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Ethylene carbonate

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CAS:96-49-1
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CAS:96-49-1
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  • Synthesis of Ethylene carbonate
  • Ethylene carbonate (sometimes abbreviated EC) is the organic compound with the formula (CH 2 O) 2 CO. It is classified as the ....
  • Feb 7,2022
Ethylene carbonate Basic information
Product Name:Ethylene carbonate
Synonyms:carbonicacid,ethyleneester;Cyclic ethylene carbonate;Cyclic ethylene ester;cyclicethylenecarbonate;Dioxolone-2;Ethylene glycol, cyclic carbonate;ethylenecarbonicacid;ethyleneglycol,cycliccarbonate
CAS:96-49-1
MF:C3H4O3
MW:88.06
EINECS:202-510-0
Product Categories:Pyridines;Aluminum Bottles;Building Blocks;Carbonates;Carbonyl Compounds;Chemical Synthesis;Heterocyclic Building Blocks;O-Containing;Organic Building Blocks;Others;Solvent Bottles;Solvent Packaging Options;Solvents;Dioxanes & Dioxolanes;Dioxolanes;API intermediates;Intermediates of Dyes and Pigments;bc0001;96-49-1
Mol File:96-49-1.mol
Ethylene carbonate Structure
Ethylene carbonate Chemical Properties
Melting point 35-38 °C(lit.)
Boiling point 243-244 °C740 mm Hg(lit.)
density 1.321 g/mL at 25 °C(lit.)
vapor density 3.04 (vs air)
vapor pressure 0.02 mm Hg ( 36.4 °C)
refractive index 1.4199
Fp 320 °F
storage temp. Store below +30°C.
solubility H2O: 1 M at 20 °C, clear, colorless
pka3.86[at 20 ℃]
form Crystalline Low Melting Solid
Specific Gravity1.321
color White to yellow
PH7 (200g/l, H2O, 20℃)
Odorodorless
explosive limit3.6-16.1%(V)
Water Solubility 214 g/L (20 ºC)
BRN 106249
Dielectric constant69.4(91℃)
Stability:Stable. Incompatible with strong oxidizing agents, acids, bases, reducing agents.
InChIKeyKMTRUDSVKNLOMY-UHFFFAOYSA-N
LogP0.11 at 20℃
CAS DataBase Reference96-49-1(CAS DataBase Reference)
NIST Chemistry ReferenceEthylene carbonate(96-49-1)
EPA Substance Registry SystemEthylene carbonate (96-49-1)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38-41
Safety Statements 26-36-39
RIDADR UN 2265 3 / PGIII
WGK Germany 1
RTECS FF9550000
Autoignition Temperature465 °C
TSCA Yes
HS Code 29209010
Hazardous Substances Data96-49-1(Hazardous Substances Data)
ToxicityLD50 orally in Rabbit: > 5000 mg/kg LD50 dermal Rabbit > 2000 mg/kg
MSDS Information
ProviderLanguage
1,3-Dioxolan-2-one English
SigmaAldrich English
ACROS English
ALFA English
Ethylene carbonate Usage And Synthesis
Chemical Propertiescolourless crystals
UsesSolvent for many polymers and resins, plasticisers, rubbers and textiles.Ethylene carbonate is used as a polar solvent and a high permittivity component of electrolytes in lithium batteries. It finds application in surface coatings, dyes, fibers and plastics. It is also used as a plasticizer and as a precursor to vinylene carbonate. Further, it is used in the preparation of dimethyl carbonate, which acts as a useful solvent and a mild methylating agent.
UsesEthylene carbonate has been used:
In the synthesis of aliphatic polyurethanes using diamines and diols.
As a precursor for ring-opening polymerization using KOH as initiator.
As a reactant in the preparation of dimethyl carbonate, glycerol carbonate by transesterification reaction.
UsesEthylene carbonate is an ester of ethylene glycol and carbonic acid. Ethylene carbonate is used as a polar solvent with a molecular dipole moment of 4.9 D, only 0.1 D lower than that of propylene carb onate. It can be used as a high permittivity component of electrolytes in lithium batteries.
DefinitionChEBI: Ethylene carbonate is a carbonate ester.
Flammability and ExplosibilityNon flammable
Purification MethodsDry 1,3-dioxolan-2-one over P2O5, then fractionally distil it at low or atmospheric pressure. Recrystallise it from dry Et2O (plates, m 36.5o, 38.5-40o was also reported). It is soluble in H2O. [Beilstein 19 II 135,19 III/IV 1556, 19/4 V 6.]
Tag:Ethylene carbonate(96-49-1) Related Product Information
Ethylene glycol Propylene carbonate Ammonium carbonate Calcium carbonate Zinc carbonate Vinylene carbonate Sodium carbonate Diethyl carbonate Dimethyl carbonate Vinyl ethylene carbonate (4-ethenyl-1,3-dioxolan-2-one),Vinyl Ethylene Carbonate Vinyl acetate Polycarbonate Barium carbonate ETHYLENE Dehydroacetic acid Phenyl salicylate ALLYL PHENYL CARBONATE 97 Rubidium carbonate