Chemical Safety Data Sheet MSDS / SDS
Methyl Iodide-13C,d2
Revision Date:2026-03-21Revision Number:1
Product identifier
- Product name: Methyl Iodide-13C,d2
- CBnumber: CB22102072
- CAS: 207507-22-0
- Synonyms: Iodomethane-13C,d2;Iodomethane-<sup>13</sup>C,d<sub>2</sub>
Relevant identified uses of the substance or mixture and uses advised against
- Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
- Uses advised against: none
Company Identification
- Company: Chemicalbook
- Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
- Telephone: 010-86108875
GHS Label elements, including precautionary statements
-
Symbol(GHS)
- Signal wordDanger
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P202 Do not handle until all safety precautions have been read and understood.
Hazard statements
H351 Suspected of causing cancer
H335 May cause respiratory irritation
H315 Causes skin irritation
H312 Harmful in contact with skin
Substance
- Product name: Methyl Iodide-13C,d2
- Synonyms: Iodomethane-13C,d2;Iodomethane-<sup>13</sup>C,d<sub>2</sub>
- CAS: 207507-22-0
- MF: H13CD2I
General advice
First aiders need to protect themselves. Show this safety data sheet to the doctor in attendance.
If inhaled
After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.
In case of skin contact
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician.
In case of eye contact
After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.
If swallowed
If swallowed: give water to drink (two glasses at most). Seek medical advice immediately. In exceptional cases only, if medical care is not available within one hour, induce vomiting (only in persons who are wide awake and fully conscious), administer activated charcoal (20 - 40 g in a 10% slurry) and consult a doctor as quickly as possible.
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11
Protection of first-aiders
For personal protection see section 8.
Notes to physician
No data available
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media
For this substance/mixture no limitations of extinguishing agents are given.
Specific hazards during fire fighting
Not combustible. Ambient fire may liberate hazardous vapours.
Hazardous combustion products
Carbon oxides Hydrogen iodide
Specific extinguishing methods
Suppress (knock down) gases/vapours/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.
Special protective equipment for fire-fighters
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel: Do not breathe vapours, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: For personal protection see section 8.
Environmental precautions
Do not let product enter drains.
Methods and materials for containment and cleaning up
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully with liquid-absorbent material . Dispose of properly. Clean up affected area.
Handling
Advice on safe handlingWork under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.
Avoidance of contact
Strong oxidizing agents Strong bases Oxygen
Storage
Further information on storage conditionsTightly closed. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorised persons.
Storage class
6.1B, Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
Recommended storage temperature
2 - 8 °C
Packaging material
Suitable material: Amber Glass Bottle/Jar
control parameter
Hazard composition and occupational exposure limitsDoes not contain substances with occupational exposure limits.
Engineering measures
No data available
Personal protective equipment
Respiratory protectionrequired when vapours/aerosols are generated.
Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.
Recommended Filter type
Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.
Filter type AX
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
Eye/face protection
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Safety glasses
Skin and body protection
Safety glasses
protective clothing
Hand protection
Material
Fluorinated rubber
Break through time
480 min
Glove thickness
0.7 mm
Protective index
Full contact
Manufacturer
Vitoject® (KCL 890 / Aldrich Z677698, Size M)
Material
Fluorinated rubber
Break through time
480 min
Glove thickness
0.7 mm
Protective index
Splash contact
Manufacturer
Vitoject® (KCL 890 / Aldrich Z677698, Size M)
Manufacturer
data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method: EN374
Remarks
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.
If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.
Hygiene measures
The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.
If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
Information on basic physicochemical properties
- OdorNo data available
- ColorNo data available
- Appearanceliquid
- Particle characteristics Particle sizeNo data available
- Molecular weight144.89 g/mol
- Oxidizing propertiesNo data available
- Explosive propertiesNo data available
- Flow timeNo data available
- Viscosity, kinematicNo data available
- Viscosity, dynamicNo data available
- Decomposition temperatureNo data available
- Autoignition temperatureNot applicable
- Partition coefficient: n-octanol/waterNo data available
- Water solubilityNo data available
- Density2.327 g/mL (25 °C) 2.327 g/cm3 (25 °C)
- Relative density2.327 g/mL at 25 °C
- Relative vapor densityNo data available
- Vapor pressureNo data available
- Lower explosion limit / Lower flammability limitNot applicable
- Upper explosion limit / Upper flammability limitNot applicable
- Self-ignitionNot applicable
- Burning rateNo data available
- Flammability (liquids)The product is not flammable.
