[1R,(+)]-6,6',12'-Trimethoxy-2,2'-dimethyloxyacanthan-7-ol

CAS No.
10172-03-9
Chemical Name:
[1R,(+)]-6,6',12'-Trimethoxy-2,2'-dimethyloxyacanthan-7-ol
Synonyms
Limacusine;[1R,(+)]-6,6',12'-Trimethoxy-2,2'-dimethyloxyacanthan-7-ol;2H-1,24:12,15-Dietheno-6,10-metheno-16H-pyrido[2',3':17,18][1,10]dioxacycloeicosino[2,3,4-ij]isoquinolin-22-ol, 3,4,4a,5,16a,17,18,19-octahydro-9,21,25-trimethoxy-4,17-dimethyl-, (4aR,16aR)-
CBNumber:
CB42145958
Molecular Formula:
C37H40N2O6
Molecular Weight:
608.72
MDL Number:
MOL File:
10172-03-9.mol

[1R,(+)]-6,6',12'-Trimethoxy-2,2'-dimethyloxyacanthan-7-ol Properties

Melting point 235-7°C
Boiling point 709.7±60.0 °C(Predicted)
Density 1.204±0.06 g/cm3(Predicted)
pka 9.38±0.20(Predicted)

[1R,(+)]-6,6',12'-Trimethoxy-2,2'-dimethyloxyacanthan-7-ol price

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
American Custom Chemicals Corporation MTB0000958 LIMACUSINE 95.00% 10172-03-9 5MG $505.01 2021-12-16 Buy
Product number Packaging Price Buy
MTB0000958 5MG $505.01 Buy

[1R,(+)]-6,6',12'-Trimethoxy-2,2'-dimethyloxyacanthan-7-ol Chemical Properties,Uses,Production

Description

A second bisbenzylisoquinoline base from Limacia cuspidata (Miers.) Hook. f. et Thorn., the alkaloid is separated from the accompanying !imacine by chromato? graphy on a silica column. It crystallizes in colourless prisms from MeOH-Me2 CO and has [α]D + 110° (CHCI3). One hydroxyl group is present and the alkaloid yields the O-methyl ether as colourless needles, m.p. 210-2° C; [α]D + 90°, (CHCI3), shown to be identical with N-methyl-dihydroepistephanine B. The structure has been established by chemical interconversions with limacine and cuspidaline (q.v.).

References

Tomita, Furukawa., Tetrahedron Lett., 4293 (I 966)
Structure:
Tomita, Furukawa, Fukagawa., l. Pharm. Soc., lapan, 87,793 (I967)

[1R,(+)]-6,6',12'-Trimethoxy-2,2'-dimethyloxyacanthan-7-ol Preparation Products And Raw materials

Raw materials

Preparation Products

10172-03-9([1R,(+)]-6,6',12'-Trimethoxy-2,2'-dimethyloxyacanthan-7-ol)Related Search:

[1R,(+)]-6,6',12'-Trimethoxy-2,2'-dimethyloxyacanthan-7-ol Limacusine 2H-1,24:12,15-Dietheno-6,10-metheno-16H-pyrido[2',3':17,18][1,10]dioxacycloeicosino[2,3,4-ij]isoquinolin-22-ol, 3,4,4a,5,16a,17,18,19-octahydro-9,21,25-trimethoxy-4,17-dimethyl-, (4aR,16aR)- 10172-03-9