中文名:Ir[dFMeppy]₂-(4,4′-dCF₃bpy)PF₆
英文名:Ir[dFMeppy]₂-(4,4′-dCF₃bpy)PF₆
纯度:≥95%
货号:I463575
Cas号:2229858-27-7
存储温度:避光,充氩
运输条件:常规运输
产品介绍:
Application
Under a dual catalytic copper/photoredox manifold, the Mes-Umemoto reagent has been demonstrated to be an excellent photocatalyst for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. For trifluoromethylation reactions, use with dMesSCF3 and supersilanol;
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关键字: 4,4'-双(三氟甲基)-2,2'-联吡啶双[3,5-二氟-2-[5-甲基-2-吡啶基)苯基]铱(III)六氟磷酸盐 ; 铱化合物Ir[dFMeppy]2-(4,4'-dCF3bpy)PF6;4,4'-Bis(trifluoromethyl)-2,2'-bipyridinebis[3,5-difluoro-2-[5-methyl-2-pyridinyl)phenyl]iridium(III)hexafluorophosphate ; Photocatalyst
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