ChemicalBook >> CAS DataBase List >>Dimethyl (1-Diazo-2-oxopropyl)phosphonate
Dimethyl (1-Diazo-2-oxopropyl)phosphonate
- CAS No.
- 90965-06-3
- Chemical Name:
- Dimethyl (1-Diazo-2-oxopropyl)phosphonate
- Synonyms
- DIMETHYL (1-DIAZO-2-OXOPROPYL)PHOSPHONATE;Ohira-Bestmann reagent;1-Diazo-1-dimethoxyphosphoryl-propan-2-one;Dimethyl (acetyldiazomethyl)phosphonate;dimethyl 1-(1-diazo-2-oxopropyl)phosphonate;1-Diazoacetonylphosphonic Acid Dimethyl Ester;Dimethyl 1-Diazoacetonylphosphonate;Dimethyl (1-azoacetonyl)phosphonate;diMethyl(1-diazo-2-oxopropyl)phosphanate;dimethyl (2-oxopropanimidoyl)phosphonate
- CBNumber:
- CB8489377
- Molecular Formula:
- C5H9N2O4P
- Molecular Weight:
- 192.11
- MDL Number:
- MFCD07368360
- MOL File:
- 90965-06-3.mol
- MSDS File:
- SDS
Last updated:2023-10-19 16:48:45
| Density | 1.28 |
|---|---|
| refractive index | n20/D1.352-1.354 |
| Flash point | 2℃ |
| storage temp. | 2-8°C |
| solubility | Chloroform, Methanol (Slightly) |
| form | Oil |
| color | Pale Yellow to Yellow |
| Merck | 14,1177 |
| BRN | 4247670 |
| Stability | Light Sensitive |
| FDA UNII | 96G79J0LR6 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS02,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H225-H302+H312+H332-H319 | |||||||||
| Precautionary statements | P210-P280-P301+P312-P303+P361+P353-P304+P340+P312-P305+P351+P338 | |||||||||
| Hazard Codes | F,Xn | |||||||||
| Risk Statements | 11-20/21/22-36 | |||||||||
| Safety Statements | 16-26-36/37 | |||||||||
| RIDADR | UN 1648 3 / PGII | |||||||||
| WGK Germany | 3 | |||||||||
| HazardClass | 3 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29319090 | |||||||||
| NFPA 704 |
|
Dimethyl (1-Diazo-2-oxopropyl)phosphonate price More Price(25)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 742724 | Dimethyl (1-diazo-2-oxopropyl)phosphonate solution ~10% in acetonitrile (H-NMR), ≥96% (HPLC) | 90965-06-3 | 10ml | $487 | 2024-03-01 | Buy |
| TCI Chemical | D3546 | Dimethyl (1-Diazo-2-oxopropyl)phosphonate >97.0%(HPLC) | 90965-06-3 | 1g | $218 | 2024-03-01 | Buy |
| TCI Chemical | D3546 | Dimethyl (1-Diazo-2-oxopropyl)phosphonate >97.0%(HPLC) | 90965-06-3 | 5g | $696 | 2024-03-01 | Buy |
| TCI Chemical | D5048 | Dimethyl (1-Diazo-2-oxopropyl)phosphonate (10% in Acetonitrile) | 90965-06-3 | 5g | $106 | 2024-03-01 | Buy |
| TCI Chemical | D5048 | Dimethyl (1-Diazo-2-oxopropyl)phosphonate (10% in Acetonitrile) | 90965-06-3 | 25g | $306 | 2024-03-01 | Buy |
Dimethyl (1-Diazo-2-oxopropyl)phosphonate Chemical Properties,Uses,Production
Description
Dimethyl (1-diazido-2-oxopropyl)phosphonate is a liquid-added organophosphorus flame retardant with good solubility with water, common organic solvents, and inorganic salts flame retardants, with excellent flame retardant properties, low price and low additive amount and other advantages.
Chemical Properties
Light yellow liquid
Application
Dimethyl (1-diazo-2-oxopropyl)phosphonate can be used as a reagent for the synthesis of:
Ethynyl compounds (alkynes) from aldehydes.
Isoquinoline and pyridine N-oxides by cyclization with oximes in the presence of Rh catalyst.
Dimethyl(diazomethyl)phosphonate through methanolysis, which is further employed as a reagent in the synthesis of enol ethers or alkynes.
Five-member heterocyclic scaffolds of pyrazoles, triazoles, and oxazoles via cycloaddition reaction and multicomponent reaction.
Uses
Reagent for transformation of aldehydes to terminal alkynes and ketones to methyl enol ethers.
Synthesis
Dissolve NaH (0.67 g, 60% w/w, 16.75 mmol) in benzene (45 mL) and dry THF (15 mL). Cool the mixture on ice. A solution of dimethyl (2-oxopropyl) phosphonate (15.3 mmol) in dry benzene (15 mL) was added. A white solid was formed. The reaction mixture was stirred at room temperature for 1 hour. To the mixture was added a solution of toluidic acid hydrazide (16.23 mmol) in dry benzene (7.5 mL). The mixture was stirred at room temperature overnight. The mixture was filtered with Hyflo. The mixture was concentrated in a vacuum to give dimethyl (1-diazido-2-oxopropyl)phosphonate.
