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a-Chloro-4-nitrotoluene(100-14-1)

a-Chloro-4-nitrotoluene(100-14-1)
Product IdentificationBack to Contents
【Product Name】

a-Chloro-4-nitrotoluene
【Synonyms】

1-(Chloromethyl)-4-nitrobenzene
4-Nitrophenylmethyl chloride
a-Chloro-p-nitrotoluene
p-(Chloromethyl)nitrobenzene
【CAS】

100-14-1
【Formula】

C7H6ClNO2
【Molecular Weight】

171.59
【EINECS】

202-822-7
【RTECS】

XS9093000
【RTECS Class】

Mutagen
【Beilstein/Gmelin】

387187
【Beilstein Reference】

4-05-00-00856
Physical and Chemical PropertiesBack to Contents
【Solubility in water】

Insoluble
【Melting Point】

68 - 70
【Boiling Point】

293
【Vapor Pressure】

.0032
【Density】

1.5647 g/cm3 (20 C)
【Partition Coefficient】

2.22
【Heat Of Vaporization】

51.1 kJ/mol
First Aid MeasuresBack to Contents
【Ingestion】

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Handling and StorageBack to Contents
【Storage】

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Handling】

All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
Hazards IdentificationBack to Contents
【Ingestion】

Causes irritation.
【Inhalation】

Causes irritation.
【Skin】

Causes irritation.
【Eyes】

Causes irritation.
【Hazards】

Incompatible with sodium hydroxide.
【EC Risk Phrase】

R 20/21/22 34
【EC Safety Phrase】

S 26 36/37/39 45
【UN (DOT)】

2433
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Wear protective gloves and clothing and safety goggles.
【Respirators】

Not available.
Fire Fighting MeasuresBack to Contents
【Flash Point】

130
【Fire Fighting】

Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Wear self-contained (positive pressure if available) breathing apparatus and full protective clothing.This material may burn but does not ignite readily. Small fires: dry chemical, carbon dioxide, water spray or foam. Large fires: Water spray, fog or foam. Move container from fire area if you can do it without risk.
【Fire Potential】

Combustible Liquid.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. If water pollution occurs, notify appropriate authorities. Do not touch spilled material; stop leak if you can do so without risk. Small spills: absorb with sand or other noncombustible absorbent material and place into containers for later disposal. Small dry spills: with clean shovel, place material into clean, dry container and cover; move containers from spill area. Large spills: dike far ahead of spill for alter disposal.
Stability and ReactivityBack to Contents
【Incompatibilities】

Incompatible with sodium hydroxide If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation.
【Stability】

Stable at room temperature in closed containers under normal storage and handling conditions.
【Combustion Products】

During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Transport InformationBack to Contents
【UN Number】

2433
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