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ChemicalBook >> CAS DataBase List >>Chlorosulfonic acid

Chlorosulfonic acid suppliers

Chlorosulfonic acid

CAS:
7790-94-5
MF:
ClHO3S
MW:
116.52

Company Type

Properties

Melting point:
-80°C
Boiling point:
151-152 °C/755 mmHg (lit.)
Density 
1.753 g/mL at 25 °C (lit.)
vapor density 
4 (vs air)
vapor pressure 
1 mm Hg ( 25 °C)
refractive index 
n20/D 1.433(lit.)
Flash point:
158°C
storage temp. 
Room Temperature, under inert atmosphere
solubility 
Miscible with hydrocarbons.
form 
Oily Liquid, Fuming In Air
pka
-6.49±0.15(Predicted)
Specific Gravity
1.753
color 
Yellow to brown
PH Range
1
Water Solubility 
reacts
Sensitive 
Moisture Sensitive
Merck 
14,2165
Stability:
Stable, but reacts violently with water. In case of spills, mop up with sand - do not add water. Reacts with most metals to yield (flammable) hydrogen gas. Incompatible with strong bases, carbonates, water, combustible materials, strong oxidizing agents, most metals, organic materials, sulfides, cyanides, carbides.
LogP
-0.003 at 25℃

Safety Information

Symbol(GHS) 
GHS hazard pictogramsGHS hazard pictograms
GHS05,GHS06
Signal word 
Danger
Hazard statements 
H314-H330-H335
Precautionary statements 
P260-P271-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes 
C
Risk Statements 
14-35-37
Safety Statements 
26-45
RIDADR 
UN 1754 8/PG 1
WGK Germany 
1
RTECS 
FX5730000
TSCA 
Yes
HazardClass 
8
PackingGroup 
I
HS Code 
28062000

Use

Chlorosulfonic acid is a strong oxidizing acid. Reacts violently with water, strong mineral acids and bases, alcohols, finely dispersed organic matter. Dangerously incompatible with combustible materials, nitrates, chlorates, metallic powders, carbides, picrates, and fulminates. Undergoes possibly violent reactions with acetic acid, acetic anhydride, acetonitrile, acrolein, acrylic acid, acrylonitrile, alkali, allyl alcohol, allyl chloride, ammonium hydroxide, aniline, butyraldehyde, cresol, cumene, diethyleneglycol methyl ether, diisopropyl ether, diphenyl ether, ethyl acetate, ethyl acrylate, ethylene chlorohydrin, ethylenediamine, ethylene glycol, glyoxal, hydrocarbons (hexane, heptane), hydrogen peroxide, isoprene, powdered metals, methyl ethyl ketone, propylene oxide, vinyl acetate. When heated to decomposition, Chlorosulfonic acid emits toxic fumes of hydrogen chloride and oxides of sulfur [Sax, 9th ed., 1996, p. 831]. Reaction with phosphorus accelerates out of control and culminates in an explosion [Heumann, K. et al., Ber., 1882, 15, p. 417]. Mixing chlorosulfuric acid and 98% sulfuric acid may evolve HCl [Subref: Anon, Loss Prev. Bull. 1977, (013), 2-3].

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