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J & K SCIENTIFIC LTD.
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| Products Intro: |
Product Name:1-piperidin-2-ylacetone (SALTDATA: FREE)
CAS:4396-01-4
Purity:95% Package:10G,1G,5G
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| | pelletierine Basic information |
| Product Name: | pelletierine | | Synonyms: | pelletierine;2-Acetonylpiperidinepunicineisopelletierine, (.+/-.)-pelletierine;isopelletierine;1-(2-Piperidinyl)-2-propanone;1-(2-Piperidyl)-2-propanone;2-(2-Oxopropyl)piperidine;1-piperidin-2-ylpropan-2-one;1-piperidin-2-ylacetone(SALTDATA: 0.15H2O) | | CAS: | 4396-01-4 | | MF: | C8H15NO | | MW: | 141.21 | | EINECS: | 224-523-0 | | Product Categories: | | | Mol File: | 4396-01-4.mol |  |
| | pelletierine Chemical Properties |
| Melting point | 130-132 °C | | Boiling point | 195 °C | | density | 0.918±0.06 g/cm3(Predicted) | | storage temp. | Hygroscopic, -20°C Freezer, Under inert atmosphere | | solubility | Chloroform (Slightly), Ethyl Acetate (Slightly) | | form | Oil | | pka | pK1:9.45 (15°C) | | color | Colourless to Light Yellow | | Stability: | Hygroscopic |
| | pelletierine Usage And Synthesis |
| Description | An alkaloid of this name was discovered by Tanret but when this alkaloid was
shown to be (±)-pelletierine, the name was adopted for this particular base
isolated from Punica granatum. The alkaloid is an oily liquid which yields a
number of well crystalline salts and derivative: the hydrochloride, m.p. 143°C;
hydrobromide, m.p. 149°C; picrate, m.p. 147 -8°C and the picrolonate, m.p. 185-6°C. The N-acetyl derivative is an oily liquid, b.p. 110-5°C/0.I mm while
the N-benzoyl compound is crystalline with m.p. 72-4°C. The alkaloid may be
prepared by the demethylation of methylisopelletierine, the action being revers_x0002_ible. | | Definition | ChEBI: Pelletierine is a citraconoyl group. | | References | Tanret., Compt. rend., 88, 716 (1879)
Tanret., ibid, 90, 696 (1880)
Hesse., Rev. trav. Chim., 52, 1005 (1919)
Hess, Littman., Annalen, 494, 7 (1932)
Wibaut, Kloppenburg, Beets., Rev. trav. Chim., 63, 134 (1944)
Anet, Hughes, Ritchie., Nature, 164, 50 I (1949)
Galinovsky, Branchetti, Vogl.,Monatsh., 84, 1221 (1953)
Galinovsky, Hollinger., ibid, 85, 1012 (1954)
Wibaut, Hirschel., Rev. trav. Chim., 75,225 (1956) |
| | pelletierine Preparation Products And Raw materials |
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