- Flammability (solid, gas)No data available
- Evaporation rateNo data available
- Flash pointNo data available
- Boiling point/boiling range42 °C
Method: lit. - Melting point/ range-66.5 °C
- pHNo data available
- Odor ThresholdNo data available
Reactivity
No data available
Chemical stability
The product is chemically stable under standard ambient conditions (room temperature) .
Possibility of hazardous reactions
May discolor on exposure to light.
Conditions to avoid
no information available
Incompatible materials
Strong oxidizing agents Strong bases Oxygen
Hazardous decomposition products
In the event of fire: see section 5
11.1 Information on toxicological effects
Mixture Acute toxicityOral: No data available
Symptoms: mucosal irritations, Cough, Shortness of breath, Possible damages:, damage of respiratory tract
Dermal: No data available
Skin corrosion/irritation
Symptoms: mucosal irritations, Cough, Shortness of breath, Possible damages:, damage of respiratory tract
Dermal: No data available
Remarks: Mixture causes skin irritation.
Serious eye damage/eye irritation
Classified based on available data. For more details, see section 2
Respiratory or skin sensitization
Classified based on available data. For more details, see section 2
Germ cell mutagenicity
Classified based on available data. For more details, see section 2
Carcinogenicity
Evidence of a carcinogenic effect.
Reproductive toxicity
Classified based on available data. For more details, see section 2
Specific target organ toxicity - single exposure
Mixture may cause respiratory irritation.
Specific target organ toxicity - repeated exposure
Classified based on available data. For more details, see section 2
Aspiration hazard
Classified based on available data. For more details, see section 2
11.2 Additional Information
Nausea, Dizziness, Headache, Blurred vision, Weakness, Drowsiness, Ataxia., Con- fusion., Convulsions, narcosis, Pulmonary edema. Effects may be delayed., Symp- toms of systemic copper poisoning may include: capillary damage, headache, cold sweat, weak pulse, and kidney and liver damage, central nervous system excitation followed by depression, jaundice, convulsions, paralysis, and coma. Death may oc- cur from shock or renal failure. Chronic copper poisoning is typified by hepatic cir- rhosis, brain damage and demyelination, kidney defects, and copper deposition in the cornea as exemplified by humans with Wilson's disease. It has also been re- ported that copper poisoning has lead to hemolytic anemia and accelerates arterio- sclerosis.
Other dangerous properties can not be excluded.
This substance should be handled with particular care.
Handle in accordance with good industrial hygiene and safety practice.
Components Iodomethane-13C,d2
Other dangerous properties can not be excluded.
This substance should be handled with particular care.
Handle in accordance with good industrial hygiene and safety practice.
