2-(Perfluorobutyl)ethyl acrylate
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- CAS-Nr.
- 52591-27-2
- Englisch Name:
- 2-(Perfluorobutyl)ethyl acrylate
- Synonyma:
- TEAc-4;DAIKIN R-1420;Perfluorobutylethyl acrylate;2-(Perfluorobutyl)ethyl acrylate;1H,1H,2H,2H-Nonafluorohexyl acrylate;1H,1H,2H,2H-Perfluorohexyl acrylate 97%;3,3,4,4,5,5,6,6,6-Nonafluorohexylacrylate;3,3,4,4,5,5,6,6,6-Nonafluorohexyl acrylate;Acrylic acid 2-(nonafluorobutyl)ethyl ester;Acrylic Acid 1H,1H,2H,2H-Nonafluorohexyl Ester
- CBNumber:
- CB9485109
- Summenformel:
- C9H7F9O2
- Molgewicht:
- 318.14
- MOL-Datei:
- 52591-27-2.mol
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2-(Perfluorobutyl)ethyl acrylate Eigenschaften
- Siedepunkt:
- 164 °C
- Dichte
- 1.414
- Brechungsindex
- 1.310
- Flammpunkt:
- 52 °C
- storage temp.
- Store at 2-8 ℃
- Löslichkeit
- Chloroform (Soluble), Ethyl Acetate (Slightly)
- Aggregatzustand
- clear liquid
- Farbe
- Colorless to Light yellow
- Wichte
- 1.440
- EPA chemische Informationen
- 1,1,2,2-Tetrahydroperfluorohexyl acrylate (52591-27-2)
Sicherheit
- Risiko- und Sicherheitserklärung
- Gefahreninformationscode (GHS)
| RIDADR |
UN 3272 3/PG III |
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| HazardClass |
3 |
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| PackingGroup |
III |
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| HS Code |
2916120090 |
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| Bildanzeige (GHS) |
 
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| Alarmwort |
Warnung |
| Gefahrenhinweise |
| Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
| H226 |
Flüssigkeit und Dampf entzündbar. |
Entzündbare Flüssigkeiten |
Kategorie 3 |
Warnung |
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| H315 |
Verursacht Hautreizungen. |
Hautreizung |
Kategorie 2 |
Warnung |
![GHS hazard pictograms]() src="/GHS07.jpg" width="20" height="20" /> |
P264, P280, P302+P352, P321,P332+P313, P362 |
| H319 |
Verursacht schwere Augenreizung. |
Schwere Augenreizung |
Kategorie 2 |
Warnung |
![GHS hazard pictograms]() src="/GHS07.jpg" width="20" height="20" /> |
P264, P280, P305+P351+P338,P337+P313P |
| H335 |
Kann die Atemwege reizen. |
Spezifische Zielorgan-Toxizität (einmalige Exposition) |
Kategorie 3 (Atemwegsreizung) |
Warnung |
![GHS hazard pictograms]() src="/GHS07.jpg" width="20" height="20" /> |
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| Sicherheit |
| P210 |
Von Hitze, heißen Oberflächen, Funken, offenen Flammen und anderen Zündquellenarten fernhalten. Nicht rauchen. |
| P280 |
Schutzhandschuhe/Schutzkleidung/Augenschutz tragen. |
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2-(Perfluorobutyl)ethyl acrylate Chemische Eigenschaften,Einsatz,Produktion Methoden
Verwenden
2-(Perfluorobutyl)ethyl Acrylate can be used as an acrylic resin surface modifier with high water repellency and oil repellency for coating agents. It can also be used in a super concentrated emulsion method to prepare a solid sheet polycarboxylic acid water reducing agent.
Application
2-(Perfluorobutyl)ethyl acrylate has been used in a wide range of scientific research applications. It has been used to create polymers for biomedical applications, such as drug delivery systems and tissue engineering scaffolds. It has also been used to create polymers for industrial applications, such as coatings and adhesives. In addition, it has been used to create polymers for energy applications, such as fuel cells and solar cells.
