2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE
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- CAS-Nr.
- 39085-59-1
- Englisch Name:
- 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE
- Synonyma:
- TPSH;TRISYLHYDRAZIDE;TPSH, Trisylhydrazide;TRIISOPROPYLBENZENE SULFONYLHYDRAZIDE;2,4,6-TRIISOPROPYLBENZENESULFONOHYDRAZINE;2,4,6-triisopropylbenzenesulphonohydrazide;2,4,6-TRIISOPROPYLBENZENESULFONO-HYDRAZIDE;2,4,6-Triisopropylphenylsulfonyl hydrazine;2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE;2,4,6-Triisopropyl benzenesulphonohydrazine
- CBNumber:
- CB5753387
- Summenformel:
- C15H26N2O2S
- Molgewicht:
- 298.44
- MOL-Datei:
- 39085-59-1.mol
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2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE Eigenschaften
- Schmelzpunkt:
- 110-112 °C (dec.) (lit.)
- Siedepunkt:
- 396.6±52.0 °C(Predicted)
- Dichte
- 1.075
- storage temp.
- -20°C
- Löslichkeit
- Chloroform (Slightly), Methanol (Slightly)
- pka
- 9.51±0.10(Predicted)
- Aggregatzustand
- Solid
- Farbe
- Off-White
- Sensitive
- Moisture Sensitive
- BRN
- 2145001
- InChIKey
- GBQCDUBJTLROBV-UHFFFAOYSA-N
- CAS Datenbank
- 39085-59-1(CAS DataBase Reference)
2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE Chemische Eigenschaften,Einsatz,Produktion Methoden
S-Sätze Betriebsanweisung:
S22:Staub nicht einatmen.
S24/25:Berührung mit den Augen und der Haut vermeiden.
Chemische Eigenschaften
White crystal
Verwenden
2,4,6-Triisopropylbenzenesulfonyl hydrazide (TPSH) is a best source of diazene. It can be used as a selective reducing agent for the reduction of alkenes and other double bonds via in situ formation of diazene (diimide) in the presence of base. TPSH reduction method is efficiently used in the synthesis of polymers and natural products as it tolerates sensitive groups such as esters, ketones, or organometal complexes. It also undergoes condensation reaction with ketones and aldehydes to produce corresponding hydrazones that can be converted into reactive intermediates such as diazoalkanes, carbenes, carbenium ions, and alkyllithiums.
It can be used as a reagent to synthesize:
- Nitrogen-containing polycyclic compounds by intramolecular cyclopropanation of N-alkyl indoles/pyrroles.
- Vinyl sulfones by sulfonylation reaction of vinyl bromides.
- Nitrile derivatives from carbonyl compounds via formation of corresponding hydrazones.
2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
Global( 136)Lieferanten
39085-59-1()Verwandte Suche:
- TRISYLHYDRAZIDE
- TPSH
- TRIISOPROPYLBENZENE SULFONYLHYDRAZIDE
- 2,4,6-triisopropylbenzenesulphonohydrazide
- 2,4,6-Triisopropyl benzenesulphonohydrazine
- 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE
- 2,4,6-TRIISOPROPYL BENZENESULFONYL HYDRAZINE
- 2,4,6-TRIISOPROPYLBENZENESULFONO-HYDRAZIDE
- 2,4,6-TRIISOPROPYLBENZENESULFONOHYDRAZINE
- 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE 96+%
- TPSH, Trisylhydrazide
- 2,4,6-Triisopropylbenzene-1-sulfonic acid hydrazide
- 2,4,6-Triisopropylbenzenesulfonic acid hydrazide
- 2,4,6-Tris(1-methylethyl)benzenesulfonic acid hydrazide
- 2,4,6-Tris(isopropyl)benzenesulphonohydrazide 95%
- 2,4,6-Tris(prop-2-yl)benzenesulphonohydrazide, TPSH
- 2,4,6-Triisopropylphenylsulfonyl hydrazine
- 2,4,6-Triisopropylbenzenesulphonohydrazide 95%
- 2,4,6-Triisopropylbenzenesulfonyl hydrazide 90%
- 2,4,6-Triisopropylbenzenesulfonyl hydrazide≥ 95%(Titration)
- 2,4,6-tri(propan-2-yl)benzenesulfonohydrazide
- Benzenesulfonic acid, 2,4,6-tris(1-methylethyl)-, hydrazide
- 39085-59-1
- CH32CH3C6H2SO2NHNH2
- C15H26N2O2S
- Building Blocks
- Organic Building Blocks
- Sulfonyl Hydrazides
- Sulfur Compounds
- Building Blocks
- Chemical Synthesis
- Organic Building Blocks
- Sulfonyl Hydrazides
- Sulfur Compounds
