中文名：[(S)-(-)-2,2'-双(二苯基膦)-1,1'-联萘基](对伞花烃)氯化钌(II)氯化物
英文名：(S)-RuCl[(p-cymene(BINAP)]Cl
纯度：≥98%
货号：S138141
Cas号：130004-33-0
存储温度：2-8°C储存,充氩
运输条件：低温运输
产品介绍：
Product class
M-P, Homogeneous Catalysts, M-C, Arene/Aryl Ligands, Phosphorus Ligands - Chiral
Reaction type
Hydrogenation, Asymmetric Reactions, Asymmetric Hydrogenation, Transfer Hydrogenation
Chemical properties
Empirical formula
[RuCl(p-cymene)(S)-BINAP)]Cl
Theoretical metal content
Applications & references
Synthesis of (R)- or (S)-4-halo-3-hydroxybuyrate ester by asymmetric hydrogenation of 4-halo-3-oxobutanoate ester; this reaction can be applied in the Producteion of L-carnitine.
Reference: EP2386536
Enantioselective hydrogenation of functionalized ketones.
Reference: EP0366390
Asymmetric hydrogenation of halogenated acetophenones to enantiomerically pure halogenated phenyl ethanol derivatives.
Reference: Cat. Lett. 1996, 41, 111 (DOI: 10.1007/BF00811721)
Highly enantioselective catalytic hydrogenation of methyl-N-tertbutyl-3-oxoglutarate as a key step in the total synthesis of rovastatin.
Reference: Tetrah. Lett. 2008, 49, 4836 (DOI: 10.1016/j.tetlet.2008.06.018)
Enantioselective hydrogenation of 4-(hydroxymethyl)furan-2(5H)-one derivatives.
Reference: J. Mol. Cat. A: Chem. 2006, 259, 103 (DOI: 10.1016/j.molcata.2006.05.066)
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关键字： 氯代[(S)-(-)-2,2'-双(二苯基膦)-1,1'-联萘](p-伞花素)氯化钌(II) ; 氯化[(S)-(-)-2,2'-双(二苯基膦)-1,1'-联萘基](对伞花烃)钌(II)氯化物;Chloro[(R)-(+)-2,2 inverted exclamation mark -bis(diphenylphosphino)-1,1 inverted exclamation mark -binaphthyl](p-cymene)ruthenium(II) Chloride ; D97679
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