laurotetanine

laurotetanine Struktur
128-76-7
CAS-Nr.
128-76-7
Englisch Name:
laurotetanine
Synonyma:
Litsoeine;NSC106610;NSC-106610;NSC 106610;Laurotetanin;laurotetanine;(6aS)-5,6,6a,7-Tetrahydro-1,2,10-trimethoxy-4H-dibenzo[de,g]quinolin-9-ol;[S,(+)]-5,6,6a,7-Tetrahydro-1,2,10-trimethoxy-4H-dibenzo[de,g]quinolin-9-ol;4H-Dibenzo[de,g]quinolin-9-ol, 5,6,6a,7-tetrahydro-1,2,10-trimethoxy-, (6aS)-
CBNumber:
CB01339347
Summenformel:
C19H21NO4
Molgewicht:
327.37
MOL-Datei:
128-76-7.mol

laurotetanine Eigenschaften

Schmelzpunkt:
125°C
Siedepunkt:
465.27°C (rough estimate)
Dichte
1.2223 (rough estimate)
Brechungsindex
1.5000 (estimate)
pka
9.76±0.20(Predicted)

Sicherheit

laurotetanine Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

The noraporphine alkaloid was first isolated by Greshoff from Litsea chrysocorna and subsequently from other species of Lauraceae including L. citrata and L. cubeba. When freshly crystallized from Me2 CO it yields colourless crystals but these become yellow in air. The alkaloid behaves as a phenolic base giving salts with mineral acids which all contain H20 of crystallization. The picrate monohydrate has m.p. 1480 C, the dibenzoyl derivative, m.p. 169-1700 C and the phenylthiocarbamide, m.p. 211-2°C. Three methoxyl groups, an imino group and a phenolic hydroxyl group are present, the latter giving the O-methyl ether which is an amorphous powder but yields a crystalline hydrochloride, m.p. 245°C; an oxalate, m.p. 233°C and the thiocarbamide, m.p. 154-5°C. The Nmethyl derivative (q.v.) is found naturally in Peurnus boldus and the O,Ndimethyl derivative is glaucine. The structure has been determined from chemical degradation and synthesis.

Einzelnachweise

Greshoff., Ber., 23,3537 (1890)
Filippo., Arch. Pharm., 236, 601 (1898)
Gorter., Bull. Jard. bot. Buitenzorg., 3, 180 (1921)
Barger, Silberschmidt.,J. Chem. Soc., 2919 (1928)
Barger et al., Ber., 66, 450 (1933)
Ruegger., Helv. Chim. Acta, 42,754 (1959)
Kikkawa.,J. Pharm. Soc., Japan, 79,83,425 (1959)

laurotetanine Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


laurotetanine Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 2)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
TargetMol Chemicals Inc.
+1-781-999-5354 +1-00000000000
marketing@targetmol.com United States 19892 58

128-76-7()Verwandte Suche:


  • laurotetanine
  • (6aS)-5,6,6a,7-Tetrahydro-1,2,10-trimethoxy-4H-dibenzo[de,g]quinolin-9-ol
  • [S,(+)]-5,6,6a,7-Tetrahydro-1,2,10-trimethoxy-4H-dibenzo[de,g]quinolin-9-ol
  • Litsoeine
  • Laurotetanin
  • NSC 106610
  • NSC106610
  • NSC-106610
  • 4H-Dibenzo[de,g]quinolin-9-ol, 5,6,6a,7-tetrahydro-1,2,10-trimethoxy-, (6aS)-
  • 128-76-7
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