ChemicalBook >> CAS DataBase List >>(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine

(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine

CAS No.
144222-34-4
Chemical Name:
(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine
Synonyms
R-TS-DPEN;(R,R)-TSDPEN;(1R,2R)-TSDPE;(1R,2R)-TSDPEN;TIANFU-CHEM (R,R)-TsDPEN;(R,R)-TsDPEN (1R,2R)-(-)-N-;(1R,2R)-N-p-Toluenesulfonyl-1,2-diphe;(1R,2R)-(-)-N-(4-Toluenesulfonyl)-1,2-;(1R,2R)-N-P-TOSYL-1,2-DIPHENYLETHYLENE-D;(1R, 2R)-(-)-N-(4-Toluene sulfonyl)-DPEN
CBNumber:
CB1180813
Molecular Formula:
C21H22N2O2S
Molecular Weight:
366.48
MDL Number:
MFCD02093428
MOL File:
144222-34-4.mol
MSDS File:
SDS
Last updated:2024-04-08 17:36:13

(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine Properties

Melting point 128-131 °C(lit.)
Boiling point 537.3±60.0 °C(Predicted)
alpha -61.5 º (c=1, CH2Cl2)
Density 1.1440 (rough estimate)
refractive index -30 ° (C=0.4, CHCl3)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility Chloroform, Methanol
pka 10.76±0.50(Predicted)
form Crystals or Crystalline Powder
color White to slightly yellow
optical activity [α]20/D 35°, c = 1 in chloroform
Water Solubility insoluble
InChIKey UOPFIWYXBIHPIP-NHCUHLMSSA-N
CAS DataBase Reference 144222-34-4(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
HS Code  29215900
NFPA 704
0
2 0

(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine price More Price(44)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 484334 (1R,2R)-(?)-N-p-Tosyl-1,2-diphenylethylenediamine 98% 144222-34-4 1g $81 2024-03-01 Buy
TCI Chemical A1548 (R,R)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide >98.0%(T) 144222-34-4 1g $87 2024-03-01 Buy
Alfa Aesar H26061 (1R,2R)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine, 98+% 144222-34-4 1g $131.65 2024-03-01 Buy
Alfa Aesar H26061 (1R,2R)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine, 98+% 144222-34-4 5g $395.65 2024-03-01 Buy
Strem Chemicals 07-2371 (1R,2R)-(-)-N-(4-toluenesulfonyl)-1,2-diphenylethylenediamine, 98% (R,R)-TsDPEN 144222-34-4 500mg $61 2024-03-01 Buy
Product number Packaging Price Buy
484334 1g $81 Buy
A1548 1g $87 Buy
H26061 1g $131.65 Buy
H26061 5g $395.65 Buy
07-2371 500mg $61 Buy

(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine Chemical Properties,Uses,Production

Chemical Properties

white to slightly yellow crystals or crystalline

Uses

Chiral diamine ligand for cooperative metal-Bronsted acid catalyzed greener reductive amination using hydrogen gas.

Metal-Br?nsted Acid Cooperative Catalysis for Asymmetric Reductive Amination

Uses

(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine is used as a catalyst in stereoselective preparation of aromatic ketone derivatives as well as other chiral organic compounds.

General Description

This product has been enhanced for catalytic efficiency.

(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 265)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652 info@fdachem.com China 18225 58
airuikechemical co., ltd.
+undefined86-15315557071 sales05@airuikechemical.com China 994 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 forrest.lee@dakenchem.com China 15956 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21689 55
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Accela ChemBio Inc.
(+1)-858-699-3322 info@accelachem.com United States 19965 58
Shandong chuangyingchemical Co., Ltd.
18853181302 sale@chuangyingchem.com CHINA 5909 58
BOC Sciences
+1-631-485-4226 inquiry@bocsci.com United States 19553 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58

View Lastest Price from (1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(r,r)-tsdpen pictures 2024-04-08 (r,r)-tsdpen
144222-34-4
US $0.00-0.00 / Kg 1Kg 99.9% 200tons airuikechemical co., ltd.
(R,R)-N-(p-Toluenesulfonyl)-1,2-diphenylethylenediamine pictures 2024-01-04 (R,R)-N-(p-Toluenesulfonyl)-1,2-diphenylethylenediamine
144222-34-4
US $50.00-1.00 / kg 1kg 99 g-kg-tons,free sample is available Henan Fengda Chemical Co., Ltd
(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine pictures 2022-09-20 (1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine
144222-34-4
US $0.00-0.00 / kg 1kg 98% 1Ton Henan Aochuang Chemical Co.,Ltd.
  • (r,r)-tsdpen pictures
  • (r,r)-tsdpen
    144222-34-4
  • US $0.00-0.00 / Kg
  • 99.9%
  • airuikechemical co., ltd.