Acute toxicity
LD50 Oral - Rat - male and female - 79.84 mg/kg (OECD Test Guideline 401)
Remarks: The value is given in analogy to the following substances: iodome- thane
LC50 Inhalation - Rat - male and female - 4 h - 4.076 mg/l - vapour (US-EPA)
Remarks: The value is given in analogy to the following substances: iodome- thane
Acute toxicity estimate Dermal - 1,100.1 mg/kg (Expert judgement)
Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
The value is given in analogy to the following substances: iodomethane
Remarks: The value is given in analogy to the following substances: iodome- thane
LC50 Inhalation - Rat - male and female - 4 h - 4.076 mg/l - vapour (US-EPA)
Remarks: The value is given in analogy to the following substances: iodome- thane
Acute toxicity estimate Dermal - 1,100.1 mg/kg (Expert judgement)
Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
The value is given in analogy to the following substances: iodomethane
Skin corrosion/irritation
Skin - Rabbit
Result: Irritations - 4 h (OECD Test Guideline 404)
Remarks: The value is given in analogy to the following substances: iodome- thane
Remarks: (Regulation (EC) No 1272/2008, Annex VI)
Result: Irritations - 4 h (OECD Test Guideline 404)
Remarks: The value is given in analogy to the following substances: iodome- thane
Remarks: (Regulation (EC) No 1272/2008, Annex VI)
Serious eye damage/eye irritation
Eyes - Rabbit
Result: Eye irritation (OECD Test Guideline 405)
Remarks: The value is given in analogy to the following substances: iodome- thane
Result: Eye irritation (OECD Test Guideline 405)
Remarks: The value is given in analogy to the following substances: iodome- thane
Respiratory or skin sensitization
Maximisation Test - Guinea pig
Result: negative (OECD Test Guideline 406)
Remarks: The value is given in analogy to the following substances: iodome- thane
Result: negative (OECD Test Guideline 406)
Remarks: The value is given in analogy to the following substances: iodome- thane
Germ cell mutagenicity
Test Type: Chromosome aberration test in vitro
Test system: Chinese hamster ovary cells
Result: negative
Remarks: The value is given in analogy to the following substances: iodome- thane
Test Type: Ames test
Test system: Escherichia coli/Salmonella typhimurium
Result: negative
Remarks: The value is given in analogy to the following substances: iodome- thane
Test Type: In vitro mammalian cell gene mutation test
Test system: Chinese hamster ovary cells
Result: positive
Remarks: The value is given in analogy to the following substances: iodome- thane
Method: US-EPA
Species: Mouse - male and female - Bone marrow
Result: negative
Remarks: The value is given in analogy to the following substances: iodome- thane
Carcinogenicity
Test system: Chinese hamster ovary cells
Result: negative
Remarks: The value is given in analogy to the following substances: iodome- thane
Test Type: Ames test
Test system: Escherichia coli/Salmonella typhimurium
Result: negative
Remarks: The value is given in analogy to the following substances: iodome- thane
Test Type: In vitro mammalian cell gene mutation test
Test system: Chinese hamster ovary cells
Result: positive
Remarks: The value is given in analogy to the following substances: iodome- thane
Method: US-EPA
Species: Mouse - male and female - Bone marrow
Result: negative
Remarks: The value is given in analogy to the following substances: iodome- thane
Suspected of causing cancer.
Reproductive toxicity
Classified based on available data. For more details, see section 2
Specific target organ toxicity - single exposure
Inhalation - May cause respiratory irritation. - Respiratory system
Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
The value is given in analogy to the following substances: iodomethane
Specific target organ toxicity - repeated exposure Aspiration hazard
Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
The value is given in analogy to the following substances: iodomethane
Classified based on available data. For more details, see section 2
Ecotoxicity
Components:
Iodomethane-13C,d2:
Toxicity to fishLC50 (Oncorhynchus mykiss (rainbow trout)): 1.4 mg/l End point: mortality Exposure time: 96 h Test Type: semi-static test Analytical monitoring: yes Method: OECD Test Guideline 203 GLP: yes Remarks: The value is given in analogy to the following substances: The value is given in analogy to the following substances: iodomethane NOEC (Oncorhynchus mykiss (rainbow trout)): 0.62 mg/l End point: mortality Exposure time: 96 h Test Type: semi-static test Analytical monitoring: yes Method: OECD Test Guideline 203 GLP: yes Remarks: The value is given in analogy to the following substances: The value is given in analogy to the following substances: iodomethane
Toxicity to daphnia and other aquatic invertebrates
EC50 (Daphnia magna (Water flea)): 0.57 mg/l End point: Immobilization Exposure time: 48 h Test Type: static test Analytical monitoring: yes Method: OECD Test Guideline 202 GLP: yes Remarks: The value is given in analogy to the following substances: The value is given in analogy to the following substances: iodomethane
Toxicity to algae/aquatic plants
ErC50 (Pseudokirchneriella subcapitata (algae)): 1.69 mg/l Exposure time: 72 h Test Type: static test Analytical monitoring: yes Method: OECD Test Guideline 201 GLP: yes Remarks: The value is given in analogy to the following substances: The value is given in analogy to the following substances: iodomethane
Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity)
NOEC (Daphnia magna (Water flea)): 0.16 mg/l End point: reproduction rate Exposure time: 21 d Test Type: semi-static test Analytical monitoring: yes Method: OECD Test Guideline 211 GLP: yes Remarks: The value is given in analogy to the following substances: The value is given in analogy to the following substances: iodomethane
Persistence and degradability
Components:
Iodomethane-13C,d2:
Biodegradabilityaerobic Inoculum: activated sludge Concentration: 100 mg/l Result: Not biodegradable Biodegradation: 0 % Exposure time: 28 d Method: OECD Test Guideline 301F GLP: yes Remarks: The value is given in analogy to the following substances: The value is given in analogy to the following substances: iodomethane
Bioaccumulative potential
No data available
Mobility in soil
No data available
Other adverse effects
No data available
Disposal methods
Waste from residuesOffer surplus and non-recyclable solutions to a licensed disposal company.
