Chemical Safety Data Sheet MSDS / SDS
GADOLEICACID
Revision Date:2026-03-20Revision Number:1
Product identifier
- Product name: GADOLEICACID
- CBnumber: CB91445223
- CAS: 29204-02-2
- Synonyms: Z-9-Eicosenoic acid;cis-9-Icosenoic acid
Relevant identified uses of the substance or mixture and uses advised against
- Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
- Uses advised against: none
Company Identification
- Company: Chemicalbook
- Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
- Telephone: 010-86108875
GHS Label elements, including precautionary statements
-
Symbol(GHS)
- Signal wordDanger
No data available
Hazard statements
No data available
Substance
- Product name: GADOLEICACID
- Synonyms: Z-9-Eicosenoic acid;cis-9-Icosenoic acid
- CAS: 29204-02-2
- MF: C20H38O2
- MW: 310.51
Description of first aid measures
General information
Immediately remove any clothing soiled by the product.
After inhalation
Supply fresh air; consult doctor in case of complaints.
After skin contact
Immediately rinse with water.
After eye contact
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing
If symptoms persist consult doctor.
Information for doctor
Most important symptoms and effects, both acute and delayed
No further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
Extinguishing media
Suitable extinguishing agents
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards arising from the substance or mixture
Can release vapors that form explosive mixtures at temperatures at or above the flashpoint.
Container explosion may occur under fire conditions.
Emits toxic fumes under fire conditions.
Sensitive to static discharge.
Vapors can travel to a source of ignition and flash back.
Container explosion may occur under fire conditions.
Emits toxic fumes under fire conditions.
Sensitive to static discharge.
Vapors can travel to a source of ignition and flash back.
Advice for firefighters
Protective equipment
No special measures required.
NFPA 704
0
3
0
| HEALTH | 0 | Poses no health hazard, no precautions necessary and would offer no hazard beyond that of ordinary combustible materials | |
| FIRE | 3 | Liquids and solids (including finely divided suspended solids) that can be ignited under almost all ambient temperature conditions . Liquids having a flash point below 22.8 °C (73 °F) and having a boiling point at or above 37.8 °C (100 °F) or having a flash point between 22.8 and 37.8 °C (73 and 100 °F). (e.g. gasoline, acetone) | |
| REACT | 0 | Normally stable, even under fire exposure conditions, and is not reactive with water (e.g. helium,N2) | |
| SPEC. HAZ. |
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Environmental precautions
Dilute with plenty of water.
Do not allow to enter sewers/ surface or ground water.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to section 13.
Ensure adequate ventilation.
Dispose contaminated material as waste according to section 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1
64-17-5 ethanol 1,800 ppm
PAC-2
64-17-5 ethanol 3300* ppm
PAC-3
64-17-5 ethanol 15000* ppm
Handling
Precautions for safe handling
No special precautions are necessary if used correctly.
Avoid breathing dust/fume/gas/mist/vapours/spray.
Avoid prolonged or repeated exposure.
Keep away from sources of ignition.
Take precautionary measures against static discharge.re.
Avoid breathing dust/fume/gas/mist/vapours/spray.
Avoid prolonged or repeated exposure.
Keep away from sources of ignition.
Take precautionary measures against static discharge.re.
Information about protection against explosions and fires
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Protect against electrostatic charges.
Conditions for safe storage, including any incompatibilities
Keep container tightly closed.
Store in accordance with information listed on the product insert.
Store in accordance with information listed on the product insert.
Storage
Store in accordance with information listed on the product insert.
Requirements to be met by storerooms and receptacles
Store in a cool location.
Information about storage in one common storage facility
Not required.
Further information about storage conditions
Keep receptacle tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
Store in cool, dry conditions in well sealed receptacles.
Specific end use(s)
No further relevant information available.
Additional information about design of technical systems
No further data; see section 7.
Control parameters
Components with limit values that require monitoring at the workplace:
| 64-17-5 ethanol | |
|---|---|
| PEL | Long-term value: 1900 mg/m³, 1000 ppm |
| REL | Long-term value: 1900 mg/m³, 1000 ppm |
| TLV | Short-term value: 1000 ppm A3 |
Additional information
The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment
General protective and hygienic measures
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Breathing equipment
Not required.
Protection of hands
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
Eye protection
Tightly sealed goggles
Information on basic physicochemical properties
- Physical StateLiquid
- ColorAccording to product specification
- OdorCharacteristic
- Structural FormulaC20H38O2
- Molecular Weight310.5 g/mol
- Odor ThresholdNot determined.
- Explosion limitsLower: 3.3 Vol %
Upper: 19 Vol % - Vapor Pressure at 20 °C (68 °F)59 hPa (44.3 mm Hg)
- Vapor Pressure at 50 °C (122 °F)280 hPa (210 mm Hg)
- Density at 20 °C (68 °F)0.79 g/cm³ (6.59255 lbs/gal)
- Relative Density0.8882
- Danger of explosionProduct is not explosive. However, formation of explosive air/ vapor mixtures are possible.
- Ignition temperatureProduct is not selfigniting.
- Decomposition temperatureNot determined.
- Auto igniting425 °C (797 °F)
- Flammability (solid,gas)Highly flammable.
- Flash point13 °C (55.4 °F)
- Boiling point/Boiling range78 °C (172.4 °F)
- Melting point/Melting range-114 °C (-173.2 °F)
- pHNot determined.
