5,6,8,14-Tetradehydro-6-methoxy-17-methyl-2,3-[methylenebisoxy]morphinan-7β-ol

5,6,8,14-Tetradehydro-6-methoxy-17-methyl-2,3-[methylenebisoxy]morphinan-7β-ol 구조식 이미지
카스 번호:
4850-04-8
상품명:
5,6,8,14-Tetradehydro-6-methoxy-17-methyl-2,3-[methylenebisoxy]morphinan-7β-ol
동의어(영문):
Nudaurine;Amurinol I;5,6,8,14-Tetradehydro-6-methoxy-17-methyl-2,3-[methylenebisoxy]morphinan-7β-ol;Morphinan-7-ol, 5,6,8,14-tetradehydro-6-methoxy-17-methyl-2,3-[methylenebis(oxy)]-, (7β)- (9CI)
CBNumber:
CB92398326
분자식:
C19H21NO4
포뮬러 무게:
327.37
MOL 파일:
4850-04-8.mol

5,6,8,14-Tetradehydro-6-methoxy-17-methyl-2,3-[methylenebisoxy]morphinan-7β-ol 속성

녹는점
201-2°C
끓는 점
523.6±50.0 °C(Predicted)
밀도
1.38±0.1 g/cm3(Predicted)
산도 계수 (pKa)
12.41±0.40(Predicted)

안전

5,6,8,14-Tetradehydro-6-methoxy-17-methyl-2,3-[methylenebisoxy]morphinan-7β-ol C화학적 특성, 용도, 생산

개요

A morphine type alkaloid, this base is a minor constituent of the seeds of Papaver nudicaule var. amurense. It forms clusters of colourless crystals from Me2CO and has [α] 22 D - 52° (c 1.0, CHCI3). The salts are crystalline and include the hydriodide, m.p. 198°C (dec.); perchlorate, m.p. 188°C (dec.) and the picrate, m.p. 150°C (dec.). The structure given above has been determined on the basis of the infrared, NMR and mass spectra.

참고 문헌

Boit, Flentje., Naturwiss., 47,180 (1960)
Flentje, Dopke, Jeffs., ibid, 52,259 (1965)
Dopke, Flentje, Jeffs., Tetrahedron, 24,4459 (1968)
Absolute configuration: Barton et ai., Chern. Ber., 100,2457 (1967)
Circular dichroism: Snatzke, Wollenberg.,!. Chern. Soc., C, 1581 (1966)

5,6,8,14-Tetradehydro-6-methoxy-17-methyl-2,3-[methylenebisoxy]morphinan-7β-ol 준비 용품 및 원자재

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