Chemical Safety Data Sheet MSDS / SDS

2-Bromobiphenyl

Revision Date:2026-03-21Revision Number:1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Product identifier

  • Product name: 2-Bromobiphenyl
  • CBnumber: CB5733745
  • EINECS Number: 218-141-3
  • Synonyms: 2-bromo-1,1'-biphenyl

Relevant identified uses of the substance or mixture and uses advised against

  • Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
  • Uses advised against: none

Company Identification

  • Company: Chemicalbook
  • Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
  • Telephone: 010-86108875

SECTION 2: Hazards identification

GHS Label elements, including precautionary statements

  • Symbol(GHS)
  • Signal wordDanger
Precautionary statements
P273 Avoid release to the environment.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
Hazard statements
H372 Causes damage to organs through prolonged or repeated exposure
H411 Toxic to aquatic life with long lasting effects
H317 May cause an allergic skin reaction
H302 Harmful if swallowed

SECTION 3: Composition/information on ingredients

Substance

  • Product name: 2-Bromobiphenyl
  • Synonyms: 2-bromo-1,1'-biphenyl
  • CAS: 2052-07-5
  • EC number: 218-141-3
  • MF: C12H9Br
  • MW: 233.1

SECTION 4: First aid measures

Eye Contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

Skin Contact

Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Get medical attention.

Inhalation

Remove from exposure, lie down. Remove to fresh air. If not breathing, give artificial respiration. Get medical attention.

Ingestion

Clean mouth with water. Get medical attention.

Most important symptoms and effects

Difficulty in breathing. Inhalation of high vapor concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting

Self-Protection of the First Aider

Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination.

Notes to Physician

Treat symptomatically. Symptoms may be delayed.

SECTION 5: Firefighting measures

Suitable Extinguishing Media

Water spray. Carbon dioxide (CO2). Dry chemical. Chemical foam.

Extinguishing media which must not be used for safety reasons

No information available.

Specific Hazards Arising from the Chemical

Thermal decomposition can lead to release of irritating gases and vapors.

Protective Equipment and Precautions for Firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

NFPA 704

2
0
0
HEALTH 2 Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury (e.g. diethyl ether, ammonium phosphate, iodine)
FIRE 0 Materials that will not burn under typical fire conditions, including intrinsically noncombustible materials such as concrete, stone, and sand. Materials that will not burn in air when exposed to a temperature of 820 °C (1,500 °F) for a period of 5 minutes.(e.g. Carbon tetrachloride)
REACT 0 Normally stable, even under fire exposure conditions, and is not reactive with water (e.g. helium,N2)
SPEC. HAZ.

SECTION 6: Accidental release measures

desc_info

Personal Precautions
Ensure adequateventilation.
Environmental Precautions
See Section 12 for additionalEcologicalInformation.
Methods for Containment and Clean Up
Soak up with inertabsorbentmaterial (e.g.sand,silicagel,acidbinder,universalbinder,sawdust).Keepinsuitable,closed
containers for disposal. Do not let this chemical enter theenvironment.
Refer to protectivemeasureslisted in Sections 8and 13.

SECTION 7: Handling and storage

Handling

Avoid contact with skin and eyes. Do not breathe mist/vapors/spray. Do not ingest. If swallowed then seek immediate medical assistance.

Storage

Keep in a dry, cool and well-ventilated place. Keep container tightly closed.

Specific Use(s)

Use in laboratories

SECTION 8: Exposure controls/personal protection

Control Parameters

Exposure Controls

Engineering Measures

Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source.

Personal protective equipment

Eye Protection
Goggles (European standard - EN 166)
Hand Protection
Protective gloves
Glove materialBreakthrough timeGlove thicknessEU standardGlove comments
Viton (R)See manufacturers recommendations-EN 374(minimum requirement)

Inspect gloves before use.
Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves.
(Refer to manufacturer/supplier for information)
Ensure gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g.
sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion.
Remove gloves with care avoiding skin contamination.
Skin and body protection
Wear appropriate protective gloves and clothing to prevent skin exposure
Respiratory Protection
No protective equipment is needed under normal use conditions.
Large scale/emergency use
Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced
Small scale/Laboratory use
Maintain adequate ventilation

Hygiene Measures

Handle in accordance with good industrial hygiene and safety practice.

Environmental exposure controls

No information available.

SECTION 9: Physical and chemical properties

Information on basic physicochemical properties

  • ColourClear colorless
  • AppearanceColorless
  • Physical StateLiquid
  • OdorNo information available
  • Odor ThresholdNo data available
  • pHNo information available
  • Melting Point/Range1.5 - 2 °C / 34.7 - 35.6 °F
  • Softening PointNo data available
  • Boiling Point/Range297 - 298 °C / 566.6 - 568.4 °F @ 760 mmHg
  • Flash Point113 °C / 235.4 °F Method - No information available
  • Evaporation RateNo data available
  • Flammability (solid,gas)Not applicable Liquid
  • Explosion LimitsNo data available
  • Vapor PressureNo data available
  • Vapor DensityNo data available (Air = 1.0)
  • Specific Gravity / Density1.352
  • Bulk DensityNot applicable Liquid
  • Water SolubilityInsoluble
  • Solubility in other solventsChloroform (Sparingly, Heated), Methanol (Slightly)
  • Partition Coefficient (n-octanol/water)No data available
  • Autoignition TemperatureNo data available
  • Decomposition TemperatureNo data available
  • ViscosityNo data available
  • Explosive PropertiesNo information available
  • Oxidizing PropertiesNo information available
  • Molecular FormulaC12 H9 Br
  • Molecular Weight233.11

SECTION 10: Stability and reactivity

Stability

Stable under normal conditions.

