TETRAETHYLAMMONIUM PERCHLORATE

TETRAETHYLAMMONIUM PERCHLORATE 구조식 이미지
카스 번호:
2567-83-1
상품명:
TETRAETHYLAMMONIUM PERCHLORATE
동의어(영문):
etraethylazanium,perchlorate;Tetraethylaminium·perchlorate;tetraethylazanium,perchlorate;TETRAETHYLAMMONIUM PERCHLORATE;Tetraethylammonium perchlorate,98%;Tetraethylammonium perchlorate,95%;Tetraethylammonium Perchlorate >tetraethylammoniumperchlorate,[dry];n,n,n-triethyl-ethanaminiuperchlorate;N,N,N-Triethylethanaminium·perchlorate
CBNumber:
CB2278968
분자식:
C8H20ClNO4
포뮬러 무게:
229.7
MOL 파일:
2567-83-1.mol

TETRAETHYLAMMONIUM PERCHLORATE 속성

녹는점
>300°C
물리적 상태
Wet crystals
수용성
물, 아세톤, 아세토니트릴 및 디메틸 설폭사이드에 용해됩니다.
BRN
3638093
안정성
Unstable. Heating may lead to an explosion. Contact with combustible material may cause fire. Incompatible with reducing agents, organic materials, finely powdered metals, aluminium, sulfur, benzene, calcium hydride, charcoal, alkenes, ethanol, strontium hydride, sulfuric acid.
CAS 데이터베이스
2567-83-1(CAS DataBase Reference)
EPA
Tetraethylammonium perchlorate (2567-83-1)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi-O,Xi,O
위험 카페고리 넘버 8-5-44-36/37/38
안전지침서 47-37/39-26-17-36
유엔번호(UN No.) 1479
TSCA Yes
위험 등급 5.1
포장분류 II
HS 번호 29239000
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어:
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H272 화재를 강렬하게 함; 산화제 산화성 액체;산화성 고체 구분 2
구분 3
위험
경고
GHS hazard pictograms P210, P220, P221P280, P370+P378,P501
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고 GHS hazard pictograms
예방조치문구:
P220 의류 그리고 가연성 물질로부터 멀리하시오.
P221 가연성 물질과 혼합되지 않도록 조치하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P405 밀봉하여 저장하시오.
NFPA 704
0
3 1
OX

TETRAETHYLAMMONIUM PERCHLORATE C화학적 특성, 용도, 생산

화학적 성질

solid

용도

Tetraethylammonium perchlorate is used as supporting electrolyte in polarographic measurements.

일반 설명

White crystalline solid. May explode from heat, shock, or friction.

공기와 물의 반응

Water soluble.

반응 프로필

Oxidizing agents, such as TETRAETHYLAMMONIUM PERCHLORATE, can react with reducing agents to generate heat and products that may be gaseous (causing pressurization of closed containers). The products may themselves be capable of further reactions (such as combustion in the air). The chemical reduction of materials in this group can be rapid or even explosive, but often requires initiation (heat, spark, catalyst, addition of a solvent). Explosive mixtures of inorganic oxidizing agents with reducing agents often persist unchanged for long periods if initiation is prevented. Such systems are typically mixtures of solids, but may involve any combination of physical states. Some inorganic oxidizing agents are salts of metals that are soluble in water; dissolution dilutes but does not nullify the oxidizing power of such materials. Organic compounds, in general, have some reducing power and can in principle react with compounds in this class. Actual reactivity varies greatly with the identity of the organic compound. Inorganic oxidizing agents can react violently with active metals, cyanides, esters, and thiocyanates. Benzene, calcium hydride, charcoal, ethanol, finely divided metals, olefins, strontium hydride, sulfur react violently with perchlorates.

Purification Methods

Crystallise the perchlorate repeatedly from water, aqueous MeOH, acetonitrile or acetone, and dry it at 70o under a vacuum for 24hours. [Cox et al. J Am Chem Soc 106 5965 1984, Liu et al. J Am Chem Soc 108 1740 1986, White & Murray J Am Chem Soc 109 2576 1987.] It has also been crystallised twice from ethyl acetate/95% EtOH (2:1) [Lexa et al. J Am Chem Soc 109 6464 1987]. [Beilstein 4 IV 332.]

TETRAETHYLAMMONIUM PERCHLORATE 준비 용품 및 원자재

원자재

준비 용품


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