Chemical Safety Data Sheet MSDS / SDS
Vinyl crotonate
Revision Date:2026-03-20Revision Number:1
Product identifier
- Product name: Vinyl crotonate
- CBnumber: CB6853121
- CAS: 14861-06-4
- EINECS Number: 238-930-6
- Synonyms: VINYE CROTONATE;Vinyl 2-butenoate
Relevant identified uses of the substance or mixture and uses advised against
- Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
- Uses advised against: none
Company Identification
- Company: Chemicalbook
- Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
- Telephone: 010-86108875
GHS Label elements, including precautionary statements
-
Symbol(GHS)
- Signal wordWarning
P501 Dispose of contents/container to..…
P403+P235 Store in a well-ventilated place. Keep cool.
P370+P378 In case of fire: Use … for extinction.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P264 Wash skin thouroughly after handling.
P240 Ground/bond container and receiving equipment.
P233 Keep container tightly closed.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
Hazard statements
H319 Causes serious eye irritation
H315 Causes skin irritation
H226 Flammable liquid and vapour
Substance
- Product name: Vinyl crotonate
- Synonyms: VINYE CROTONATE;Vinyl 2-butenoate
- CAS: 14861-06-4
- EC number: 238-930-6
- MF: C6H8O2
- MW: 112.13
If inhaled
Remove person to fresh air and keep comfortable for breathing. Get medical advice/ attention if you feel unwell.
In case of skin contact
Take off all contaminated clothing immediately. If on skin, rinse well with water. If skin irritation occurs: Get medical advice/ attention.
In case of eye contact
Rinse with plenty of water. If easy to do, remove contact lens, if worn. If eye irritation persists: Get medical advice/ attention.
If swallowed
Get medical advice/ attention. Rinse mouth.
Most important symptoms and effects, both acute and delayed
None known.
Suitable extinguishing media
Dry powder, Foam, Water spray, Carbon dioxide (CO2)
Specific hazards during fire fighting
No information available.
Specific extinguishing methods
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Immediately evacuate personnel to safe areas. Cool closed containers exposed to fire with water spray. Remove undamaged containers from fire area if it is safe to do so.
Special protective equipment for fire-fighters
Use personal protective equipment.
NFPA 704
2
3
2
| HEALTH | 2 | Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury (e.g. diethyl ether, ammonium phosphate, iodine) | |
| FIRE | 3 | Liquids and solids (including finely divided suspended solids) that can be ignited under almost all ambient temperature conditions . Liquids having a flash point below 22.8 °C (73 °F) and having a boiling point at or above 37.8 °C (100 °F) or having a flash point between 22.8 and 37.8 °C (73 and 100 °F). (e.g. gasoline, acetone) | |
| REACT | 2 | Undergoes violent chemical change at elevated temperatures and pressures, reacts violently with water, or may form explosive mixtures with water (e.g. white phosphorus, potassium, sodium) | |
| SPEC. HAZ. |
Personal precautions, protective equipment and emergency procedures
Wear suitable protective equipment. Keep people away from and upwind of spill/leak. Ensure adequate ventilation. Entry to non-involved personnel should be controlled around the leakage area by roping off, etc.
Environmental precautions
Prevent product from entering drains.
Methods and materials for containment and cleaning up
Collect as much of the spill as possible with a suitable absorbent material.
Handling
Technical measuresPrevent generation of vapor or mist. Take precautionary measures against static discharge. Use explosion-proof equipment.
Local/Total ventilation
Ensure adequate ventilation. Use a local exhaust ventilation.
Advice on safe handling
Avoid contact with skin, eyes and clothing. Wear personal protective equipment. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not subject to grinding, shock or friction. Wash hands and face thoroughly after handling.
Avoidance of contact
Strong bases, Strong acids, Oxidizing agents
Storage
Conditions for safe storageKeep container tightly closed. Store in a refrigerator. Keep in a well-ventilated place. Use explosion-proof equipment.
Ingredients with workplace control parameters
Contains no substances with occupational exposure limit values.
Engineering measures
Install a closed system or local exhaust.
Also install safety shower and eye bath.
Also install safety shower and eye bath.
Personal protective equipment
Respiratory protectionGas mask
Eye/face protection
Safety glasses
Face-shield
Skin and body protection
Face-shield
Protective suit
Hand protection
Protective gloves *Use personal protective equipment(PPE) approved under appropriate government standards and follow local and national regulations.
Information on basic physicochemical properties
- Physical stateclear liquid
- FlammabilityNo data available
- Evaporation rateNo data available
- Flash point32 °C
- Boiling point/boiling range134 °C
- Melting point/freezing point-60 °C
- pHNo data available
- Odor ThresholdNo data available
- OdorNo data available
- Colorcolorless
- Appearanceliquid
- Molecular weight112.13 g/mol
- Viscosity, kinematicNo data available
- Viscosity, dynamic0.7 mPa.s ( 20 °C)
- Decomposition temperatureNo data available
- Autoignition temperatureNo data available
- Partition coefficient: n-octanol/waterNo data available
- Solubility in other solventsChloroform (Soluble), Methanol (Slightly)
- Water solubilityslightly soluble
- Solubility(ies)Chloroform (Soluble), Methanol (Slightly)
- Relative density0.94
- Relative vapor density4.0
- Vapor pressure66.7 Pa (20 °C)
- Lower explosion limit / Lower flammability limitNo data available
- Upper explosion limit / Upper flammability limitNo data available
Reactivity
No data available
Chemical stability
Polymerization may occur under the influences of heat, light or on contact with polymerization initiators such as peroxides etc.
