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| (R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Basic information | Reaction |
| (R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Chemical Properties |
Melting point | 218-220°C (dec.) | alpha | -412° ±15° (c 0.5, CHCl3) | storage temp. | Inert atmosphere,Room Temperature | solubility | Chloroform, Methanol | form | Powder | color | Orange |
| (R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Usage And Synthesis |
Reaction |
- Ligand for Palladium-catalyzed amination of aryl halides
- Ligand for Rhodium-catalyzed asymmetric alcoholysis and aminolysis of oxabenzonorbornadiene
- Ligand for Rhodium-catalyzed asymmetric ring opening of oxabicyclic alkenes with organoboronic acids
- Ligand for Copper-catalyzed asymmetric 1,4-hydrosilylations of α,β-unsaturated esters
- Ligand for Ruthenium-catalyzed asymmetric hydrogenation of N-sulfonated-α-dehydroamino acids
- Ligand for Rhodium-catalyzed asymmetric hydrogenation of enamines
- Ligand for Palladium-catalyzed Kumada coupling of aryl and vinyl tosylates
- Ligand for Palladium-catalyzed enantioselective synthesis of aryl sulfoxides
- Ligand for Rhodium-catalyzed enantioselective insertion of a carbenoid carbon into a C-C bond
| Chemical Properties | Orange powder | Uses | It may be used as a ligand in the palladium-catalyzed alkoxycarbonylation of 6-bromo-1,4-benzodioxane with sodium tert-butoxide to form the corresponding tert-butyl ester. | General Description | (R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine (PPF-tBu) is a chiral ferrocenyl diphosphine ligand. |
| (R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Preparation Products And Raw materials |
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