- FormulationA solution in ethanol
- Other informationNo information available
- Solids content0.0 %
- VOC content99.00 % 782.1 g/l / 6.53 lb/gal
- Organic solvents99.0 %
- SOLUBILITYEthanol: soluble
- KinematicNot determined.
- Dynamicat 20 °C (68 °F): 1.2 mPas
- Partition coefficient (n-octanol/water)Not determined.
- Water at 20 °C (68 °F)1,000 g/l
- Solubility in / Miscibility withEthanol: soluble
- Evaporation RateNot determined.
- Vapor DensityNot determined.
Reactivity
No further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided
No decomposition if used according to specifications.
Possibility of hazardous reactions
No dangerous reactions known.
Conditions to avoid
No further relevant information available.
Incompatible materials
No further relevant information available.
Hazardous decomposition products
No dangerous decomposition products known.
Information on toxicological effects
Acute toxicity
LD/LC50 values that are relevant for classification:
| Substance / Estimate | Route | Endpoint | Value |
|---|---|---|---|
| 64-17-5 ethanol | Oral | LD50 | 10,470 mg/kg (rat) OECD Test Guideline 401 |
| 64-17-5 ethanol | Inhalative | LC50/4 h | 117–125 mg/l (rat) OECD 403 (rat) |
Primary irritant effect
on the skin
No irritant effect.
on the eye
Irritating effect.
Sensitization
No sensitizing effects known.
Additional toxicological information
The product shows the following dangers according to internally approved calculation methods for preparations
Irritant
Irritant
Carcinogenic categories
IARC (International Agency for Research on Cancer)
64-17-5 ethanol 1
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
Toxicity
Aquatic toxicity
No further relevant information available.
Persistence and degradability
No further relevant information available.
Behavior in environmental systems
Bioaccumulative potential
No further relevant information available.
Mobility in soil
No further relevant information available.
Additional ecological information
General notes
Water hazard class 1 (Self-assessment) slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
Results of PBT and vPvB assessment
PBT
Not applicable.
vPvB
Not applicable.
PBT:
Not applicable.
vPvB:
Not applicable.
Other adverse effects
No further relevant information available.
Waste treatment methods
Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings
Recommendation
Disposal must be made according to official regulations.
Recommended cleansing agent
Water, if necessary with cleansing agents.
UN-Number
DOT, IMDG, IATA UN1170
UN proper shipping name
DOT Ethanol solutions
IMDG ETHANOL SOLUTION (ETHYL ALCOHOL
SOLUTION)
IATA Ethanol solution
IMDG ETHANOL SOLUTION (ETHYL ALCOHOL
SOLUTION)
IATA Ethanol solution
Transport hazard class(es)
DOTClass: 3 Flammable liquids
Label: 3
IMDG, IATA
Label: 3
Class: 3 Flammable liquids
Label: 3
Label: 3
Packing group
DOT, IMDG, IATA II
Environmental hazards
Not applicable.
Special precautions for user
Warning: Flammable liquids
Hazard identification number (Kemler code)
33
EMS Number
F-E,S-D
Stowage Category
A
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
Transport/Additional information
DOT:
Quantity limitations
On passenger aircraft/rail: 5 L
On cargo aircraft only: 60 L
On cargo aircraft only: 60 L
IMDG:
Limited quantities (LQ)
1L
Excepted quantities (EQ)
Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
IATA:
Remarks
When sold in quantities of less than or equal to 1 mL, or 1 g, with an Excepted Quantity Code of
E1, E2, E4, or E5, this item meets the De Minimis
Quantities exemption, per IATA 2.6.10.
Therefore packaging does not have to be labeled as
Dangerous Goods/Excepted Quantity.
E1, E2, E4, or E5, this item meets the De Minimis
Quantities exemption, per IATA 2.6.10.
Therefore packaging does not have to be labeled as
Dangerous Goods/Excepted Quantity.
UN "Model Regulation"
UN 1170 ETHANOL SOLUTION (ETHYL ALCOHOL
SOLUTION), 3, II
SOLUTION), 3, II
Safety, health and environmental regulations/legislation specific for the substance or mixture
No further relevant information available.
Sara
| Section 355 (extremely hazardous substances): | None of the ingredients is listed. |
| Section 313 (Specific toxic chemical listings): | None of the ingredients is listed. |
| TSCA (Toxic Substances Control Act): | 64-17-5 ethanol ACTIVE |
| Hazardous Air Pollutants: | None of the ingredients is listed. |
Proposition 65
| Chemicals known to cause cancer: | None of the ingredients is listed. |
| Chemicals known to cause reproductive toxicity for females: | None of the ingredients is listed. |
| Chemicals known to cause reproductive toxicity for males: | None of the ingredients is listed. |
| Chemicals known to cause developmental toxicity: | 64-17-5 ethanol |
Carcinogenic categories
| EPA (Environmental Protection Agency): | None of the ingredients is listed. |
| TLV (Threshold Limit Value): | 64-17-5 ethanol A3 |
| NIOSH-Ca (National Institute for Occupational Safety and Health): | None of the ingredients is listed. |
Chemical safety assessment
A Chemical Safety Assessment has not been carried out.
Abbreviations and acronyms
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Flammable Liquids 2: Flammable liquids – Category 2
Eye Irritation 2A: Serious eye damage/eye irritation – Category 2A
DOT: US Department of Transportation
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Flammable Liquids 2: Flammable liquids – Category 2
Eye Irritation 2A: Serious eye damage/eye irritation – Category 2A
Disclaimer:
The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.