Possibility of hazardous reactions
None under normal processing.
Conditions to avoid
Heat. Electrical spark Open flame Electrostatic discharge Exposure to light.
Incompatible materials
Strong bases, Strong acids, Oxidizing agents
Hazardous decomposition products
Carbon monoxide, Carbon dioxide (CO2)
Acute toxicity
Components
Vinyl Crotonate
Acute oral toxicity
LD50 (Rat): 6,500 mg/kg Assessment: The substance or mixture has no acute oral toxicity
Acute inhalation toxicity
LCLo (Rat): 4000 ppm Exposure time: 4 h Test atmosphere: gas Assessment: The substance or mixture has no acute inhalation toxicity
Acute dermal toxicity
LD50 (Rabbit): 4.7 g/kg Assessment: The substance or mixture has no acute dermal toxicity
Skin corrosion/irritation
Product
Result
Skin irritation
Components
Vinyl Crotonate
Result
Skin irritation
Serious eye damage/eye irritation
Product
Result
Eye irritation
Components
Vinyl Crotonate
Result
Eye irritation
Respiratory or skin sensitization
Classified based on available data. For more details, see section 2.
Germ cell mutagenicity
Classified based on available data. For more details, see section 2.
Carcinogenicity
Classified based on available data. For more details, see section 2.
Reproductive toxicity
Classified based on available data. For more details, see section 2.
STOT-single exposure
Classified based on available data. For more details, see section 2.
STOT-repeated exposure
Classified based on available data. For more details, see section 2.
Repeated dose toxicity
Classified based on available data. For more details, see section 2.
Aspiration toxicity
Classified based on available data. For more details, see section 2.
RTECS No.
GQ5850000 (Vinyl Crotonate)
Ecotoxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Other adverse effects
No data available
Disposal methods
Waste from residuesDisposal in accordance with local and national regulations. Take precautions against ignition or explode. Entrust disposal to a licensed waste disposal company.
Contaminated packaging
Disposal in accordance with local and national regulations. Before disposal of used container, remove contents completely.
International Regulations
IATA-DGR
UN/ID No.UN 3272
Proper shipping name
Esters, n.o.s.
Class
3
Packing group
III
IMDG-Code
UN numberUN 3272
Proper shipping name
ESTERS, N.O.S.
Class
3
Packing group
III
EmS Code
F-E, S-D
Domestic regulation
GB 6944/12268
UN numberUN 3272
Proper shipping name
ESTERS , N.O. S.
Class
3
Packing group
III
Measures on the Environmental Administration of New Chemical Substances Registration
Registration/Notification numberB1A232216251
Downstream users need to comply with the conditions of safe use of the chemical, understand the environmental and health hazard and risk management measures identified on the SDS as well as the local/national regulations concerning the chemical.
Downstream users need to comply with the conditions of safe use of the chemical, understand the environmental and health hazard and risk management measures identified on the SDS as well as the local/national regulations concerning the chemical.
The ingredients of this product are reported in the following inventories
CH BAGREGOn the inventory, or in compliance with the inventory
TSCA
Substance(s) not listed on TSCA inventory
AICS
Not in compliance with the inventory
DSL
This product contains the following components that are not on the
Canadian DSL nor NDSL.
Vinyl Crotonate
ENCS
Canadian DSL nor NDSL.
Vinyl Crotonate
Not in compliance with the inventory
ISHL
On the inventory, or in compliance with the inventory
KECI
Not in compliance with the inventory
PICCS
Not in compliance with the inventory
IECSC
Not in compliance with the inventory
NZIoC
Not in compliance with the inventory
Abbreviations and acronyms
CAS: Chemical Abstracts Service
TWA: Time-Weighted Average
STEL: Short-Term Exposure Limit
LD50: Lethal Dose 50%
LC50: Lethal Concentration 50%
EC50: Effective Concentration 50%
PEL: Permissible Exposure Limit
TLV: Threshold Limit Value
IMDG: International Maritime Dangerous Goods Code
IATA: International Air Transport Association
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
DOT: US Department of Transportation
NFPA: National Fire Protection Association
NIOSH: National Institute for Occupational Safety and Health
OSHA: Occupational Safety and Health Administration
TWA: Time-Weighted Average
STEL: Short-Term Exposure Limit
LD50: Lethal Dose 50%
LC50: Lethal Concentration 50%
EC50: Effective Concentration 50%
PEL: Permissible Exposure Limit
TLV: Threshold Limit Value
IMDG: International Maritime Dangerous Goods Code
IATA: International Air Transport Association
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
DOT: US Department of Transportation
NFPA: National Fire Protection Association
NIOSH: National Institute for Occupational Safety and Health
OSHA: Occupational Safety and Health Administration
Disclaimer:
The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.