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(R)-(+)-N,N-DIMETHYL-1-PHENYLETHYLAMINE

CAS No.
19342-01-9
Chemical Name:
(R)-(+)-N,N-DIMETHYL-1-PHENYLETHYLAMINE
Synonyms
Nicotinamide Impurity 252;ALPHA,N,N-TRIMETHYLBENZYLAMINE;[(R)-α-Methylbenzyl]dimethylamine;(R)-N,N,alpha-trimethylbenzylamine;(r)-(+)-n,n,α-trimethylbenzylamine;(R)-1-Phenyl-N,N-dimethylethanamine;(R)-N,N-Dimethyl-l-phenylethanamine;(1R)-N,N-dimethyl-1-phenylethanamine;(R)-(+)-N,N-DIMETHYL-1-PHENETHYLAMINE;(R)-(+)-ALPHA-N,N-TRIMETHYLBENZYLAMINE
CBNumber:
CB1354214
Molecular Formula:
C10H15N
Molecular Weight:
149.23
MDL Number:
MFCD00008857
MOL File:
19342-01-9.mol
MSDS File:
SDS
Last updated:2023-05-25 18:00:59

(R)-(+)-N,N-DIMETHYL-1-PHENYLETHYLAMINE Properties

Melting point 143°C (estimate)
Boiling point 81 °C/16 mmHg (lit.)
Density 0.908 g/mL at 25 °C (lit.)
FEMA 4248 | N,N-DIMETHYLPHENETHYLAMINE
refractive index n20/D 1.503(lit.)
Flash point 148 °F
storage temp. 2-8°C
pka 8.88±0.50(Predicted)
form clear liquid
color Colorless to Light yellow
Odor at 0.10 % in propylene glycol. sweet fishy ammoniacal amine
Odor Type fishy
optical activity [α]20/D +50.2°, c = 1 in methanol
JECFA Number 1613
BRN 3030178
InChIKey BVURNMLGDQYNAF-SECBINFHSA-N
LogP 2.33
CAS DataBase Reference 19342-01-9(CAS DataBase Reference)
FDA UNII 13X1WU55OQ

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
8-10-23
HS Code  29214990
NFPA 704
2
3 1

(R)-(+)-N,N-DIMETHYL-1-PHENYLETHYLAMINE price More Price(11)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 242071 (R)-(+)-N,N-Dimethyl-1-phenylethylamine 97% 19342-01-9 1g $90.3 2023-06-20 Buy
TCI Chemical D1707 (R)-(+)-N,N-Dimethyl-1-phenylethylamine >98.0%(T) 19342-01-9 1mL $41 2024-03-01 Buy
TRC D457105 (R)-(+)-N,N-dimethyl-1-phenylethanamine 19342-01-9 1g $75 2021-12-16 Buy
Chem-Impex 37548 (R)-(+)-N,N-Dimethyl-1-phenylethylamine,≥98%(T) ≥98%(T) 19342-01-9 1ML $32.61 2021-12-16 Buy
AK Scientific V4063 (R)-(+)-N,N-dimethyl-1-phenylethanamine 19342-01-9 1mL $67 2021-12-16 Buy
Product number Packaging Price Buy
242071 1g $90.3 Buy
D1707 1mL $41 Buy
D457105 1g $75 Buy
37548 1ML $32.61 Buy
V4063 1mL $67 Buy

(R)-(+)-N,N-DIMETHYL-1-PHENYLETHYLAMINE Chemical Properties,Uses,Production

Chemical Properties

Colorless to yellow liquid; sweet fishy aroma.

Chemical Properties

clear colorless liquid

Purification Methods

The amine is mixed with aqueous 10N NaOH and extracted with toluene. The extract is washed with saturated aqueous NaCl, dried over K2CO3, and transferred to fresh K2CO3 until the solution is clear, and is filtered. The filtrate is distilled. If a short column packed with glass helices is used, the yield is reduced but a purer product is obtained. [Ingersoll Org Synth 25 89 1945, Snyder & Brewster J Am Chem Soc 71 291 4165 1949, Cope et al. J Am Chem Soc 71 3931 1949.] The (-)-picrate has m 140-141o from EtOH). The racemate [1126-71-2] has b 88-89o/16mm, 92-94o/30mm, 194-195o/760mm, d4 0.908. [Beilstein 13 III 2392.]

(R)-(+)-N,N-DIMETHYL-1-PHENYLETHYLAMINE Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)(+)-N N-DIMETHYL-ALPHA-PHENETHYLAMINE (R)-(+)-N,N-DIMETHYL-1-PHENETHYLAMINE (R)-(+)-N,N-DIMETHYL-1-PHENYLETHYLAMINE (R)-(+)-ALPHA-METHYL-N,N-DIMETHYLBENZYLAMINE (R)-(+)-ALPHA-N,N-TRIMETHYLBENZYLAMINE ALPHA,N,N-TRIMETHYLBENZYLAMINE (+)-N,N-Dimethyl[(R)-1-phenylethyl]amine (R)-1-Phenyl-N,N-dimethylethanamine (R)-N,N-Dimethyl-1-phenylethane-1-amine [(R)-α-Methylbenzyl]dimethylamine [R,(+)]-N,N,α-Trimethylbenzenemethanamine [R,(+)]-α-Methyl-N,N-dimethylbenzenemethanamine (R)-N,N,alpha-trimethylbenzylamine (R)-(+)-N,N-DIMETHYL-1-PHENETHYLAMINE, 9 7% Benzenemethanamine, N,N,.alpha.-trimethyl-, (.alpha.R)- (r)-(+)-n,n,α-trimethylbenzylamine (R)-(+)-N,N-Dimethyl-1-phenethylamine,99+% (R)-(+)-N,N-Dimethyl-1-phenylethylamine 97% (R)-(+)-N,N-Dimethyl-1-phenylethylamine (R)-(+)-N,N-dimethyl-1-phenylethanamine BenzeneMethanaMine, N,N,a-triMethyl-, (aR)- (1R)-N,N-dimethyl-1-phenylethanamine (R)-(+)-N,N-Dimethyl-1-phenylethylamine> Benzenemethanamine, N,N,α-trimethyl-, (αR)- (R)-N,N-Dimethyl-l-phenylethanamine Nicotinamide Impurity 252 19342-01-9 Asymmetric Synthesis Chiral Resolution Reagents Chiral Resolving Reagents