2,2-비스(3-아미노-4-히드록시페닐)프로판

2,2-비스(3-아미노-4-히드록시페닐)프로판
2,2-비스(3-아미노-4-히드록시페닐)프로판 구조식 이미지
카스 번호:
1220-78-6
한글명:
2,2-비스(3-아미노-4-히드록시페닐)프로판
동의어(한글):
2,2-비스(3-아미노-4-히드록시페닐)프로판
상품명:
2,2-Bis(3-amino-4-hydroxyphenyl)propane
동의어(영문):
BHAPP;Oxyindene;4,4''-(Propane;4,4'-Isopropylidenebis(2-aminophenol);2-Bis(3-amino-4-hydroxyphenyl)propane;2,2-Bis(3-amino-4-hydroxyphenyl)propan;2,2-BIS-(3-AMINO-4-HYDROXYPHENYL)PROPANE;2,2-Bis(3-amino-4-hydroxylphenyl)propane;4,4'-(Propane-2,2-diyl)bis(2-aMinophenol);4,4'-(Propane-2,2-diyl)bis(2-aminophenol)
CBNumber:
CB81090679
분자식:
C15H18N2O2
포뮬러 무게:
258.32
MOL 파일:
1220-78-6.mol

2,2-비스(3-아미노-4-히드록시페닐)프로판 속성

녹는점
248-250 °C
끓는 점
471.1±45.0 °C(Predicted)
밀도
1.265±0.06 g/cm3(Predicted)
저장 조건
Keep in dark place,Inert atmosphere,Room temperature
용해도
soluble in Dimethylformamide
물리적 상태
powder to crystal
산도 계수 (pKa)
10.62±0.10(Predicted)
색상
흰색에서 노란색, 주황색으로
CAS 데이터베이스
1220-78-6(CAS DataBase Reference)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
HS 번호 29222990
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
예방조치문구:
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.

2,2-비스(3-아미노-4-히드록시페닐)프로판 C화학적 특성, 용도, 생산

개요

2,2-Bis(3-amino-4-hydroxyphenyl)propane (BAP) is a diamine organic compound that is used in the synthesis of polyimides.

용도

2,2-bis(4-hydroxy-3-aminophenyl)propane is used as a polyimide intermediate and functional monomer.

Synthesis

Synthesis_1220-78-6
Thedinitro compound (2) (10,000 g, 0.0314 mol) was heated to reflux inabsolute ethanol (100 mL) in the presence of wet 10% Pd/C catalyst(0.650 g). Hydrazine monohydrate (20 mL) was then added dropwiseover a period of 30 min, and the reaction was maintained at reflux for24 h. The hot solution was filtered through Celite to eliminate thecatalyst and partially concentrated under reduced pressure. Afterwards,the concentrate was poured into cold distilled water. The crude productwas filtered, washed with water, dried under vacuum and recrystallizedtwice from methanol to give (3). The diamino compound was obtainedas a white powder: yield: 88%; mp. 263 ??C (DSC); Analysis: Calculatedfor C15H18N2O2: C, 69.74%; H, 7.02%; N, 10.84%. Found: C, 69.35%;H, 7.15%; N, 11.02%. 1H NMR (400 MHz, DMSO-d6): |? (ppm); 8.57 (s,1H, OH), 6.43 (d, J=8.1 Hz, 1H, Har), 6.34 (d, J=1.8 Hz, 1H, Har),6.21 (dd, J=8.1 Hz, 1.8 Hz, 1H, Har), 4.23 (s, 2H, NH) 1.37 (s, 3H, CH3f). 13C NMR (100 MHz, DMSO-d6): |? (ppm) 142.4, 141.4, 135.4, 114.4,113.5, 113.4, 40.8, 30.9.

2,2-비스(3-아미노-4-히드록시페닐)프로판 준비 용품 및 원자재

원자재

준비 용품


2,2-비스(3-아미노-4-히드록시페닐)프로판 공급 업체

글로벌( 144)공급 업체
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Capot Chemical Co.,Ltd.
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008657128800458; +8615858145714
fandachem@gmail.com China 9340 55
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795
ivan@atkchemical.com China 32715 60
career henan chemical co
+86-0371-86658258
sales@coreychem.com China 29914 58

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