N,N'-Ethylenbis[N-acetylacetamid]

Tetraacetylethylenediamine Struktur
10543-57-4
CAS-Nr.
10543-57-4
Bezeichnung:
N,N'-Ethylenbis[N-acetylacetamid]
Englisch Name:
Tetraacetylethylenediamine
Synonyma:
TAED;TEAD;TAEG;Nikon A;Mykon ATC;Mikon ATC;TETRAACETYLENEDIAMINE;TETRACETYLETHYLENEDIAMINE;TETRAACETYLETHYLENEDIAMINE;1,2-Bis(diacetylamino)ethane
CBNumber:
CB4401238
Summenformel:
C10H16N2O4
Molgewicht:
228.24
MOL-Datei:
10543-57-4.mol

N,N'-Ethylenbis[N-acetylacetamid] Eigenschaften

Schmelzpunkt:
149-154 °C
Siedepunkt:
140 °C (1.5002 mmHg)
Dichte
0.9
Brechungsindex
1.4550 (estimate)
Flammpunkt:
140 °C
pka
-1.23±0.70(Predicted)
Aggregatzustand
Granular Powder
Farbe
Off-white to beige
Wasserlöslichkeit
slightly soluble
Merck 
14,9028
BRN 
1795711
InChIKey
BGRWYDHXPHLNKA-UHFFFAOYSA-N
CAS Datenbank
10543-57-4(CAS DataBase Reference)
NIST chemische Informationen
N,n,n',n'-tetraacetylethylenediamine(10543-57-4)
EPA chemische Informationen
Tetraacetylethylenediamine (10543-57-4)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
S-Sätze: 22-24/25
WGK Germany  1
TSCA  Yes
HS Code  29241900
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P302+P352, P321,P332+P313, P362
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P305+P351+P338,P337+P313P
Sicherheit
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P302+P352 BEI BERÜHRUNG MIT DER HAUT: Mit viel Wasser/... (Hersteller kann, falls zweckmäßig, ein Reinigungsmittel angeben oder, wenn Wasser eindeutig ungeeignet ist, ein alternatives Mittel empfehlen) waschen.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen.
P332+P313 Bei Hautreizung: Ärztlichen Rat einholen/ärztliche Hilfe hinzuziehen.
P337+P313 Bei anhaltender Augenreizung: Ärztlichen Rat einholen/ärztliche Hilfe hinzuziehen.

N,N'-Ethylenbis[N-acetylacetamid] Chemische Eigenschaften,Einsatz,Produktion Methoden

S-Sätze Betriebsanweisung:

S22:Staub nicht einatmen.
S24/25:Berührung mit den Augen und der Haut vermeiden.

Chemische Eigenschaften

Tetraacetylethylenediamine is off-white to beige granular powder

Verwenden

Tetraacetylethylenediamine (TAED) is a bleaching activator which is mainly used in detergents and additives for laundry washing and dishwashing. Typical concentrations of TAED range between 1.4% and 13% in these products. A small amount of the produced TAED is also used in bleaching of paper, textiles and for the generation of Peracetic acid.
Peroxide bleach activator for household detergents, paper pulp.

synthetische

Tetraacetylethylenediamine (TAED) is produced in a two stage process from ethylenediamine (ED) and acetic anhydride (Ac2O). ED is first diacetylated to DAED. In the second step DAED is subsequently converted with Ac2O via TriAED into TAED (Clariant, 1999). TAED is crystallized out of the reaction mixture, filtered, washed and dried, and if necessary also granulated. The raw materials used occur almost quantitatively in the product. Byproducts are not formed.
TAED was prepared by acetylation of diacetylethylenediamine (DAED) with acetic anhydride in a 5 L reactor coupled with a packed distillation column, 2.5 cm in inside diameter and 1 m in length. The reaction temperature was set at 135 °C and the reflux ratio at 6. The molar ratio of acetic anhydride to DAED was varied from 3 to 5. A TAED yield as high as 80% was obtained, higher by 15% than in the absence of distillation.

