ChemicalBook--->CAS DataBase List--->1592-20-7

1592-20-7

1592-20-7 Structure

1592-20-7 Structure
IdentificationMore
[Name]

4-Vinylbenzyl chloride
[CAS]

1592-20-7
[Synonyms]

4-(CHLOROMETHYL)STYRENE
4-VINYLBENZYL CHLORIDE
CHLOROMETHYLSTYRENE
VINYLBENZYL CHLORIDE
1-(chloromethyl)-4-ethenyl-benzen
1-(chloromethyl)-4-ethenyl-Benzene
1-(chloromethyl)-4-vinylbenzene
4-VINYLBENZYL CHLORIDE, STAB.
4-Vinylbenylchloride
4-Vinylbenzyl chloride, tech., 90%
4-VINYLBENZYLCHLORIDE,TECHNICAL
P-CHLOROMETHYL STYRENE(4-VINYLBENZYL CHLORIDE)
p-Vinylbenzyl chloride
PARA-VINYLBENZYLCHLORIDE
4-CHLOROMETHYLSTYRENE, STABILIZED WITH TBC+ONP+O-NITROCRESOL
BENZENE,1-(CHLOROMETHYL)-4-ETHENYL-
4-(Chloromethyl)styrene (stabilized with TBC + ONP + 2-Nitro-p-cresol)
CMS 14
p-(Chloromethyl)styrene
4-Vinylbenzyl chloride,90%,tech.
[EINECS(EC#)]

250-005-9
[Molecular Formula]

C9H9Cl
[MDL Number]

MFCD00051362
[Molecular Weight]

152.62
[MOL File]

1592-20-7.mol
Chemical PropertiesBack Directory
[Appearance]

clear yellow liquid
[Boiling point ]

229 °C(lit.)
[density ]

1.083 g/mL at 25 °C(lit.)
[vapor density ]

5.3 (vs air)
[vapor pressure ]

1 mm Hg ( 56.1 °C)
[refractive index ]

n20/D 1.572(lit.)
[Fp ]

221 °F
[storage temp. ]

−20°C
[solubility ]

Chloroform (Sparingly)
[Water Solubility ]

Insoluble in water
[form ]

Liquid
[color ]

Clear yellow
[BRN ]

2204384
[Stability:]

Light Sensitive
[InChIKey]

ZRZHXNCATOYMJH-UHFFFAOYSA-N
[CAS DataBase Reference]

1592-20-7(CAS DataBase Reference)
[Storage Precautions]

Air sensitive;Light sensitive
[EPA Substance Registry System]

1592-20-7(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

R34:Causes burns.
R43:May cause sensitization by skin contact.
R21/22:Harmful in contact with skin and if swallowed .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 3265 8/PG 3
[WGK Germany ]

3
[F ]

8-19
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

29039990
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sodium hydroxide-->Dichloromethane-->tert-Butanol-->Potassium tert-butoxide-->Aluminium chloride hexahydrate-->tert-Butyl methyl ether-->PETROLEUM ETHER-->Chloromethyl methyl ether-->1,1,2,2-Tetrachloroethane-->(2-Bromoethyl)benzene
[Preparation Products]

4-(PYRROLIDIN-1-YLMETHYL)BENZENEBORONIC ACID, PINACOL ESTER 97%1-[4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZYL]PYRROLIDINE-->4-(2-CYANOETHYLAMINOCARBONYL)PHENYLBORONIC ACID-->3-(2-CYANOETHYLAMINOCARBONYL)PHENYLBORONIC ACID-->4-(PIPERIDINE-1-CARBONYL)PHENYLBORONIC ACID-->4-VINYLBENZYL ACETATE-->1-[4-(chloromethyl)phenyl]ethanone-->4-CHLOROMETHYLBENZALDEHYDE; >95%DISCONTINUED 10/25/01-->4-CHLOROMETHYLSTILBENE-->4-Vinylbenzyl glycidyl ether-->1-(4-vinylbenzyl)piperidine
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

4-Chloromethyl styrene(1592-20-7).msds
Hazard InformationBack Directory
[Chemical Properties]

clear yellow liquid
[Uses]

Component of ion exchange resins, photo-resist polymers, cross-linkable fibers, coupling agents and electroconducting polymers.
Starter for various copolymer preparations.
Dual functional monomer. Readily derivatized by chloride displacement.
[Purification Methods]

Purify 4-vinylbenzyl chloride by dissolving it in Et2O, washing it with 0.5% of aqueous NaOH, separating, drying the organic layer (Na2SO4), evaporating and distilling the residual oil under N2 in vacuo. Add 0.05% of 4-tert-butylcatechol as stabilizer. It is lachrymatory. [Nishikubo et al. Tetrahedron Lett 22 3872 1981, Tanimoto et al. Synth Commun 4 193 1974, Beilstein 6 IV 3818.]
Spectrum DetailBack Directory
[Spectrum Detail]

4-Vinylbenzyl chloride(1592-20-7)FT-IR
4-Vinylbenzyl chloride(1592-20-7)IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

4-Vinylbenzyl chloride, tech., 90%(1592-20-7)
[Sigma Aldrich]

1592-20-7(sigmaaldrich)
[TCI AMERICA]

4-(Chloromethyl)styrene  (stabilized with TBC + ONP + 2-Nitro-p-cresol),>90.0%(GC)(1592-20-7)
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