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106-14-9

106-14-9 Structure

106-14-9 Structure
IdentificationMore
[Name]

12-HYDROXYSTEARIC ACID
[CAS]

106-14-9
[Synonyms]

(+/-)-12-HYDROXYOCTADECANOIC ACID
12-HYDROXYOCTADECANOIC ACID
12-HYDROXYSTEARIC ACID
DL-12-HYDROXYOCTADECANOIC ACID
DL-12-HYDROXYSTEARIC ACID
LEMOSOL COAGULANT
12-hydroxy-octadecanoicaci
12-hydroxystearic
12-hydroxy-stearicaci
12-Hydroxysteric acid
Barolub fto
barolubfto
Cerit Fac 3
ceritfac3
Ceroxin gl
ceroxingl
Harwax A
harwaxa
Hydrofol Acid 200
hydrofolacid200
[EINECS(EC#)]

203-366-1
[Molecular Formula]

C18H36O3
[MDL Number]

MFCD00004592
[Molecular Weight]

300.48
[MOL File]

106-14-9.mol
Chemical PropertiesBack Directory
[Description]

12-Hydroxy stearic acid (12-HSA) is a saturated hydroxy fatty acid. It's a waxy, odourless, tasteless and cream coloured compound in flakes / powder.
appearance creamish flakes or powder
melting point °C min. 70
colour Gardner max. 6
colour (on 1” Lovibond) max 20 yellow / max. 4,5 red
acid value mg KOH/g min. 175
iodine value (Wijs) g I2/100g max. 5
hydroxyl value min. 150
saponification value mg KOH/g 175 - 190
[Appearance]

white to slightly beige powder or flakes
[Melting point ]

74-76 °C (lit.)
[Boiling point ]

180 °C
[density ]

1.0238 (rough estimate)
[refractive index ]

1.4200 (estimate)
[storage temp. ]

−20°C
[form ]

Crystalline
[pka]

4.78±0.10(Predicted)
[color ]

White
[Water Solubility ]

Soluble in ether, alcohol and chloroform. Insoluble in water.
[BRN ]

1726730
[Uses]

  1. lubrication: 12-Hydroxy stearic acid (12-HSA) gives better Lithium, Barium and Calcium multi-purpose greases. It provides excellent resistance to water, oils, solvents and crude petroleum, wide temperature range stability and high drop point.
  2. cosmetics: 12-HSA is used for gelling liquid Paraffin in creams and ointments, which easily liquefy on the skin. Esters of 12-HSA are used in various cosmetic products (lipsticks, deodorant and antiperspirant sticks, shaving creams, etc.).
  3. coatings: 12-HSA is reacted with acrylic esters to produce hard, durable thermosetting polymers used in the high quality automotive, industrial appliance and metal decorative finishes.
  4. rubber: functions as an activator and internal lubricant for natural and synthetic rubbers
  5. others: 12-HSA is an useful component in polishes, inks and hot melt adhesives
[CAS DataBase Reference]

106-14-9(CAS DataBase Reference)
[EPA Substance Registry System]

Octadecanoic acid, 12-hydroxy- (106-14-9)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[RTECS ]

WI3850000
[TSCA ]

Yes
[HS Code ]

29181990
[Hazardous Substances Data]

106-14-9(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sodium hydroxide-->Sulfuric acid-->Castor oil-->Nickel aluMinuM-->Hydrogenated castor oil-->ethyl 12-oxooctadecanoate-->11-CYANO-1-UNDECANOIC ACID-->12-HYDROXYSTEARIC ACID ETHYL ESTER-->DODECANEDIOIC ACID MONOETHYL ESTER-->12-Chloro-12-oxododecanoic acid ethyl ester-->12-oxooctadecanoic acid-->METHYL RICINOLEATE-->Hexylmagnesium chloride-->CYCLODODECANOL-->Ricinoleic acid
[Preparation Products]

Extreme pressure lithium-based grease-->2-Nonenal
Hazard InformationBack Directory
[Chemical Properties]

white powder
[Definition]

ChEBI: A hydroxy fatty acid that is stearic acid bearing a hydroxy substituent at position 12.
[General Description]

Non-isothermal nucleation rate of a self-assembling fibrillar network of 12-hydroxyoctadecanoic acid (12-hydroxystearic acid) in canola oil has been reported. It is commonly used as gelling agent for organic solvents. Self-assembled monolayers of 12-hydroxyoctadecanoic acid and its 4,4′-bipyridinium salt have been observed on the solution graphite interface using scanning tunnelling microscopy.
Spectrum DetailBack Directory
[Spectrum Detail]

12-HYDROXYSTEARIC ACID(106-14-9)MS
12-HYDROXYSTEARIC ACID(106-14-9)1HNMR
12-HYDROXYSTEARIC ACID(106-14-9)13CNMR
12-HYDROXYSTEARIC ACID(106-14-9)IR1
12-HYDROXYSTEARIC ACID(106-14-9)IR2
12-HYDROXYSTEARIC ACID(106-14-9)IR3
12-HYDROXYSTEARIC ACID(106-14-9)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

DL-12-Hydroxystearic acid, 99+%(106-14-9)
[Alfa Aesar]

12-Hydroxystearic acid, tech. 85%(106-14-9)
[Sigma Aldrich]

106-14-9(sigmaaldrich)
[TCI AMERICA]

12-Hydroxystearic Acid,>75.0%(GC)(106-14-9)
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