1-아다만테인카복실산
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1-아다만테인카복실산 속성
- 녹는점
- 172-174 °C (lit.)
- 끓는 점
- 253.08°C (rough estimate)
- 밀도
- 0.9976 (rough estimate)
- 굴절률
- 1.4910 (estimate)
- 저장 조건
- Sealed in dry,Room Temperature
- 용해도
- 에 용해됨클로로포름, 메탄올 (약간 용해됨)
- 물리적 상태
- 결정성 분말
- 산도 계수 (pKa)
- 4.86±0.20(Predicted)
- 색상
- 흰색에서 황백색까지
- 수용성
- 물에 불용성. 메탄올에 대한 용해도는 매우 희미한 탁도를 제공합니다. 에탄올, 클로로포름, 디클로로메탄에 용해됩니다.
- BRN
- 1910637
- InChI
- InChI=1S/C11H16O2/c12-10(13)11-4-7-1-8(5-11)3-9(2-7)6-11/h7-9H,1-6H2,(H,12,13)
- InChIKey
- JIMXXGFJRDUSRO-UHFFFAOYSA-N
- SMILES
- C12(C(O)=O)CC3CC(CC(C3)C1)C2
- CAS 데이터베이스
- 828-51-3(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
위험품 표기 | Xi | ||
---|---|---|---|
위험 카페고리 넘버 | 36/37/38 | ||
안전지침서 | 22-24/25-36-26 | ||
WGK 독일 | 3 | ||
RTECS 번호 | AU4452200 | ||
위험 참고 사항 | Irritant | ||
HS 번호 | 29162000 | ||
기존화학 물질 | 2008-2-25 |
1-아다만테인카복실산 C화학적 특성, 용도, 생산
화학적 성질
white to off-white crystalline powder용도
1-Adamantanecarboxylic acid can be used as:- A stabilizer in the synthesis of monodisperse, highly crystalline CoPt3?nanoparticles and porous platinum nanoparticles.
- An additive in polycondensation reactions to yield conjugated polymers as possible optoelectronic materials.
- An additive in the allylic substitution reaction, which is catalyzed by palladium in an aqueous medium.
Purification Methods
Possible impurities are trimethylacetic acid and C9 and C13 acids. Dissolve 15g of the acid in CCl4 (300mL) and shake with 110mL of 15N aqueous NH3 whereby the ammonium salt separates and is collected. Acid impurities form soluble ammonium salts. The salt is washed with cold Me2CO (20mL) and suspended in H2O (250mL). This is treated with 12N HCl and extracted with CHCl3 (100mL). The dried (Na2SO4) extract was evaporated and the residue was recrystallised from a mixture of MeOH (30mL) and H2O (ca 10mL) to give the pure acid (10-11g). [Koch & Haaf Org Synth Coll Vol V 20 1973.] It was also recrystallised from absolute EtOH and dried under vacuum at 100o. Alternatively, the acid (5g) is refluxed for 2hours with 15mL of MeOH and 2mL of 98% H2SO4 (cool when mixing this solution). Pour into 10 volumes of H2O and extract with the minimum volume of CHCl3 to give clear separation of phases. The extract is washed with H2O, dried (CaCl2) and distilled. The methyl ester is collected at 77-79o/1mm, m 38-39o. The ester is hydrolysed with the calculated amount of N KOH and refluxed until clear. Acidification with HCl provides the pure acid with 90% recovery. The amide crystallises from cyclohexane, m 189o. [Stetter et al. Chem Ber 92 1629 1959.] [Beilstein 9 IV 253.]1-아다만테인카복실산 준비 용품 및 원자재
원자재
준비 용품
1-아다만테인카복실산 공급 업체
글로벌( 491)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
---|---|---|---|---|---|
Huzhou Chenxi Environmental Protection Technology Co. , Ltd. | +8616762203950 |
1034385273@qq.com | China | 27 | 58 |
Henan Allgreen Chemical Co.,LTD | +86-37155567971 +86-13633837469 |
info@allgreenchem.com | China | 5986 | 58 |
Hebei Mojin Biotechnology Co., Ltd | +8613288715578 |
sales@hbmojin.com | China | 12468 | 58 |
Hebei Zhuanglai Chemical Trading Co.,Ltd | +8613343047651 |
admin@zlchemi.com | China | 2603 | 58 |
Hebei Shengyang Water Conservancy Engineering Co., Ltd. | +8615373025980 |
clara@hbshengyang.com | China | 783 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 |
sales@capotchem.com | China | 29797 | 60 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 |
info@dakenam.com | China | 15956 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21688 | 55 |
AB PharmaTech,LLC | 323-480-4688 |
United States | 989 | 55 | |
career henan chemical co | +86-0371-86658258 |
sales@coreychem.com | China | 29914 | 58 |
1-아다만테인카복실산 관련 검색:
시트르산 아다만탄 엽산 아세트산 글리신 1-아다만테인카복실산
1-Adamantanol
Amantadine
Altrenogest
Ascoric Acid
1-ADAMANTANECARBOXYLIC ACID ETHYL ESTER
AMANTANIUM BROMIDE
4-KETO-1-ADAMANTANECARBOXYLIC ACID,4-OXO-1-ADAMANTANECARBOXYLIC ACID
Bolmantalate
3-(ACETYLAMINO)-1-ADAMANTANECARBOXYLIC ACID,1-ACETYLAMINO-3-ADAMANTANECARBOXYLIC ACID
3-BROMO-1-ADAMANTANECARBOXYLIC ACID
3-Hydroxy-1-AdaMantane Carboxylic Acid
1-ADAMANTANECARBOXYLIC ACID CHLORIDE,1-ADAMANTANECARBOXYLIC ACID CHLOROANHYDRIDE