International Regulations
IATA-DGR
Not permitted for transport
IMDG-Code
UN number : UN 2644
Proper shipping name : METHYL IODIDE
Class : 6.1
Packing group : I
Labels : 6.1
EmS Code : F-A, S-A
Marine pollutant : no
Proper shipping name : METHYL IODIDE
Class : 6.1
Packing group : I
Labels : 6.1
EmS Code : F-A, S-A
Marine pollutant : no
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
National Regulations
JT/T 617
UN number : UN 2644
Proper shipping name : METHYL IODIDE
Class : 6.1
Packing group : I
Labels : 6.1
Environmentally hazardous : no
Proper shipping name : METHYL IODIDE
Class : 6.1
Packing group : I
Labels : 6.1
Environmentally hazardous : no
Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely based upon the properties of the unpackaged material as it is described within this Safety Data Sheet. Transportation classifications may vary by mode of transportation, package sizes, and variations in regional or country regulations.
Downstream users need to comply with the conditions of safe use of the chemical, understand the environmental and health hazard and risk management measures identified on the SDS as well as the local/national regulations concerning the chemical.
National regulatory information
Law on the Prevention and Control of Occupational Diseases
Regulations on Safety Management of Hazardous Chemicals
Catalogue of Hazardous Chemicals
Identification of Major Hazard Installations for Hazardous Chemicals (GB 18218)
No. / Code Chemical name / Category Threshold quantity
J5 Acute toxic 500 t
Hazardous Chemicals for Priority Management
Not listed under SAWS
Catalogue of Specially Controlled Hazardous
Not listed Chemicals
List of Explosive Precursors
Not listed
Regulations on Labour Protection in Workplaces where Toxic Substances are Used
Catalogue of Highly Toxic Chemicals
Not listed
Regulation of Environmental Management on the First Import of Chemicals and the Import and Export of Toxic Chemicals
China Severely Restricted Toxic Chemicals for Import and Export
Not listed
Measures on the Environmental Administration of New Chemical Substances Registration
Registration/Notification number
B1A222232294
Regulation on the Administration of Precursor Chemicals
Catalogue and Classification of Precursor Chemicals
Not listed
Regulations on the Administration of Controlled Chemicals
List of Controlled Chemicals
Not listed
Regulations of Ozone Depleting Substances Management
List of Controlled Ozone Depleting Substances
Not listed
List of Controlled Ozone Depleting Substances Import and Export
Not listed
Environmental Protection Law
List of Priority Controlled Chemicals
Not listed
List of Key Controlled New Pollutants
Not listed
Full text of other abbreviations
ACGIHUSA. ACGIH Threshold Limit Values (TLV)
GBZ 2.1-2007
Occupational exposure limits for hazardous agents in the workplace - Chemical hazardous agents.