Synthese
1H,1H,2H,2H-nonafluoro-1-hexanol (52.8 g) as fluoro alcohol and triethylamine (50 g) were dissolved in 500 ml of tetrahydrofuran. A solution of 18.1 g of acryloyl chloride as acid chloride in 100 ml of tetrahydrofuran was dropped in this solution over 2 hours while the mixture was being cooled in ice and stirred. After the completion of the dropping, the resulting white precipitate was filtrated and tetrahydrofuran and triethylamine were removed from the filtrate using a rotary evaporator. NMR measurement revealed that the resulting compound was 1H,1H,2H,2H-nonafluorohexyl acrylate.
Research
Since the bioaccumulation of the degradation products of fluoropolymer with a long Rf side chain (C ≥ 8) has a potential environmental risk, it is necessary to design fluoropolymer coating with a short Rf side chain. Honda et al. studied the effect of α-substituent on the wetting behavior and molecular motion at the surfaces of poly{2-(perfluorobutyl)ethyl acrylate} [PFA-C4], poly{2-(perfluorobutyl)ethyl methacrylate} [PFMA-C4], poly{2-(perfluorobutyl)ethyl α-fluoroacrylate} [PFFA-C4], and poly{2-(perfluorobutyl)ethyl α-chloroacrylate} [PFClA-C4] films. In the case of PFA-Cy with long Rf groups [y ≥ 8], the mobility of the side chains is low at room temperature because of the crystallization of the Rf groups at the surface region[1].
2-(Perfluorobutyl)ethyl acrylate Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
2-(Perfluorobutyl)ethyl acrylate Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
Global( 107)Lieferanten
52591-27-2()Verwandte Suche:
Tris(trimethylsilyl)phosphat
Trinexapac-ethyl
Benzyl(purin-6-yl)amin
Ethylacetat
Ethanol
Ethylcyanacetat
Ethyl-4-hydroxybenzoat
Methylacrylat
Methylpropiolat
Perfluoroalkylethyl acrylate
Ethylacrylat
2-Propensäure
ISOXADIFEN-ETHYL
3,3,4,4,5,5,6,6,6-Nonafluorhexanol
3,3,4,4,5,5,6,6,6-Nonafluorhexylmethacrylat
Polyacrylate rubber
URETHANE ACRYLATE
- 1H,1H,2H,2H-Nonafluorohexyl Acrylate (stabilized with TBC)
- 1H,1H,2H,2H-Nonafluorohexyl Acrylate (stabilized with MEHQ)
- Perfluorobutylethyl acrylate
- 2-Propenoic acid 3,3,4,4,5,5,6,6,6-nonafluorohexyl ester
- 3,3,4,4,5,5,6,6,6-Nonafluorohexyl acrylate
- 3,3,4,4,5,5,6,6,6-Nonafluorohexylacrylate
- Acrylic acid 2-(nonafluorobutyl)ethyl ester
- Acrylic acid 3,3,4,4,5,5,6,6,6-nonafluorohexyl ester
- Propenoic acid 3,3,4,4,5,5,6,6,6-nonafluorohexyl ester
- 1H,1H,2H,2H-Perfluorohexyl acrylate 97%
- 2-(Perfluorobut-1-yl)ethyl acrylate, 3,3,4,4,5,5,6,6,6-Nonafluorohex-1-yl prop-2-enoate, TEAc-4
- DAIKIN R-1420
- 1H,1H,2H,2H-Nonafluorohexyl acrylate
- 2-(Perfluorobutyl)ethyl acrylate
- 3,3,4,4,5,5,6,6,6-Nonafluorohex-1yl acrylate 97%
- 1H,1H,2H,2H-Nonafluorohexyl Acrylate (stabilized with MEHQ)
- 9-formyl-3-hydroxy-6-oxo-7-(1-oxopentyl)-1-pentyl-2-benzo[b][1,4]benzodioxepincarboxylic acid
- 1H,1H,2H,2H-Nonafluorohexyl Acrylate (stabilized with MEHQ) >
- 2-Propenoic acid,3,3,4,4,5,5,6,6,6-nonafluorohexyl ester，>98.0%(GC)
- Acrylic Acid 1H,1H,2H,2H-Nonafluorohexyl Ester
- TEAc-4
- 52591-27-2
- C9H7F9O2
- Halogenated Heterocycles ,Isoquinolines ,Quinolines ,Quinaldines
