silver picrate

silver picrate Basic information
Product Name:silver picrate
Synonyms:silver picrate;Picragol;Picrotol;Silver trinitrophenolate;Silver(I) 2,4,6-trinitrophenolate;Silver(I)2,4,6-trinitrophenolate;Nsc168933;Phenol, 2,4,6-trinitro-, silver(1+) salt
CAS:146-84-9
MF:C6H2AgN3O7
MW:335.96418
EINECS:205-682-5
Product Categories:
Mol File:146-84-9.mol
silver picrate Structure
silver picrate Chemical Properties
solubility slightly soluble in H2O, ethanol; insoluble in chloroform,ethyl ether
form yellow crystals
color yellow crystals, crystalline
Water Solubility soluble ~50 parts H2O; slightly soluble alcohol; insoluble CHCl3, ether [MER06]
CAS DataBase Reference146-84-9
EPA Substance Registry SystemPhenol, 2,4,6-trinitro-, silver(1+) salt (146-84-9)
Safety Information
RIDADR UN 1347 4.1/ PGI
HazardClass 4.1
PackingGroup I
MSDS Information
silver picrate Usage And Synthesis
Chemical PropertiesSilver picrate is a yellow powder or crystalline material which turns brown when heated or exposed to light. Commercial product is a white to light tan solid paste. Contains about 35% water, which reduces its tendency toward rapid decomposition or explosion. Considered safe for storage, handling and shipping, but should be treated as an explosive.
Chemical PropertiesYellow crystals containing 30% silver, soluble in water. Slightly soluble in alcohol and acetone; insoluble in ether and chloroform.
UsesMedicine (antimicrobial agent).
General DescriptionA white to light colored solid paste. Contains about 35% water, which reduces its tendency toward rapid decomposition or explosion. Considered safe for storage, handling and shipping, but should be treated as an explosive. Contact may cause irritation to skin, eyes, and mucous membranes. May be toxic by ingestion.
Air & Water ReactionsWater soluble [Hawley].
Reactivity Profilesilver picrate may be ignited by heat, sparks or flames. The DRIED OUT material may explode if exposed to heat, flame, friction or shock.
HazardSevere explosion risk. Very toxic.
Health HazardSome are toxic and may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may cause pollution.
Safety ProfileA flammable solid and unstable substance forbidden from transport. When heated to decomposition it emits toxic vapors of NOx.
Potential ExposureUsed in antibacterial medicines.
ShippingUN1347 Silver picrate, wetted with not ,30 % water, by mass, Hazard Class: 4.1; Labels: 4.1-Flammable solid.
IncompatibilitiesOrganics or other oxidizable materials. Dried out material is unstable and a severe explosion risk; protect from shock, light, and vibration.
silver picrate Preparation Products And Raw materials
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