Chemical Safety Data Sheet MSDS / SDS
Mancozeb
Revision Date:2026-03-21Revision Number:1
Product identifier
- Product name: Mancozeb
- CBnumber: CB0290308
- CAS: 8018-01-7
- EINECS Number: 616-995-5
- Synonyms: ((1,2-Ethanediylbis(carbamodithioato)))manganese mixture with ((1,2-ethandiylbis(carbamodithioate)))zinc
Relevant identified uses of the substance or mixture and uses advised against
- Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
- Uses advised against: none
Company Identification
- Company: Chemicalbook
- Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
- Telephone: 010-86108875
GHS Label elements, including precautionary statements
-
Symbol(GHS)
- Signal wordDanger
P501 Dispose of contents/container to..…
P391 Collect spillage. Hazardous to the aquatic environment
P273 Avoid release to the environment.
P501 Dispose of contents/container to..…
P314 Get medical advice/attention if you feel unwell.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P501 Dispose of contents/container to..…
P405 Store locked up.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P281 Use personal protective equipment as required.
P202 Do not handle until all safety precautions have been read and understood.
P201 Obtain special instructions before use.
P501 Dispose of contents/container to..…
P363 Wash contaminated clothing before reuse.
P321 Specific treatment (see … on this label).
P333+P313 IF SKIN irritation or rash occurs: Get medical advice/attention.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P272 Contaminated work clothing should not be allowed out of the workplace.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
Hazard statements
H410 Very toxic to aquatic life with long lasting effects
H373 May cause damage to organs through prolonged or repeated exposure
H351 Suspected of causing cancer
H317 May cause an allergic skin reaction
Substance
- Product name: Mancozeb
- Synonyms: ((1,2-Ethanediylbis(carbamodithioato)))manganese mixture with ((1,2-ethandiylbis(carbamodithioate)))zinc
- CAS: 8018-01-7
- EC number: 616-995-5
- MF: C4H8MnN2S4Zn
- MW: 332.71
First Aid Measures
General adviceIf symptoms persist, call a physician. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing.
Eye contact
Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Keep eye wide open while rinsing. If symptoms persist, call a physician.
Skin Contact
Consult a physician if necessary. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Wash off immediately with soap and plenty of water.
Inhalation
Remove to fresh air If breathing is irregular or stopped, administer artificial respiration Avoid direct contact with skin. Use barrier to give mouth-to-mouth resuscitation Call a physician
Ingestion
Do NOT induce vomiting. Drink plenty of water. If symptoms persist, call a physician. Rinse mouth.
Self-protection of the first aider
Use personal protective equipment as required.
Most important symptoms and effects, both acute and delayed
SymptomsNo information available.
Indication of any immediate medical attention and special treatment needed
Note to physiciansMay cause sensitization of susceptible persons.
Suitable Extinguishing Media
Suitable Extinguishing MediaUse extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable Extinguishing Media
No information available.
Specific hazards arising from the chemical
Specific hazards arising from the chemicalIn the event of fire and/or explosion do not breathe fumes. May cause sensitization by inhalation and skin contact. Thermal decomposition can lead to release of irritating and toxic gases and vapors.
Hazardous combustion products
Hydrogen sulfide. Carbon oxides. Nitrogen oxides (NOx).
Explosion data
Sensitivity to Mechanical ImpactNo information available.
Sensitivity to Static Discharge
No information available.
Protective equipment and precautions for firefighters
Protective equipment and precautions for firefightersAs in any fire, wear self contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
Personal precautions, protective equipment and emergency procedures
Personal precautionsAvoid contact with skin, eyes or clothing. Use personal protective equipment as required.
Environmental precautions
Environmental precautionsPrevent entry into waterways, sewers, basements or confined areas. Do not flush into surface water or sanitary sewer system. See Section 12 for additional Ecological
Information. Prevent product from entering drains. Should not be released into the environment.
Information. Prevent product from entering drains. Should not be released into the environment.
Methods and material for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so.
Methods for cleaning up
Use personal protective equipment as required. Take up mechanically, placing in appropriate containers for disposal. Clean contaminated surface thoroughly. Cover powde spill with plastic sheet or tarp to minimize spreading and keep powder dry. Avoid creating dust. Soak up with inert absorbent material.