ACGIH / TWA
8-hour, time-weighted average
GBZ 2.1-2007 / PC-TWA AIIC - Australian Invent Transport by Land of Bra bw - Body weight; CMR Standard of the German List (Canada); ECx - Conc associated with x% respo Chemical Substances (Jap response; ERG - Emerge GLP - Good Laboratory P cer; IATA - International Construction and Equipm Half maximal inhibitory c tion; IECSC - Inventory o tional Maritime Dangerou Industrial Safety and H Standardization; KECI - K tration to 50 % of a test (Median Lethal Dose); MA lution from Ships; n.o.s. No Observed (Adverse) E fect Level; NOELR - No Norm; NTP - National Toxi icals; OECD - Organizatio fice of Chemical Safety a and Toxic substance; PIC stances; (Q)SAR - (Quant (EC) No 1907/2006 of th Registration, Evaluation, Accelerating Decompositi Chemical Substance Inve Thailand Existing Chemica States); UN - United Nat Transport of Dangerous WHMIS - Workplace Hazar
Permissible concentration - time weighted average ry of Industrial Chemicals
ANTT - National Agency for il
ASTM - American Society for the Testing of Materials
- Carcinogen, Mutagen or Reproductive Toxicant
DIN nstitute for Standardisation
DSL - Domestic Substances ntration associated with x% response
ELx - Loading rate se
EmS - Emergency Schedule
ENCS - Existing and New n)
ErCx - Concentration associated with x% growth rate cy Response Guide
GHS - Globally Harmonized System
actice
IARC - International Agency for Research on Canir Transport Association
IBC - International Code for the nt of Ships carrying Dangerous Chemicals in Bulk
IC50 ncentration
ICAO - International Civil Aviation Organiza- Existing Chemical Substances in China
IMDG - Interna- Goods
IMO - International Maritime Organization
ISHL alth Law (Japan)
ISO - International Organisation for rea Existing Chemicals Inventory
LC50 - Lethal Concenopulation
LD50 - Lethal Dose to 50% of a test population POL - International Convention for the Prevention of Pol- Not Otherwise Specified
Nch - Chilean Norm
NO(A)EC fect Concentration
NO(A)EL - No Observed (Adverse) Efbservable Effect Loading Rate
NOM - Official Mexican ology Program
NZIoC - New Zealand Inventory of Chemfor Economic Co-operation and Development
OPPTS - Ofd Pollution Prevention
PBT - Persistent, Bioaccumulative S - Philippines Inventory of Chemicals and Chemical Subtative) Structure Activity Relationship
REACH - Regulation European Parliament and of the Council concerning the uthorisation and Restriction of Chemicals
SADT - Selfn Temperature
SDS - Safety Data Sheet
TCSI - Taiwan tory
TDG - Transportation of Dangerous Goods
TECI s Inventory
TSCA - Toxic Substances Control Act (United ons
UNRTDG - United Nations Recommendations on the oods
vPvB - Very Persistent and Very Bioaccumulative
ous Materials Information System
ANTT - National Agency for il
ASTM - American Society for the Testing of Materials
- Carcinogen, Mutagen or Reproductive Toxicant
DIN nstitute for Standardisation
DSL - Domestic Substances ntration associated with x% response
ELx - Loading rate se
EmS - Emergency Schedule
ENCS - Existing and New n)
ErCx - Concentration associated with x% growth rate cy Response Guide
GHS - Globally Harmonized System
actice
IARC - International Agency for Research on Canir Transport Association
IBC - International Code for the nt of Ships carrying Dangerous Chemicals in Bulk
IC50 ncentration
ICAO - International Civil Aviation Organiza- Existing Chemical Substances in China
IMDG - Interna- Goods
IMO - International Maritime Organization
ISHL alth Law (Japan)
ISO - International Organisation for rea Existing Chemicals Inventory
LC50 - Lethal Concenopulation
LD50 - Lethal Dose to 50% of a test population POL - International Convention for the Prevention of Pol- Not Otherwise Specified
Nch - Chilean Norm
NO(A)EC fect Concentration
NO(A)EL - No Observed (Adverse) Efbservable Effect Loading Rate
NOM - Official Mexican ology Program
NZIoC - New Zealand Inventory of Chemfor Economic Co-operation and Development
OPPTS - Ofd Pollution Prevention
PBT - Persistent, Bioaccumulative S - Philippines Inventory of Chemicals and Chemical Subtative) Structure Activity Relationship
REACH - Regulation European Parliament and of the Council concerning the uthorisation and Restriction of Chemicals
SADT - Selfn Temperature
SDS - Safety Data Sheet
TCSI - Taiwan tory
TDG - Transportation of Dangerous Goods
TECI s Inventory
TSCA - Toxic Substances Control Act (United ons
UNRTDG - United Nations Recommendations on the oods
vPvB - Very Persistent and Very Bioaccumulative
ous Materials Information System
Disclaimer:
The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.
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