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Selenium sulfide(56093-45-9)

Selenium sulfide(56093-45-9)
Product IdentificationBack to Contents
【Product Name】

Selenium sulfide
【Synonyms】

Selenium monosulfide
【CAS】

7446-34-6
【Formula】

SSe
【Molecular Weight】

111.02
【RTECS】

VT0525000
【RTECS Class】

Tumorigen; Drug; Mutagen
【Beilstein/Gmelin】

68528 (G)
Physical and Chemical PropertiesBack to Contents
【Appearance】

Orange-yellow tablets or powder. Has a faint odor.
【Solubility in water】

Insoluble
【Density】

3.056 g/cm3 (20 C)
【Usage】

An antifungal agent often used in shampoos for the treatment of dandruff and seborrheic dermatitis.
First Aid MeasuresBack to Contents
【Ingestion】

Seek medical assistance.
【Inhalation】

IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. IMMEDIATELY call a physician and be prepared to transport the victim to a hospital even if no symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used.
【Skin】

IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.
【Eyes】

First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.
Handling and StorageBack to Contents
【Storage】

All containers of selenium or its compounds should be stored in a dry, preferably cool room. Do not store near noncompatible materials such as acids or oxidizing agents.
【Handling】

All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
Hazards IdentificationBack to Contents
【Inhalation】

Pulmonary edema and cardiopulmonary arrest are possible.
【Skin】

Dermatitis and nasal irritation may be present.
【Eyes】

See Inhalation.
【Ingestion】

Gastrointestinal effects are generally the first symptoms seen. Acute effects may include: vomiting, hypersalivation, diarrhea, abdominal pain, a burning sensation in the nostrils and/or oral mucosa, chemical burns of the alimentary tract and a garlic-like odor on the breath.
【UN (DOT)】

3283
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Dispensers of liquid detergent should be available. In the laboratory, gloves and protective clothing should always be worn but should not be assumed to provide full protection. Carefully fitted masks or respirators may be necessary when working with particulates or gases, and disposable plastic aprons might provide additional protection. Protective clothing should be of distinctive color, as a reminder not to be worn outside the laboratory.
【Respirators】

Wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter.
【Exposure Effects】

Dizziness, decreased reflexes, CNS depression, and coma have been reported.
【Exposure limit(s)】

OSHA: PEL (8 h TWA): 0.2 mg/m3.
Fire Fighting MeasuresBack to Contents
【Fire Fighting】

Fires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher.
【Fire Potential】

This material is probably combustible.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

If you spill this chemical, you should dampen the solid spill material with water, then transfer the dampened material to a suitable container. Use absorbent paper dampened with water to pick up any remaining material. Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal. Wash all contaminated surfaces with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.
Stability and ReactivityBack to Contents
【Incompatibilities】

Incompatible with acids.
【Stability】

No data.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

3283
【Hazard Class】

6.1(a)
【Packing Group】

II
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