Precautions for safe handling
Advice on safe handlingAvoid contact with skin, eyes or clothing. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Use personal protective equipment as required. Do not breathe dust/fume/gas/mist/vapors/spray.
Conditions for safe storage, including any incompatibilities
Storage ConditionsKeep container tightly closed in a dry and well-ventilated place. Keep out of the reach of children. Keep containers tightly closed in a cool, well-ventilated place. Store at 4 °C.
Incompatible materials
None known based on information supplied.
Control parameters
Exposure Guidelines.
Other Information
Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992).
| Column 1 | Column 2 | Column 3 | Column 4 |
|---|---|---|---|
| Mancozeb 8018-01-7 | - | (vacated) Ceiling: 5 mg/m3 Ceiling: 5 mg/m3 Mn | IDLH: 500 mg/m3 Mn TWA: 1 mg/m3 Mn STEL: 3 mg/m3 Mn |
Appropriate engineering controls
Engineering ControlsShowers
Eyewash stations
Ventilation systems
Eyewash stations
Ventilation systems
Individual protection measures, such as personal protective equipment
Eye/face protectionTight sealing safety goggles.
Skin and Body Protection
Wear protective gloves and protective clothing.
Respiratory protection
If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations.
General Hygiene Considerations
When using do not eat, drink or smoke. Wash contaminated clothing before reuse.
Information on basic physicochemical properties
- Physical StateSolid
- AppearanceNo information available
- OdorNo information available
- pHNo information available
- Melting point/freezing pointNo information available
- Boiling pointNo information available
- Flash point138 °C
- Liquid DensityNo information available
- Evaporation rateNo information available
- Upper flammability limitsNo information available
- Lower flammability limitNo information available
- Vapor pressureNegligible at 20 °C
- Vapor densityNo information available
- Specific gravityNo information available
- Water solubility6-20 mgl-1 (20 °C)
- Solubility in other solventsNo information available
- Partition coefficient1.33
- Autoignition temperatureNo information available
- Decomposition temperatureNo information available
- Kinematic viscosityNo information available
- Explosive propertiesNo information available
- Oxidizing propertiesNo information available
- Density and/or relative density1.92 g/cm3
- SolubilityDMSO: 1 mg/mL (1.51 mM); Water: < 0.1 mg/mL (insoluble)
- ColourLight yellow to yellow
Reactivity
Not applicable
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Hazardous polymerization
No information available.
Conditions to avoid
Extremes of temperature and direct sunlight.
Incompatible materials
Strong oxidizing agents.
Hazardous Decomposition Products
Hydrogen sulfide. Carbon oxides. Nitrogen oxides (NOx).
Information on likely routes of exposure
InhalationClassified based on available data. For more details, see section 2.
Eye contact
Classified based on available data. For more details, see section 2.
Skin Contact
Classified based on available data. For more details, see section 2.
Ingestion
Classified based on available data. For more details, see section 2.
Information on toxicological effects
SymptomsClassified based on available data. For more details, see section 2.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Chronic ToxicityRepeated contact may cause allergic reactions in very susceptible persons. Avoid repeated exposure. May cause adverse effects on the bone marrow and blood-forming system. Target Organ Effects Blood, Central nervous system, Respiratory system, Kidney.
Numerical measures of toxicity - Product Information
Unknown acute toxicityClassified based on available data. For more details, see section 2
The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (oral)
The following values are calculated based on chapter 3.1 of the GHS document
5000 mg/kg
ATEmix (dermal)
5005 mg/kg
Ecotoxicity
Very toxic to aquatic life with long lasting effects
0% of the mixture consists of components(s) of unknown hazards to the aquatic environment.
| Chemical name | Algae/aquatic plants | Fish | Toxicity to Microorganisms | Crustacea |
|---|---|---|---|---|
| Mancozeb 8018-01-7 | - | 1: 48 h Lepomis macrochirus mg/L LC50 | - | - |
Mancozeb -
1: 48 h Lepomis macrochirus - -
Persistence and degradability
No information available.
Bioaccumulation
No information available.
Mobility
No information available.
