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Ethyl chrysanthemumate

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Products Intro: Product Name:Ethyl chrysanthemumate
CAS:97-41-6
Purity:99% Package:25KG
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Products Intro: Product Name:Ethyl chrysanthemumate
CAS:97-41-6
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CAS:97-41-6
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Products Intro: Product Name:L.C. Acid (2,2-Dimethyl-3-Trifloro Propenyl Cyclopropane Carbolic Acid)
CAS:97-41-6
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Products Intro: Product Name:Ethyl chrysanthemumate
CAS:97-41-6
Purity:99% Package:5KG;1KG Remarks:C12H20O2

Ethyl chrysanthemumate manufacturers

  • Ethyl chrysanthemumate
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  • $0.00 / 25KG
  • 2023-06-20
  • CAS:97-41-6
  • Min. Order: 1KG
  • Purity: 99%
  • Supply Ability: 50000KG/month
Ethyl chrysanthemumate Basic information
Product Name:Ethyl chrysanthemumate
Synonyms:2,2-DIMETHYL-3-(2-METHYL-1-PROPENYL)CYCLOPROPANE CARBOXYLIC ACID ETHYL ESTER;2,2-DIMETHYL-3-(1-ISOBUTENYL)CYCLOPROPANE-1-CARBOXYLIC ACID ETHYL ESTER;ethyl 2,2-dimethyl-3-(2-methylpropenyl)cyclopropanecarboxylate;CHRYSANTHEMUM MONOCARBOXYLIC ACID ETHYL ESTER;CHRYSANTHEMYLMONOCARBOXYLIC ACID ETHYL ESTER;ETHYL CHRYSANTHEMUMATE;ETHYL 2,2-DIMETHYL-3-(1-ISOBUTENYL)CYCLOPROPANE-1-CARBOXYLATE;ETHYL 2,2-DIMETHYL-3-(2-METHYL-1-PROPENYL)CYCLOPROPANECARBOXYLATE
CAS:97-41-6
MF:C12H20O2
MW:196.29
EINECS:202-579-7
Product Categories:Cyclopropanes;Simple 3-Membered Ring Compounds;Pharmaceutical Intermediates;3
Mol File:97-41-6.mol
Ethyl chrysanthemumate Structure
Ethyl chrysanthemumate Chemical Properties
Boiling point 112 °C10 mm Hg(lit.)
density 0.906 g/mL at 25 °C(lit.)
refractive index n20/D 1.461(lit.)
Fp 184 °F
storage temp. 2-8°C
solubility Chloroform (Slightly), Methanol (Slightly)
form Liquid
color Yellow
Odorat 10.00 % in dipropylene glycol. herbal wine fruity everlasting flower chrysanthemum sweet
Odor Typeherbal
BRN 2045740
LogP4.181 (est)
CAS DataBase Reference97-41-6(CAS DataBase Reference)
NIST Chemistry ReferenceEthyl chrysanthemate(97-41-6)
EPA Substance Registry SystemCyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1-propenyl)-, ethyl ester (97-41-6)
Safety Information
Safety Statements 24/25
WGK Germany 2
RTECS GZ1727000
TSCA Yes
HS Code 29162090
MSDS Information
Ethyl chrysanthemumate Usage And Synthesis
Chemical Propertiesclear colorless to yellow liquid
UsesEthyl Chrysanthemate is an organic building block used in the synthesis of various chemical compounds, such as insecticide, Resmethrin (R144685). It is used in the preparation of trans-norchrysanthemates and trans-norpyrethrates, having insecticidal activity.
Synthesis Reference(s)Tetrahedron Letters, 22, p. 1783, 1981 DOI: 10.1016/S0040-4039(01)90438-1
Synthesis, p. 600, 1976 DOI: 10.1055/s-1976-24132
Purification MethodsPurify the ester by vacuum distillation. The free trans-acid has m 54o (from EtOAc), and the free cis-acid has m 113-116o (from EtOAc). The 4-nitrophenyl ester has m 44-45o (from pet ether) [Campbell & Harper J Chem Soc 283 1945, IR: Allen et al. J Org Chem 22 1291 1957]. [Beilstein 9 II 45.]
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