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2-Bromonaphthalene

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CAS:580-13-2
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2-Bromonaphthalene manufacturers

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2-Bromonaphthalene Basic information
Product Name:2-Bromonaphthalene
Synonyms:BETA-NAPHTHYL BROMIDE;BETA-BROMONAPHTHALENE;BROMONAPHTHALENE(2-);2-BROMONAPHTHALENE;2-bromo-naphthalen;2-Naphthyl bromide;Naphthalene, 2-bromo-;naphthalene,2-bromo-
CAS:580-13-2
MF:C10H7Br
MW:207.07
EINECS:209-452-5
Product Categories:B;Bioactive Small Molecules;Building Blocks;C9 to C12;Cell Biology;Chemical Synthesis;Halogenated Hydrocarbons;Organic Building Blocks;White crystal powder;Aryl;C9 to C12;Halogenated Hydrocarbons;FINE Chemical & INTERMEDIATES;Naphthalene derivatives;Aromatic Compounds;Naphthalene series;bc0001;OLED
Mol File:580-13-2.mol
2-Bromonaphthalene Structure
2-Bromonaphthalene Chemical Properties
Melting point 52-55 °C (lit.)
Boiling point 281-282 °C (lit.)
density 1,605 g/cm3
refractive index 1.6382
Fp >230 °F
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility methanol: soluble50mg/mL, clear, colorless to yellow
form Liquid
color Clear light yellow to orange-brown
Water Solubility slightly soluble
Merck 14,1426
BRN 1858110
InChI1S/C10H7Br/c11-10-6-5-8-3-1-2-4-9(8)7-10/h1-7H
InChIKeyAPSMUYYLXZULMS-UHFFFAOYSA-N
SMILESBrc1ccc2ccccc2c1
CAS DataBase Reference580-13-2(CAS DataBase Reference)
NIST Chemistry Reference2-Bromonaphthalene(580-13-2)
EPA Substance Registry SystemNaphthalene, 2-bromo- (580-13-2)
Safety Information
Hazard Codes 
RIDADR UN1230 - class 3 - PG 2 - Methanol
WGK Germany 3
TSCA TSCA listed
HS Code 29039990
Storage Class11 - Combustible Solids
Hazard ClassificationsAcute Tox. 4 Oral
Eye Irrit. 2
MSDS Information
ProviderLanguage
2-Bromonaphthalene English
ACROS English
SigmaAldrich English
ALFA English
2-Bromonaphthalene Usage And Synthesis
Chemical PropertiesWhite or pale yellow powder
Uses2-Bromonaphthalene is used as a raw material in the preparation of biaryls through Suzuki cross coupling reaction. Further, it plays a vital role in the preparation of dyes. It is also used to study potential tumorigenicity.
Synthesis Reference(s)The Journal of Organic Chemistry, 32, p. 1607, 1967 DOI: 10.1021/jo01280a069
Tetrahedron Letters, 26, p. 5939, 1985 DOI: 10.1016/S0040-4039(00)98266-2
General DescriptionReaction of 2-bromonaphthalene with cuprous cyanide in N-methylpyrrolidone has been investigated. Nanosecond time-resolved resonance Raman spectra of the T1→Tn transition of 2-bromonaphthalene in methanol solvent has been investigated.
Purification MethodsPurify 2-bromonaphthalene by fractional elution from a chromatographic column of activated alumina. Crystallise it from EtOH. [Beilstein 5 IV 1667.]
Tag:2-Bromonaphthalene(580-13-2) Related Product Information
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