Storage and manufacture of Oxygen

Oxygen comprises 21% of the Earth's atmosphere and is the third most abundant element in the universe by mass after hydrogen and helium. It is a highly reactive non-metal with the atomic number 8 and chemical symbol O. 

Uses

1. Management of cellular hypoxia (either caused by hypoxaemia or low cardiac output states). 2. Treatment of carbon monoxide poisoning. 3. Treatment of anaerobic infections. 4. Treatment of decompression sickness. 

Presentation and storage 

Oxygen is a colourless, tasteless and odourless gas at room temperature and pressure. It supports combustion and, in the correct circumstances, is explosive. It has a specific gravity of 1.105 and a molecular mass 32. At atmospheric pressure, it liquefies at −183°C. 

There are two common means of oxygen storage for hospital use: 

1. Cylinders. Traditionally cylinders containing oxygen have a black body with white shoulders, although there are now lightweight, fibreglass cylinders in use that are fully white in colour. Both types of cylinders store oxygen at a pressure of 137 bar (13,700 kPa) at 15°C when full. 

2. Vacuum insulated evaporator (VIE). The VIE is a large vessel that stores liquid oxygen at approximately −160°C and 7 bar and is used in medical or industrial facilities where oxygen demand is high (usually in excess of 150,000 l week −1 ). Oxygen is delivered to the hospital from either the VIE or a cylinder manifold through PMGV and is regulated to 4 bar.

Manufacture

Oxygen can be manufactured from air in two main ways: 

1. Fractional distillation of air. Oxygen is manufactured commercially by fractional distillation of liquid air. Before liquefaction of air, carbon dioxide is removed and liquid oxygen and nitrogen separated by means of their different boiling points (oxygen –183°C; nitrogen – 195°C). 

2. Oxygen concentrators. Oxygen concentrators produce oxygen from ambient air by absorption of nitrogen onto types of alumina silicates. Oxygen concentrators are useful both in hospitals and in long-term domestic use in remote areas such as in developing countries and in military surgery. The gas formed by oxygen concentrators contains small quantities of inert gases (e.g. argon); these are harmless but reduce the maximal concentration of oxygen that can be produced.