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(+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOL

CAS No.
137365-16-3
Chemical Name:
(+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOL
Synonyms
(+)-DINOL;(4S-trans)-2,2-di-me-A,A,A,A-tetra-2-nap -dioxo;(+)-2,3-O-isopropylidene-1,1,4,4-tetra (2-naph.)-D-threitol;(+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOL;(+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOL;(4s,5s)-2,2-dimethyl-α,α,α',α'-tetra(2-naphthyl)dioxolane-4,5-dimethanol;(+)-DINOL, (+)-2,3-O-Isopropylidene-1,1,4,4-tetra(2-naphthyl)-D-threitol;(4S,5S)-2,2-DiMethyl-α,α,α`,α`-tetra(2-naphthyl)-1,3-dioxolane-4,5-diMethanol;((4S,5S)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(di(naphthalen-2-yl)methanol);(4s-trans)-2,2-dimethyl-α,α,α',α'-tetra(2-naphthyl)-1,3-dioxolane-4,5-dimethanol
CBNumber:
CB1463840
Molecular Formula:
C47H38O4
Molecular Weight:
666.8
MDL Number:
MFCD00142323
MOL File:
137365-16-3.mol
MSDS File:
SDS
Last updated:2022-11-11 11:01:00

(+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOL Properties

Melting point 214-216 °C(lit.)
Density 1.269±0.06 g/cm3(Predicted)
storage temp. 2-8°C
pka 12.14±0.29(Predicted)
optical activity [α]20/D +116°, c = 1 in ethyl acetate
InChIKey QWADMRIAKWGVBF-CXNSMIOJSA-N

SAFETY

Risk and Safety Statements

WGK Germany  3
10

(+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOL price More Price(1)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
American Custom Chemicals Corporation CHM0004335 (+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA (2-NAPH)-D-THREITOL 95.00% 137365-16-3 1G $893.19 2021-12-16 Buy
Product number Packaging Price Buy
CHM0004335 1G $893.19 Buy

(+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOL Chemical Properties,Uses,Production

Uses

Reagent for the highly enantioselective addition of primary alkyl Grignards to ketones. Chiral auxiliary used for the asymmetric addition of nucleophiles to carbonyls.

(+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOL Preparation Products And Raw materials

Raw materials

Preparation Products

(+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOL Suppliers

Global( 15)Suppliers
Supplier Tel Email Country ProdList Advantage
LEAP CHEM CO., LTD.
+86-852-30606658 market18@leapchem.com China 24738 58
Energy Chemical 021-021-58432009 400-005-6266 sales8178@energy-chemical.com China 44700 61
Tianjin Derchemist Science & Technology Co., Ltd. 22-58627059 13920586291 zdcomcon@126.com China 3022 50
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51471 80
Shanghai Chiral bio-compound co., Ltd. 021-5068 3667/17749785980/1029026415; 17749785980 1029026415@qq.com China 2791 58
Shanghai Anyinuo Biomedical Technology Co., Ltd. 021-34625901 420970979@qq.com China 5751 58
Jiangsu aikang biomedical research and development co., LTD 025-66110311 13155353615 qzhang@aikonchem.com China 15527 58
Beijing Jin Ming Biotechnology Co., Ltd. 010-60605840 psaitong@jm-bio.com China 29778 58
Shanghai Haohong Scientific Co., Ltd. 400-400-8210725 malulu@leyan.com China 40041 58
Hangzhou Bingochem Co., Ltd. 0571-87632989 sales@bingochem.com China 21673 58
(4S,5S)-2,2-dimethyl-α4,α4,α5,α5-tetra-2-naphthalenyl-1,3-Dioxolane-4,5-dimethanol (+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOL (4S-TRANS)-2,2-DIMETHYL-ALPHA,ALPHA,ALPHA',ALPHA'-TETRA(2-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOL (4S,5S)-2,2-DIMETHYL-ALPHA,ALPHA,ALPHA',ALPHA'-TETRA(2-NAPHTHYL)DIOXOLANE-4,5-DIMETHANOL (+)-DINOL (+)-2,3-O-isopropylidene-1,1,4,4-tetra (2-naph.)-D-threitol (4S-trans)-2,2-di-me-A,A,A,A-tetra-2-nap -dioxo (4S-TRANS)-2,2-DI-ME-A,A,A',A'-TETRA-2-N AP -DIOXOLAN-DIMETHANOL, 98%(99% EE/HPLC (4S,5S)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetra(2-naphthyl)dioxolane-4,5-di (4s,5s)-2,2-dimethyl-α,α,α',α'-tetra(2-naphthyl)dioxolane-4,5-dimethanol (4s-trans)-2,2-dimethyl-α,α,α',α'-tetra(2-naphthyl)-1,3-dioxolane-4,5-dimethanol (+)-DINOL, (4S,5S)-2,2-Dimethyl-α,α,αμ,αμ-tetra(2-naphthyl)dioxolane-4,5-dimethanol, (+)-2,3-O-Isopropylidene-1,1,4,4-tetra(2-naphthyl)-D-threitol (+)-DINOL, (+)-2,3-O-Isopropylidene-1,1,4,4-tetra(2-naphthyl)-D-threitol (4S,5S)-2,2-DiMethyl-α,α,α`,α`-tetra(2-naphthyl)-1,3-dioxolane-4,5-diMethanol [(4S,5S)-5-[hydroxy(dinaphthalen-2-yl)Methyl]-2,2-diMethyl-1,3-dioxolan-4-yl]-dinaphthalen-2-ylMethanol 1,3-Dioxolane-4,5-dimethanol, 2,2-dimethyl-α4,α4,α5,α5-tetra-2-naphthalenyl-, (4S,5S)- (+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOL ((4S,5S)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(di(naphthalen-2-yl)methanol) (4S,5S)-2,2-dimethyl-α4,α4,α5,α5-tetra-2-naphthalenyl-1,3-Dioxolane-4,5-dimethanol 137365-16-3 Privileged Ligands TADDOLs Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents