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| | Chloro[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]gold(I) Basic information | | Reaction |
| Product Name: | Chloro[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]gold(I) | | Synonyms: | Chemical Name：Chloro[1,3-bis(mesityl)imidazole-2-ylidene]gold(I);Chloro[1,3-bis(mesityl)imidazole-2-ylidene]gold(I);Chloro(1,3-dimesityl-1H-imidazol-2(3H)-ylidene)aurate(I);IMesAuCl;CHLORO[1,3-BIS(2,4,6-TRIMETHYLPHENYL)2H-IMIDAZOL-2-YLIDENE]GOLD(I),98%;Chloro[1,3-bis(2,4,6-trimethylphenyl)2H-imidazol-2-ylidene]gold(I), 98%;1,3-bis(2,4,6-trimethylphenyl)2H-imidazol-2-ylidene]gold(I)Chloro;oro[1,3-bis(2,4,6-trimethyL | | CAS: | 852445-81-9 | | MF: | C21H24AuClN2 | | MW: | 536.84821 | | EINECS: | | | Product Categories: | | | Mol File: | 852445-81-9.mol | ![Chloro[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]gold(I) Structure](CAS/20180906/GIF/852445-81-9.gif) |
| | Chloro[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]gold(I) Chemical Properties |
| Melting point | >300 °C | | storage temp. | 2-8°C | | form | Powder | | color | white | | Sensitive | air sensitive |
| | Chloro[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]gold(I) Usage And Synthesis |
| Reaction |
- Catalyst for the rearrangement of alkynyl sulfoxides to benzothiepinones
- Catalyst for the rearrangement of homopropargylic ethers to α,β-unsaturated carbonyl compounds
- Catalyst for oxidative cyclopropanation of N-Allylynamides to 3-aza-bicyclo[3.1.0]-hexan-2-one derivatives
- Catalyst for oxidative rearrangement of homopropargylic ethers to cyclobutanones
| | Description | Chloro[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]gold(I), also known as [(IMes)AuCl], is an useful organometallic catalyst. Organometallics are useful reagents, catalysts, and precursor materials with applications in thin film deposition, industrial chemistry, pharmaceuticals, LED manufacturing, and others.
| | Chemical Properties | White powder | | Uses | Gold Catalysts — 21st Century ′Gold Rush′ | | Preparation | Ag2O (0.5 mmol) was added to the CH2Cl2 solution of 1,3-bis(mesityl)imidazolium chloride (1mmol). After stirring at room temperature for 3 hours, the suspension becomes clear. Then drop 1mmol of Me2SAuCl solution into CH2Cl2 and stir for 4 hours. After the mixture is filtered through Celite, the solvent is evaporated. Hexane is added to the remaining mixture and filtered to obtain Chloro[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]gold(I).![Chemical Name：Chloro[1,3-bis(mesityl)imidazole-2-ylidene]gold(I)](/NewsImg/2023-10-09/6383245566383785326572571.jpg "Chemical Name：Chloro[1,3-bis(mesityl)imidazole-2-ylidene]gold(I)") |
| | Chloro[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]gold(I) Preparation Products And Raw materials |
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