Disposal of wastes
Disposal should be in accordance with applicable regional, national and local laws and regulations. Should not be released into the environment.
Contaminated packaging
Do not reuse container.
Other Information
Waste codes should be assigned by the user based on the application for which the product was used.
California Hazardous Waste Status
This product contains one or more substances that are listed with the State of California as a hazardous waste.
| Chemical name | California Hazardous Waste Status |
|---|---|
| Mancozeb 8018-01-7 | Toxic |
DOT
UN/ID noUN3077
Hazard Class
9
Packing Group
III
Proper shipping name
Environmentally hazardous substance, solid, n.o.s.
Description
UN3077, Environmentally hazardous substance, solid, n.o.s. (Mancozeb), 9, III, Marine pollutant Marine pollutant This product contains a chemical which is listed as a marine pollutant according to DOT
Emergency Response Guide Number
171
IMDG
UN/ID noUN3077
Hazard Class
9
Packing Group
III
Proper shipping name
Environmentally hazardous substance, solid, n.o.s.
Description
UN3077, Environmentally hazardous substance, solid, n.o.s. (Mancozeb), 9, III, Marine pollutant
Special Provisions
274, 335, 966, 967, 969
EmS-No
F-A, S-F Marine pollutant This product contains a chemical which is listed as a marine pollutant according to IMDG/IMO
IATA
UN/ID noUN3077
Hazard Class
9
Packing Group
III
Proper shipping name
Environmentally hazardous substance, solid, n.o.s.
Description
UN3077, Environmentally hazardous substance, solid, n.o.s. (Mancozeb), 9, III
ERG Code
9L
International Inventories
All of the components in the product are on the following Inventory lists
Australia (AICS) South Korea (KECL): China (IECSC) ENCS (Japan): Philippines (PICCS)
X - Listed
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
Australia (AICS) South Korea (KECL): China (IECSC) ENCS (Japan): Philippines (PICCS)
X - Listed
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
| Chemical name | TSCA | DSL | NDSL | EINECS | ELINCS | ENCS | IECSC | KECL | PICCS | AICS |
|---|---|---|---|---|---|---|---|---|---|---|
| Mancozeb | - | - | - | - | - | X | X | X | X | X |
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
SARA 311/312 Hazard Categories
Acute health hazardYes
Chronic Health Hazard
Yes
Fire hazard
No
Sudden release of pressure hazard
No
Reactive hazard
No
CWA (Clean Water Act)
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42).
| Chemical name | CWA - Reportable Quantities | CWA - Toxic Pollutants | CWA - Priority Pollutants | CWA - Hazardous Substances |
|---|---|---|---|---|
| Mancozeb 8018-01-7 | X |
US State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals.
| Chemical name California Proposition 65 |
|---|
| Chemical name |
| Mancozeb - 8018-01-7 |
U.S. State Right-to-Know Regulations
| Chemical name | New Jersey | Massachusetts | Pennsylvania |
|---|---|---|---|
| Mancozeb 8018-01-7 | X | Not Listed | X |
Abbreviations and acronyms
CAS: Chemical Abstracts Service
TWA: Time-Weighted Average
STEL: Short-Term Exposure Limit
LD50: Lethal Dose 50%
LC50: Lethal Concentration 50%
EC50: Effective Concentration 50%
PEL: Permissible Exposure Limit
TLV: Threshold Limit Value
IMDG: International Maritime Dangerous Goods Code
IATA: International Air Transport Association
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
DOT: US Department of Transportation
NFPA: National Fire Protection Association
NIOSH: National Institute for Occupational Safety and Health
OSHA: Occupational Safety and Health Administration
TWA: Time-Weighted Average
STEL: Short-Term Exposure Limit
LD50: Lethal Dose 50%
LC50: Lethal Concentration 50%
EC50: Effective Concentration 50%
PEL: Permissible Exposure Limit
TLV: Threshold Limit Value
IMDG: International Maritime Dangerous Goods Code
IATA: International Air Transport Association
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
DOT: US Department of Transportation
NFPA: National Fire Protection Association
NIOSH: National Institute for Occupational Safety and Health
OSHA: Occupational Safety and Health Administration
Disclaimer:
The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.