(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine Spectrum

(R,R)-N-(P-TOLUENESULFONYL)-1,2-DIPHENYLETHYLENEDIAMINE (R,R)-N-(2-AMINO-1,2-DIPHENYLETHYL)-P-TOLUENESULFONAMIDE (R,R)-TSDPEN (1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine (1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine98% (R,R)-Ts-DPEN, (1R,2R)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine, 98% Benzenesulfonamide,N-[(1R,2R)-2-amino-1,2-diphenylethyl]-4-methyl- (1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine≥ 99% (Assay, Chiral purity) (1R,2R)-N-p-Tosyl-1,2-diphenylethylenediamine,99%e.e. (1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediaMine 98% (1R,2R)-(-)-N-(4-toluenesulfonyl)-1,2-diphenylethylenediaMine,(R,R)-TsDPEN N-[(1R,2R)-2-Amino-1,2-diphenylethyl]-4-methylbenzenesulphonamide, (1R,2R)-1,2-Diphenyl-N-tosylethane-1,2-diamine N-[(1R,2R)-2-Amino-1,2-diphenylethyl]toluene-4-sulphonamide R-TS-DPEN BenzenesulfonaMide,N-[(1R,2R)-2-aMino-1,2-diphenyl )-N-p-Tosyl-1,2-diphenylethylenediaMine 98% (1R,2R)-(-)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediaMine, 98% 500MG (1R,2R)-(-)-N-(p-Tolylsulfonyl)-1,2-diphenylethylenediaMine (1R,2R)-1-AMino-2-tosylaMino-1,2-diphenylethane (1R,2R)-N-p-Toluenesulfonyl-1,2-diphe (1R,2R)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine (1R,2R)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine, 98+% (R,R)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine (1R,2R)-N-(P-TOLUENESULFONYL)-1,2-DIPHENYL-1,2-ETHANEDIAMINE (1R,2R)-TSDPEN (1R,2R)-(-)-N-P-TOSYL-1,2-DIPHENYLETHYLENEDIAMINE (1R, 2R)-(-)-N-(4-TOLUENE SULFONYL)1,2-DIPHENYL-1,2-ETHANE DIAMINE (1R,2R)-(-)-N-(4-TOLUENESULFONYL)-1,2-DIPHENYLETHYLENEDIAMINE (1R,2R)-(-)-N-(4-TOLUENESULPHONYL)-1,2-DIPHENYLETHYLENEDIAMINE N-((1R,2R)-2-amino-1,2-diphenylethyl)-4-methylbenzenesulfonamide (1R,2R)-N-P-TOSYL-1,2-DIPHENYLETHYLENE-D (1R,2R)-(-)-N-(4-toluenesulfonyl)-1,2-diphenylethylenediamine,98%(R,R)-TsDPEN (1R,2R)-(-)-N-(4-TOLUENESULFONYL)-1,2-DIPHENYL-1,2-ETHANEDIAMINEC21H22N2O2S (1R,2R)-1,2-Diamino-1,2-diphenyl-N1-(4-methylsulphonyl)ethane N-[(1R,2R)-2-Amino-1,2-diphenylethyl]-4-methylbenzenesulphonamide (R,R)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine, 98+% (1R,2R)-(-)-N-(4-Toluenesulfonyl)-1,2- (1R,2R)-(-)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine,98% (1R,2R)-N-p-Tosyl-1,2-diphenylethylenediami (1R,2R)-TSDPE [(1R,2R)-2-[(4-methylphenyl)sulfonylamino]-1,2-diphenylethyl]ammonium N-[(1R,2R)-2-amino-1,2-diphenylethyl]-4-methylbenzene-1-sulfonamide N-[(1R,2R)-2-Amino-1,2-diphenylethyl]toluene-4-sulfonamide (1R,2R)-(-)-N-(p-Toluenesulfonyl)-1,2-diphenylethylenediamine (R,R)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide > (R,R)-TsDPEN (1R,2R)-(-)-N- (1R, 2R)-(-)-N-(4-Toluene sulfonyl)-DPEN (1R,2R)-(-)-N-(4-toluenesulfonyl)-1,2-diphenylethylenediamine,98%,99%ee (1R,2R)-(-)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamin... TIANFU-CHEM (R,R)-TsDPEN (1R,2R)-(-)-N-(4-Toluenesulfonyl)-1,2-diphenylethylen (1R,2R)-(-)-N-(p-Tolylsulfonyl)-1,2-diphenylethylenediami (1R,2R)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine / R-DPEN Tos 144222-34-4 C21H22N2O2S Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents Hydrogenation