Dimethyl (1-Diazo-2-oxopropyl)phosphonate Preparation Products And Raw materials
Raw materials
Preparation Products
1-CHLORO-2-ETHYNYLBENZENE
N-Boc-propargylamine
tert-butyl 4-(prop-2-ynyl)piperidine-1-carboxylate
CYCLOHEXYLACETYLENE
4-Morpholinecarboxylic acid, 2-ethynyl-, 1,1-dimethylethyl ester, (2S)-
2-ETHYNYLTOLUENE 97
1-Ethynyl-2-phenylbenzene
3-NITROPHENYLACETYLENE
1-BROMO-3-ETHYNYL-BENZENE
4-Ethynylpyridine
1of4
Global( 229)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
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View Lastest Price from Dimethyl (1-Diazo-2-oxopropyl)phosphonate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2022-09-14 | Dimethyl (1-diazo-2-oxopropyl)phosphonate
90965-06-3
|
US $0.00-0.00 / KG | 1KG | 98% | 1Ton | Henan Aochuang Chemical Co.,Ltd. | |
 |
2019-07-06 | (1-DIAZO-2-OXO-PROPYL)-PHOSPHONIC ACID DIMETHYL ESTER
90965-06-3
|
US $1.00 / kg | 1kg | as customer's need | 1000kg | Career Henan Chemical Co |
-
- Dimethyl (1-diazo-2-oxopropyl)phosphonate
90965-06-3
- US $0.00-0.00 / KG
- 98%
- Henan Aochuang Chemical Co.,Ltd.
-
- (1-DIAZO-2-OXO-PROPYL)-PHOSPHONIC ACID DIMETHYL ESTER
90965-06-3
- US $1.00 / kg
- as customer's need
- Career Henan Chemical Co
90965-06-3(Dimethyl (1-Diazo-2-oxopropyl)phosphonate)Related Search:
(1-DIAZO-2-OXO-PROPYL)-PHOSPHONIC ACID DIMETHYL ESTER
(1-DIAZO-2-OXO-PROPYL)-PHOSPHONIC ACID DIMETHYL ESTER BESTMANN OHIRA REAGENT
Dimethyl 1-Diazoacetonylphosphonate
diMethyl(1-diazo-2-oxopropyl)phosphanate
(1-Diazo-2-oxopropyl)phosphonic Acid Dimethyl Ester
Dimethyl 1-Diazoacetonylphosphonate
1-Diazoacetonylphosphonic Acid Dimethyl Ester
Ohira-Bestmann Reagent
Phosphonic acid,P-(1-diazo-2-oxopropyl)-, diMethyl ester
Dimethyl (1-azoacetonyl)phosphonate solution
Dimethyl (1-diazo-2-oxopropyl)phosphonate solution
Dimethyl (acetyldiazomethyl)phosphonate solution
dimethyl (4-oxo-4,5-dihydro-3H-pyrazol-3-yl)phosphonate
Dimethyl (1-Diazo-2-oxopropyl)phosphonate (10% in Acetonitrile)
Dimethyl (1-diazo-2-oxo-prop-1-yl)phosphonate
Dimethyl (1-diazo-2-oxopropyl)-phosphonatephosphonate
Dimethyl (1-azoacetonyl)phosphonate
Dimethyl (1-diazo-2-oxopropyl)phosphonate≥ 98% (HPLC)
dimethyl (2-oxopropanimidoyl)phosphonate
Dimethyl (1-Diazo-2-oxopropyl)phosphonat
Dimethyl(1-Diazo-2-oxopropyl)phosphonate>
Dimethyl (1-diazo-2-oxopropyl)phosphonate, 97%, for synthesis
Dimethyl (1-Diazo-2-Oxopropyl)Phosphonate Solution,>98%
1-diazonio-1-dimethoxyphosphorylprop-1-en-2-olate
(1-Diazo-2-oxo-propyl)-phosphonic acid dimethyl ester, 99+%
(1Z)-1-diazonio-1-(dimethoxyphosphoryl)prop-1-en-2-olate
DIMETHYL (1-DIAZO-2-OXOPROPYL)PHOSPHONATE
1-Diazoacetonylphosphonic Acid Dimethyl Ester
Ohira-Bestmann reagent
1-Diazo-1-dimethoxyphosphoryl-propan-2-one
Dimethyl (acetyldiazomethyl)phosphonate
dimethyl 1-(1-diazo-2-oxopropyl)phosphonate
(S)-2-(Cyclohexylmethyl)succinicacid-4-methyl
ester
90965-06-3
90965-06-5
C5H9N2O4P