Health Hazard

TAED is of very low toxicity by all exposure routes examined. Up to 2 g/kg BW there is no acute toxicity. TAED is practically non-irritating to skin and eyes and there is no evidence of a sensitizing potential by skin contact. The only effect after repeated oral and dermal dosing was reversible centrilobular hypertrophy in the liver at high doses due to the induction of metabolizing enzymes. In a 90-day whole body inhalation study no adverse effects in the rat lung, respiratory tract or nasal mucosa were observed. Biokinetic data showed that TAED is rapidly absorbed from the rat intestine and largely metabolized via diacetylation to TriAED and DAED which are excreted in the urine.

N,N'-Ethylenbis[N-acetylacetamid] Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


N,N'-Ethylenbis[N-acetylacetamid] Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 344)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282
alice@crovellbio.com China 8822 58
Hebei Mojin Biotechnology Co., Ltd
+8613288715578
sales@hbmojin.com China 12471 58
Hebei Yanxi Chemical Co., Ltd.
+8617531190177
peter@yan-xi.com China 6000 58
Hebei Dangtong Import and export Co LTD
+8615632927689
admin@hbdangtong.com China 990 58
Hebei Jingbo New Material Technology Co., Ltd
+8619931165850
hbjbtech@163.com China 1000 58
Shandong Juchuang Chemical Co., LTD
+undefined15030412209
admin@juchuangchem.com China 387 58
Hebei Saisier Technology Co., LTD
+86-18400010335 +86-18034520335
admin@hbsaisier.cn China 938 58
Ouhuang Engineering Materials (Hubei) Co., Ltd
+8617702722807
admin@hbouhuang.com China 3001 58
Hebei Zhuanglai Chemical Trading Co.,Ltd
+8613343047651
admin@zlchemi.com China 1516 58
Hebei Shengyang Water Conservancy Engineering Co., Ltd.
+8615373025980
clara@hbshengyang.com China 777 58

10543-57-4(N,N'-Ethylenbis[N-acetylacetamid])Verwandte Suche:


  • n,n’-1,2-ethanediylbis[n-acetyl-acetamid
  • N,N’-1,2-ethanediylbis[N-acetyl-Acetamide
  • N,N’-1,2-ethanediylbis[N-acetylacetamide]
  • N,N’-ethylenebis[N-acetylacetamide]
  • N-Acetyl-N-[2-(diacetylamino)ethyl]acetamide
  • TetraAcetylEthyleneDiamine(Taed)
  • Mykon ATC
  • Nikon A
  • 1,2-Bis(diacetylamino)ethane
  • Tetraacetylethylenediamine,90%
  • Tetraacetylethylenediamine,99.5+%
  • TETRAACETYLENEDIAMINE
  • N,N'-Ethylenbis-(N-acetylacetamid)
  • 1,2-Bis-(diacetamido)-ethane
  • N,N'-(ethane-1,2-diyl)bis(N-acetylacetaMide)
  • N,N,N',N'-Tetraacetylethylenediamine technical, >=90% (CHN)
  • N,N,N',N'-Tetraacetylethylenediamine≥ 90% (HPLC)
  • TETRACETYLETHYLENEDIAMINE
  • TETRAACETYLETHYLENEDIAMINE
  • N,N'-ETHYLENEBIS(DIACETAMIDE)
  • N,N,N',N'-TETRAACETYLETHYLENEDIAMINE
  • Acetamide, N,N'-1,2-ethanediylbis[N-acetyl-
  • TAED Tetraacetylethylenediamine
  • Tetraacetylethylenediamine ISO 9001:2015 REACH
  • Mikon ATC
  • Detergents Tetraacetylethylenediamine
  • TEAD
  • TAED
  • TAEG
  • N,N,N',N'-Tetraacetylethylenediamine
  • 10543-57-4
  • C10H16O4N2
  • Nitrogen Compounds
  • Organic Building Blocks
  • Protected Amines
  • Building Blocks
  • Daily Chemical Usage
  • bc0001
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