Hazardous Reactions

No information available.

Hazardous Polymerization

Hazardous polymerization does not occur.

Conditions to Avoid

Incompatible products.

Materials to avoid

Strong oxidizing agents.

Hazardous Decomposition Products

Carbon monoxide (CO). Carbon dioxide (CO2). Hydrogen halides.

SECTION 11: Toxicological information

Product Information

No acute toxicity information is available for this product

(a) acute toxicity;

(b) skin corrosion/irritation;

Category 2

(c) serious eye damage/irritation;

Category 2

(d) respiratory or skin sensitization;

Respiratory
No data available
Skin
No data available

(e) germ cell mutagenicity;

No data available

(f) carcinogenicity;

No data available
There are no known carcinogenic chemicals in this product

(g) reproductive toxicity;

No data available

(h) STOT-single exposure;

Category 3
Results / Target organs
Respiratory system

(i) STOT-repeated exposure;

No data available
Target Organs
No information available.

(j) aspiration hazard;

No data available

Other Adverse Effects

The toxicological properties have not been fully investigated.

Symptoms / effects,both acute and delayed

Inhalation of high vapor concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting

SECTION 12: Ecological information

Ecotoxicity effects

Do not empty into drains.

Persistence and Degradability

No information available

Bioaccumulative Potential

No information available

Mobility in soil

No information available

Endocrine Disruptor Information

This product does not contain any known or suspected endocrine disruptors

Persistent Organic Pollutant

This product does not contain any known or suspected substance

Ozone Depletion Potential

This product does not contain any known or suspected substance

SECTION 13: Disposal considerations

Waste from Residues/Unused Products

Waste is classified as hazardous. Dispose of in accordance with the European Directives on waste and hazardous waste. Dispose of in accordance with local regulations.

Contaminated Packaging

Dispose of this container to hazardous or special waste collection point.

Other Information

Waste codes should be assigned by the user based on the application for which the product was used. Do not empty into drains.

SECTION 14: Transport information

Road and Rail Transport

Not Regulated

IMDG/IMO

Not regulated

IATA

Not regulated

Special Precautions for User

No special precautions required

SECTION 15: Regulatory information

International Inventories

X = listed, China (IECSC), Europe (EINECS/ELINCS/NLP), U.S.A. (TSCA), Canada (DSL/NDSL), Philippines (PICCS), Japan (ENCS), Japan (ISHL), Australia (AICS), Korea (KECL).
ComponentThe
Inventory of
Hazardous
Chemicals (2015
Edition)
List of dangerous goods GB 12268 - 2012TCSIIECSCEINECSTSCADSLPICCSENCSISHLAICSKECL
1,1'-Biphenyl, 2-bromo---X-218-141-3X--XX--

National Regulations

SECTION 16: Other information

Revision Summary

Not applicable.

Training Advice

Chemical hazard awareness training, incorporating labelling, Safety Data Sheets (SDS), Personal Protective Equipment (PPE) and hygiene.
Use of personal protective equipment, covering appropriate selection, compatibility, breakthrough thresholds, care, maintenance, fit and standards.
First aid for chemical exposure, including the use of eye wash and safety showers.
Chemical incident response training.

Legend

CAS
Chemical Abstracts Service
TSCA
United States Toxic Substances Control Act Section 8(b)
Inventory
EINECS/ELINCS
European Inventory of Existing Commercial Chemical
Substances/EU List of Notified Chemical Substances
DSL/NDSL
Canadian Domestic Substances List/Non-Domestic
Substances List
PICCS
Philippines Inventory of Chemicals and Chemical Substances
ENCS
Japanese Existing and New Chemical Substances
IECSC
Chinese Inventory of Existing Chemical Substances
AICS
Australian Inventory of Chemical Substances
KECL
Korean Existing and Evaluated Chemical Substances
NZIoC
New Zealand Inventory of Chemicals
WEL
Workplace Exposure Limit
TWA
Time Weighted Average
ACGIH
American Conference of Governmental Industrial Hygienists
IARC
International Agency for Research on Cancer
DNEL
Derived No Effect Level
PNEC
Predicted No Effect Concentration
RPE
Respiratory Protective Equipment
LD50
Lethal Dose 50%
LC50
Lethal Concentration 50%
EC50
Effective Concentration 50%
NOEC
No Observed Effect Concentration
POW
Partition coefficient Octanol:Water
PBT
Persistent, Bioaccumulative, Toxic
vPvB
very Persistent, very Bioaccumulative
ICAO/IATA
International Civil Aviation Organization/International Air
Transport Association
IMO/IMDG
International Maritime Organization/International Maritime
Dangerous Goods Code
ADR
European Agreement Concerning the International Carriage of
Dangerous Goods by Road
MARPOL
International Convention for the Prevention of Pollution from
Ships
OECD
Organisation for Economic Co-operation and Development
ATE
Acute Toxicity Estimate
BCF
Bioconcentration factor
VOC
(Volatile Organic Compound)

Key literature references and sources for data

https://echa.europa.eu/information-on-chemicals
Suppliers safety data sheet, Chemadvisor - LOLI, Merck index, RTECS

Disclaimer

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text
Disclaimer:

The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.

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