 g/cm3(Temp: 25 °C; Press: 760 Torr)(predicted)
storage temp. Refrigerator, under inert atmosphere
solubility Chloroform (Slightly), Methanol (Slightly)
form Oil
color Colourless
Safety Information
MSDS Information
2,6-Dimethylphenylpropionate Usage And Synthesis
Chemical PropertiesColourless Oil
Uses2,6-Dimethylphenylpropionate is used as an intermediate in the Saliniketal A, B formal synthesis desymmetrization.
Preparation 2,6-Dimethylphenyl Propionate is prepared in excellent yield by the reaction of the sodium or lithium salt of 2,6-dimethylphenol with propionyl chloride.[1a,1b]
General Description2,6-Dimethylphenyl Propionate is a lithium, titanium, and zirconium enolates used in the stereoselective synthesis of anti or syn β-hydroxy acid derivatives.
References1. (a) Montgomery, S. H.; Pirrung, M. C.; Heathcock, C. H. OS 1985, 63, 99; OSC 1990, 7, 190. (b) Heathcock, C. H.; Pirrung, M. C.; Montgomery, S. H.; Lampe, J. T 1981, 37, 4087
2,6-Dimethylphenylpropionate Preparation Products And Raw materials
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