| Identification | More | [Name]
Aluminium chloride hexahydrate | [CAS]
7784-13-6 | [Synonyms]
ALUMINII CHLORIDUM HEXAHYDRICUM
ALUMINIUM(+3)CHLORIDE HEXAHYDRATE
ALUMINIUM CHLORIDE 6H2O
ALUMINIUM CHLORIDE 6-HYDRATE
ALUMINIUM CHLORIDE HEXAHYDRATE
ALUMINIUM CHLORIDE HYDRATE
ALUMINIUM CHLORIDE HYDRATED
ALUMINIUM(III) CHLORIDE HEXAHYDRATE
ALUMINUM CHLORIDE
ALUMINUM CHLORIDE, 6-HYDRATE
ALUMINUM CHLORIDE HEXAHYDRATE
ALUMINUM CHLORIDE HYDRATED
ALUMINUM CHLORIDE, HYDROUS
ALUMINUM TRICHLORIDE HEXAHYDRATE
HYDROCHLORIC ACID ALUMINUM SALT HEXAHYDRATE
aluminum(iii)chloride,hexahydrate
Aluminumchloride(AlCl3)hexahydrate
chlorured’aluminium,hexahydrate
hydrousaluminumchloride
trichloroaluminumhexahydrate | [EINECS(EC#)]
231-208-1 | [Molecular Formula]
AlCl3H12O6 | [MDL Number]
MFCD00149134 | [Molecular Weight]
241.43 | [MOL File]
7784-13-6.mol |
| Chemical Properties | Back Directory | [Appearance]
white to pale yellow crystalline solid | [Melting point ]
100°C (dec.) | [density ]
2.39
| [vapor pressure ]
1 mm Hg ( 100 °C)
| [storage temp. ]
Store at +15°C to +25°C. | [solubility ]
water: soluble0.5g/10 mL, clear, colorless | [form ]
Solid | [color ]
White To Light Yellow | [Specific Gravity]
2.398 | [Odor]
Odorless | [PH]
2.5 (50g/l, H2O, 20℃) | [PH Range]
2.5 - 3.5 | [Stability:]
Stable, but may decompose upon exposure to moist air or water. Incompatible with acids.Note that decomposition of the anhydrous product, possibly caused by moisture leaking into the container or being trapped within it, may cause a pressure rise in a sealed container, potentially leading to explosive rupture. | [Water Solubility ]
477 g/L (20 ºC) | [Sensitive ]
Moisture Sensitive | [Merck ]
14,337 | [Exposure limits]
NIOSH: TWA 2 mg/m3 | [LogP]
-1.380 (est) | [CAS DataBase Reference]
7784-13-6(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,C | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R34:Causes burns.
R36/38:Irritating to eyes and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . | [RIDADR ]
UN 3260 8/PG 3
| [WGK Germany ]
1
| [RTECS ]
BD0530000
| [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
28273200 | [Toxicity]
LD50 orally in Rabbit: 3311 mg/kg |
| Raw materials And Preparation Products | Back Directory | [Raw materials]
Hydrochloric acid-->Aluminum hydroxide-->ALUMINUM INGOTS-->Aluminium trichloride,solution | [Preparation Products]
4-Chlorobenzhydrol-->Musk xylene-->SODIUM 3-4-ISOBUTYLPHENYL)-2,3-EPOXYBUTYURATE-->1,4,5,8-Naphthalenetetracarboxylic acid-->Vat Yellow 4-->1-(2,5-Dimethoxyphenyl)-2-oximino-1-propanone-->4-(4-Aminophenyl)butyric acid-->2-(4-isobutylphenyl)propionaldehyde oxime-->METHYL 4-(4-(BIS(2-CHLOROETHYL)AMINO)PHENYL)BUTYRATE-->KETAMINE RELATED COMPOUND A (50 MG) (1 -[(2-CHLOROPHENYL)(METHYLIMINO)METHYL]CYLCOPENTA-NOL)-->ETHYL 3-(6-METHOXY-2-NAPHTHYL)-3-METHYL GLYCIDATE-->4-Bromo-2,2-diphenylbutyric acid-->METHYL 3-(6-METHOXY-2-NAPHTHYL)-3-METHYL GLYCIDATE-->3-(o-chlorophenyl)-3-hydroxy-3-phenylpropiononitrile-->Ethyl(4-butyry-2,3-dichloro)phenoxyacetate-->1-(2,3-DICHLORO-4-HYDROXYPHENYL)BUTAN-1-ONE-->(2-Chlorophenyl)phenyl-methanone-->4-[2-(diethylamino)ethoxy]benzophenone-->BUCLIZINE-->METHYL 4-(4-(BIS(2-HYDROXYETHYL)AMINO)PHENYL)BUTYRATE-->ALPHA,ALPHA-DIPHENYL-GAMMA-BUTYROLACTONE-->8-ACETYL-7-HYDROXY-4-METHYLCOUMARIN-->1,5-DIHYDROXYANTHRAQUINONE-->3-BENZOYLPHENYLACETIC ACID-->ETHYL 3-(4-ISOBUTYLPHENYL)-3-METHYL GLYCIDATE-->3,3-Diphenylpropionic acid-->4-BROMO-2,2-DIPHENYLBUTYRONITRILE-->3,4-Dichlorobenzophenone-->water-proofing agnet AC-->5-(2-Carboxybenzoyl)-2-chlorobenzenesulfonyl chloride-->4-chloro-4'-methoxybenzophenone-->2-(4-Chlorobenzoyl)benzoic acid-->3-(4-ACETYLAMINOBENZOYL)PROPANOIC ACID-->3-BENZOYLPROPIONIC ACID-->1,4-Dibenzoylbutane-->2',5'-Dihydroxyacetophenone-->ALUMINUM CHLOROHYDRATE-->2-BENZOYLBENZOYL CHLORIDE-->TRANS-1,2-DIBENZOYLETHYLENE-->4-tert-Amylphenol |
| Questions And Answer | Back Directory | [Physical Properties]
White or yellowish deliquescent powder; faint odor of HCl; density 2.40 g/cm3; soluble in water and polar organic solvents such as alcohol; aqueous solution acidic.
| [Uses]
The Aluminium chloride hexahydrate is used in the preparation of deodorant and antiperspirant. Also, it is applied in textile finishing to improve the antistatic characteristics and flammability ratings of various textile materials. Commercially, it is sold as crystalline powder or as a 28% solution in water.
| [Preparation]
Aluminum chloride hexahydrate is prepared by dissolving Al(OH)3 in conc. HCl and passing gaseous HCl through the solution at 0°C. The precipitate is washed with diethyl ether and dried. Alternatively, it is prepared by hydrolyzing anhydrous AlCl3 in cold dilute HCl.
| [Reactions]
Decomposes to alumina when heated at 300°C;
2AlCl3 •6H2O →2Al2O3 + 6HCl + 9H2O
Reacts with caustic soda solution forming gelatinous precipitate of aluminum hydroxide (hydrous aluminum oxide); yields aluminum monobasic stearate, Al(OH)2[OOC(CH2)16CH3] when its solution is mixed with a solution of sodium stearate.
|
| Hazard Information | Back Directory | [Chemical Properties]
white to pale yellow crystalline solid | [Definition]
ChEBI: Aluminium trichloride hexahydrate is a hydrate. It contains an aluminium trichloride. | [Indications]
Aluminum chloride hexahydrate (6.25% Xerac A-C) is an effective antiperspirant
that has also an antibacterial effect. It may be useful in cases of acne
in which sweating is prominent or appears to be aggravating the disease, but
its effects have not been well studied. |
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