一般描述
cis,cis-Mucononitrile (Z,Z-2,4-hexadienedinitrile) can be prepared by the copper-catalyzed oxidation of o-phenylenediamine. 13C MAS NMR spectra of cis,cis-mucononitrile oriented in liquid-crystalline media has been studied. Pt-catalyzed addition of diethylphosphine to cis,cis-mucononitrile yields the new diphosphine, Et2PCH(CN)CH(CH2CH2CN)PEt2.
应用
cis,cis-Mucononitrile may be used in chemical synthesis.
Sigma-Aldrich西格玛奥德里奇(上海)贸易有限公司
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