中文名称双(正丁基环戊二烯基)二氯化锆中文同义词双(正丁基环戊二稀基)二氯化锆;二氯化双(正丁基环成二烯基)锆;双(正丁基环戊二烯基)二氯化锆;双[(1,2,3,4,5-Η)-1-丁基-2,4-环戊二烯-1-基]二氯合锆;双(丁基环戊二烯基)二氯化锆(IV);二(正丁基环戊二烯基)二氯化锆(IV),98+%;二(正丁基环戊二烯基)二氯化锆(IV);1,1'-DIBUTYLZIRCONOCENEDICHLORIDE1,1'-二丁基二茂二氯化锆英文名称Bis(n-butylcyclopentadienyl)zirconiumdichloride英文同义词Bis(n-butylcyclopentadienyl)zirconium(IV)dichloride,98+%;Bis(n-butylcyclopentadienyl)zirconiumdichloride,97%;Bis(n-butylcyclopent;ZirconiuM,bis[(1,2,3,4,5-h)-1-butyl-2,4-cyclopentadien-1-yl]dichloro-;Bis(n-butylcyclopentadienyl)zirconiuMdichlorideSynonyMsBis(butylcyclopentadienyl)zirconiuM(IV)dichloride;Name:bis(n-butylcyclopentadienyl)zirconiumdichloride";Dibutylzirconocenedichloride;Bis(n-butylcyclopentadienyl)zirconiumdichloride,98+%CAS号73364-10-0分子式C18H26Cl2Zr分子量404.53EINECS号416-980-1相关类别催化剂;聚合催化剂;合成中间体;金属有机物;精细化工原料;原料;metallocene;ClassesofMetalCompounds;Metallocenes;Titanocene,etc.;TransitionMetalCompounds;Zr(Zirconium)Compounds;CatalysisandInorganicChemistry;ChemicalSynthesis;ZirconiumMol文件73364-10-0.mol
SAFETY DATA SHEETS
According to the UN GHS revision 10
Version: 1.0
Creation Date: July 15, 2019
Revision Date: July 15, 2019
SECTION 1: Identification
1.1GHS Product identifier
| Product name | Zirconium, bis[(1,2,3,4,5-h)-1-butyl-2,4-cyclopendandiene-1-yl]dichloro-bis(n-butylcyclopentadienyl) zirconium dichloride |
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1.2Other means of identification
| Product number | - |
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| Other names | Bis(n-butylcyclopentadienyl)zirconium dichloride; |
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1.3Recommended use of the chemical and restrictions on use
| Identified uses | Industrial and scientific research use. |
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| Uses advised against | no data available |
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SECTION 2: Hazard identification
2.1Classification of the substance or mixture
Skin corrosion, Sub-category 1B
Skin sensitization, Category 1
Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 2
2.2GHS label elements, including precautionary statements
| Pictogram(s) |   |
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| Signal word | Danger |
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| Hazard statement(s) | H314 Causes severe skin burns and eye damage H317 May cause an allergic skin reaction H411 Toxic to aquatic life with long lasting effects |
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| Precautionary statement(s) |
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| Prevention | P260 Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash ... thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/... P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. |
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| Response | P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P363 Wash contaminated clothing before reuse. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P316 Get emergency medical help immediately. P321 Specific treatment (see ... on this label). P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P302+P352 IF ON SKIN: Wash with plenty of water/... P333+P317 If skin irritation or rash occurs: Get medical help. P362+P364 Take off contaminated clothing and wash it before reuse. P391 Collect spillage. |
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| Storage | P405 Store locked up. |
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| Disposal | P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. |
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2.3Other hazards which do not result in classification
SECTION 3: Composition/information on ingredients
3.1Substances
| Chemical name | Common names and synonyms | CAS number | EC number | Concentration |
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| Zirconium, bis[(1,2,3,4,5-h)-1-butyl-2,4-cyclopendandiene-1-yl]dichloro-bis(n-butylcyclopentadienyl) zirconium dichloride | Zirconium, bis[(1,2,3,4,5-h)-1-butyl-2,4-cyclopendandiene-1-yl]dichloro-bis(n-butylcyclopentadienyl) zirconium dichloride | 73364-10-0 | - | 100% |
SECTION 4: First-aid measures
4.1Description of necessary first-aid measures
If inhaled
Move the victim into fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration and consult a doctor immediately. Do not use mouth to mouth resuscitation if the victim ingested or inhaled the chemical.
Following skin contact
Take off contaminated clothing immediately. Wash off with soap and plenty of water. Consult a doctor.
Following eye contact
Rinse with pure water for at least 15 minutes. Consult a doctor.
Following ingestion
Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.
4.2Most important symptoms/effects, acute and delayed
4.3Indication of immediate medical attention and special treatment needed, if necessary
SECTION 5: Fire-fighting measures
5.1Suitable extinguishing media
Use dry chemical, carbon dioxide or alcohol-resistant foam.
5.2Specific hazards arising from the chemical
5.3Special protective actions for fire-fighters
Wear self-contained breathing apparatus for firefighting if necessary.
SECTION 6: Accidental release measures
6.1Personal precautions, protective equipment and emergency procedures
Avoid dust formation. Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. Use personal protective equipment.Wear chemical impermeable gloves. Ensure adequate ventilation.Remove all sources of ignition. Evacuate personnel to safe areas.Keep people away from and upwind of spill/leak.
6.2Environmental precautions
Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.
