ChemicalBook--->CAS DataBase List--->935-95-5

935-95-5

935-95-5 Structure

935-95-5 Structure
IdentificationMore
[Name]

2,3,5,6-TETRACHLOROPHENOL
[CAS]

935-95-5
[Synonyms]

2,3,5,6-Tetrachloropheno1
2,3,5,6-TETRACHLOROPHENOL
2,3,5,6-tetrachloro-pheno
Phenol, 2,3,5,6-tetrachloro-
phenol,2,3,5,6-tetrachloro
2,3,5,6-TETRACHLOROPHENOL, 1X1ML, MEOH 2 000UG/ML
2,3,5,6-TETRACHLOROPHENOL PESTANAL, 10 M
2,3,5,6-TETRACHLOROPHENOL, 50 MG, NEAT
2,3,5,6-tetrachlorophenate
2,3,5,6-TCP
2,3,5,6-TECP
[EINECS(EC#)]

213-310-8
[Molecular Formula]

C6H2Cl4O
[MDL Number]

MFCD00044671
[Molecular Weight]

231.89
[MOL File]

935-95-5.mol
Chemical PropertiesBack Directory
[Appearance]

Brown solid; phenol odor. Soluble in sodium hydroxide solutions and most organic solvents; insoluble in water.
[Melting point ]

115-116℃ (isooctane )
[Boiling point ]

331.59°C (rough estimate)
[density ]

1.6 g/cm3 (60℃)
[refractive index ]

1.5133 (estimate)
[Fp ]

11 °C
[storage temp. ]

APPROX 4°C
[form ]

neat
[pka]

5.09±0.20(Predicted)
[Water Solubility ]

0.1g/L(25 ºC)
[BRN ]

2049586
[Uses]

Fungicide, wood preservative.
[CAS DataBase Reference]

935-95-5(CAS DataBase Reference)
[EPA Substance Registry System]

2,3,5,6-Tetrachlorophenol (935-95-5)
Safety DataBack Directory
[Hazard Codes ]

T,F
[Risk Statements ]

R25:Toxic if swallowed.
R37/38:Irritating to respiratory system and skin .
R41:Risk of serious damage to eyes.
R39/23/24/25:Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed .
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R11:Highly Flammable.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S39:Wear eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37:Wear suitable protective clothing and gloves .
S16:Keep away from sources of ignition-No smoking .
[RIDADR ]

UN 2020 6.1/PG 3
[WGK Germany ]

3
[RTECS ]

SM9450000
[Hazardous Substances Data]

935-95-5(Hazardous Substances Data)
Hazard InformationBack Directory
[General Description]

Leaflets (from ligroin) or light beige powder.
[Reactivity Profile]

2,3,5,6-TETRACHLOROPHENOL(935-95-5) is incompatible with acid chlorides, acid anhydrides and oxidizing agents. .
[Air & Water Reactions]

Insoluble in water.
[Fire Hazard]

Flash point data for this chemical are not available. 2,3,5,6-TETRACHLOROPHENOL is probably combustible.
[Chemical Properties]

Brown solid; phenol odor. Soluble in sodium hydroxide solutions and most organic solvents; insoluble in water.
[Definition]

ChEBI: The 2,3,5,6-isomer of tetrachlorophenol
[Production Methods]

Chlorophenols are generally prepared by the chlorination of phenol. There are other routes of synthesis as through diazotizing p-chloroaniline or dechlorinating (by alkaline hydrolysis) 1,2,4,5-tetrachlorobenzene to yield 2,4,5-trichlorophenol (TCP). Polychlorinated dibenzo-p-dioxins can be formedduringthemanufacturingprocess of the chlorophenols. The amount formed depends on temperature and pressure process variability during production. The more notable toxic dioxin, 2,3,7,8-tetrachlorodibenzo-p-dioxin (2,3,7,8-TCDD), is formed during the production of 2,4,5- TCP. Laboratory reference standards of 2,3,7,8-TCDD are prepared by heating 2,4,5-TCP under alkaline conditions. All technical and formulated products containing 2,4,5-TCP are expected to be contaminated to varying degrees by this 2,3,7,8-TCDD by-product of the manufacturing process.
[Hazard]

Toxic by ingestion and inhalation, strong irritant.
[Carcinogenicity]

There was no evidence of carcinogenic activity of 2,4-dichlorophenol in F344/N rats or B6C3F1 mice from the NTP bioassay program, but 2,4,6-trichlorophenol was reported to be carcinogenic in both species.
[Purification Methods]

Crystallise the phenol from pet ethers. The benzoate has m 136o (from EtOH). [Beilstein 6 II 182, 6 III 730, 6 IV 1025.]
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2,3,5,6-tetrachlorophenol(935-95-5).msds
Spectrum DetailBack Directory
[Spectrum Detail]

2,3,5,6-TETRACHLOROPHENOL(935-95-5)MS
2,3,5,6-TETRACHLOROPHENOL(935-95-5)1HNMR
2,3,5,6-TETRACHLOROPHENOL(935-95-5)13CNMR
2,3,5,6-TETRACHLOROPHENOL(935-95-5)IR1
2,3,5,6-TETRACHLOROPHENOL(935-95-5)IR2
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

935-95-5(sigmaaldrich)
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