트리옥틸 인산염

트리옥틸 인산염
트리옥틸 인산염 구조식 이미지
카스 번호:
78-42-2
한글명:
트리옥틸 인산염
동의어(한글):
인산트리스(2-에틸헥실)에스터;트리스(2-에틸헥실)인산염;트리옥틸인산염;인산트리스(2-에틸헥실)에스터
상품명:
Tris(2-ethylhexyl) phosphate
동의어(영문):
TOP;TRIOCTYL PHOSPHATE;TEHP;TRIS(2-ETHYLHEXYL) PHOSPHATE;TRI(2-;AmgardTOF;flexoltof;Flexol TOF;NCI-C54751;kronitextof
CBNumber:
CB4670674
분자식:
C24H51O4P
포뮬러 무게:
434.63
MOL 파일:
78-42-2.mol
MSDS 파일:
SDS

트리옥틸 인산염 속성

녹는점
-70°C
끓는 점
215 °C4 mm Hg(lit.)
밀도
0.92 g/mL at 20 °C(lit.)
증기압
2.1 mm Hg ( 20 °C)
굴절률
n20/D 1.444(lit.)
인화점
>230 °F
저장 조건
Store below +30°C.
용해도
<0.001g/L
물리적 상태
액체
Specific Gravity
0.93
색상
무색
수소이온지수(pH)
7 (H2O, 20℃)
수용성
18°C에서 <0.1g/100mL
BRN
1715839
CAS 데이터베이스
78-42-2(CAS DataBase Reference)
NIST
2-Ethylhexanol phosphate (3:1)(78-42-2)
EPA
Tris(2-ethylhexyl) phosphate (78-42-2)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi
위험 카페고리 넘버 38
안전지침서 23-43-24/25
WGK 독일 2
RTECS 번호 MP0770000
자연 발화 온도 370 °C
TSCA Yes
HS 번호 29190090
유해 물질 데이터 78-42-2(Hazardous Substances Data)
독성 LD50 orally in Rabbit: 37000 mg/kg LD50 dermal Rabbit 20000 mg/kg
기존화학 물질 KE-34815
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
예방조치문구:
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P302+P352 피부에 묻으면 다량의 물로 씻으시오.
P332+P313 피부 자극이 생기면 의학적인 조치· 조언을 구하시오.
NFPA 704
0
1 0

트리옥틸 인산염 MSDS


Tris(2-ethylhexyl) phosphate

트리옥틸 인산염 C화학적 특성, 용도, 생산

화학적 성질

Tris(2-ethylhexyl) phosphate, a clear, viscous liquid, is used as a component of vinyl stabilizers, grease additives, and flame-proofing compositions; however, it is used primarily as a plasticizer for vinyl plastic and synthetic rubber compounds.
Tris(2-ethylhexyl) phosphate
Tris(2-ethylhexyl) phosphate has been employed as a specialty flameretardant plasticizer for vinyl compositions where low temperature flexibility is critical, eg, in military tarpaulins. It can be included in blends with general purpose plasticizers such as phthalate esters to improve low temperature flexibility.

용도

Solvent, antifoaming agent, plasticizer.

일반 설명

Clear colorless to pale yellow liquid with a slight sharp odor. Insoluble in water; Soluble in alcohol, acetone, and ether. Combustible.

반응 프로필

Tris(2-ethylhexyl) phosphate is incompatible with oxidizing materials. Tris(2-ethylhexyl) phosphate may soften or deteriorate certain plastics and elastomers. Tris(2-ethylhexyl) phosphate is incompatible with cellulose acetate and cellulose acetate butyrate.

위험도

Toxic by ingestion and inhalation.

Purification Methods

TEHP, in an equal volume of diethyl ether, is shaken with aqueous 5% HCl, and the organic phase is filtered to remove traces of pyridine (used as a solvent during manufacture) as its hydrochloride. This layer is shaken with aqueous Na2CO3, then water, and the ether is distilled off at room temperature. The ester is then filtered, dried for 12hours at 100o/15mm, and again filtered, then shaken intermittently for 2days with activated alumina (100g/L). It is decanted through a fine sintered-glass disc (with exclusion of moisture), and distilled under vacuum. [French & Muggleton J Chem Soc 5064 1957.] *Benzene can be used as a solvent (to give 0.4M solution) instead of ether. IR ( ): 1702, 1701, 481 and 478cm -1 [Bellamy & Becker J Chem Soc 475 1952]. The uranyl nitrate salt is purified by partial crystallisation from hexane [Siddall & Dukes J Am Chem Soc 81 790 1959, Siddall J Am Chem Soc 81 4176 1959]. [Beilstein 1 IV 1786.]

트리옥틸 인산염 준비 용품 및 원자재

원자재

준비 용품


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