6.3Methods and materials for containment and cleaning up
Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.
SECTION 7: Handling and storage
7.1Precautions for safe handling
Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
7.2Conditions for safe storage, including any incompatibilities
Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials.
SECTION 8: Exposure controls/personal protection
8.1Control parameters
Occupational Exposure limit values
Biological limit values
8.2Appropriate engineering controls
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
8.3Individual protection measures, such as personal protective equipment (PPE)
Eye/face protection
Wear tightly fitting safety goggles with side-shields conforming to EN 166(EU) or NIOSH (US).
Skin protection
Wear fire/flame resistant and impervious clothing. Handle with gloves. Gloves must be inspected prior to use. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Respiratory protection
If the exposure limits are exceeded, irritation or other symptoms are experienced, use a full-face respirator.
Thermal hazards
SECTION 9: Physical and chemical properties and safety characteristics
| Physical state | white crystalline powder or needles |
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| Colour | no data available |
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| Odour | no data available |
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| Melting point/freezing point | 271°C(lit.) |
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| Boiling point or initial boiling point and boiling range | 144°C |
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| Flammability | no data available |
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| Lower and upper explosion limit/flammability limit | no data available |
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| Flash point | 54°C(lit.) |
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| Auto-ignition temperature | no data available |
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| Decomposition temperature | no data available |
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| pH | no data available |
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| Kinematic viscosity | no data available |
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| Solubility | no data available |
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| Partition coefficient n-octanol/water | no data available |
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| Vapour pressure | no data available |
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| Density and/or relative density | no data available |
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| Relative vapour density | no data available |
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| Particle characteristics | no data available |
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SECTION 10: Stability and reactivity
10.1Reactivity
10.2Chemical stability
10.3Possibility of hazardous reactions
10.4Conditions to avoid
10.5Incompatible materials
10.6Hazardous decomposition products
SECTION 11: Toxicological information
Acute toxicity
Skin corrosion/irritation
Serious eye damage/irritation
Respiratory or skin sensitization
Germ cell mutagenicity
Carcinogenicity
Reproductive toxicity
STOT-single exposure
STOT-repeated exposure
Aspiration hazard
SECTION 12: Ecological information
12.1Toxicity
Toxicity to fish: no data available
Toxicity to daphnia and other aquatic invertebrates: no data available
Toxicity to algae: no data available
Toxicity to microorganisms: no data available
12.2Persistence and degradability
12.3Bioaccumulative potential
12.4Mobility in soil
12.5Other adverse effects
SECTION 13: Disposal considerations
13.1Disposal methods
Product
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Contaminated packaging
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
SECTION 14: Transport information
14.1UN Number
| ADR/RID: UN3261 (For reference only, please check.) | IMDG: UN3261 (For reference only, please check.) | IATA: UN3261 (For reference only, please check.) |
14.2UN Proper Shipping Name
| ADR/RID: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. (For reference only, please check.) | IMDG: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. (For reference only, please check.) | IATA: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. (For reference only, please check.) |
14.3Transport hazard class(es)
| ADR/RID: 8 (For reference only, please check.) | IMDG: 8 (For reference only, please check.) | IATA: 8 (For reference only, please check.) |
14.4Packing group, if applicable
| ADR/RID: I (For reference only, please check.) | IMDG: I (For reference only, please check.) | IATA: I (For reference only, please check.) |
14.5Environmental hazards
| ADR/RID: Yes | IMDG: Yes | IATA: Yes |
14.6Special precautions for user
14.7Transport in bulk according to IMO instruments
SECTION 15: Regulatory information
15.1Safety, health and environmental regulations specific for the product in question
| Chemical name | Common names and synonyms | CAS number | EC number |
|---|
| Zirconium, bis[(1,2,3,4,5-h)-1-butyl-2,4-cyclopendandiene-1-yl]dichloro-bis(n-butylcyclopentadienyl) zirconium dichloride | Zirconium, bis[(1,2,3,4,5-h)-1-butyl-2,4-cyclopendandiene-1-yl]dichloro-bis(n-butylcyclopentadienyl) zirconium dichloride | 73364-10-0 | - |
| European Inventory of Existing Commercial Chemical Substances (EINECS) | Not Listed. |
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| EC Inventory | Not Listed. |
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| United States Toxic Substances Control Act (TSCA) Inventory | Listed. |
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| China Catalog of Hazardous chemicals 2015 | Not Listed. |
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| New Zealand Inventory of Chemicals (NZIoC) | Not Listed. |
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| Philippines Inventory of Chemicals and Chemical Substances (PICCS) | Not Listed. |
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| Vietnam National Chemical Inventory | Not Listed. |
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| Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) | Listed. |
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| Korea Existing Chemicals List (KECL) | Listed. |
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SECTION 16: Other information
Information on revision
| Creation Date | July 15, 2019 |
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| Revision Date | July 15, 2019 |
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Abbreviations and acronyms
CAS: Chemical Abstracts Service
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
IMDG: International Maritime Dangerous Goods
IATA: International Air Transportation Association
TWA: Time Weighted Average
STEL: Short term exposure limit
LC50: Lethal Concentration 50%
LD50: Lethal Dose 50%
EC50: Effective Concentration 50%
References
IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
ECHA - European Chemicals Agency, website: https://echa.europa.eu/
Any questions regarding this SDS, Please send your inquiry to sds@xixisys.com
Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.
关键字： 双(正丁基环戊二烯基)二氯化锆;73364-10-0;催化剂原料;
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